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Antioxidant effects of chlorophyll and pheophytin on the autoxidation of oils in the dark. II. The mechanism of antioxidative action of chlorophyll

Endo, Yasushi, Usuki, Riichiro, Kaneda, Takashi·1985·Journal of the American Oil Chemists' Society

Abstract

To understand the mechanism of the antioxidant effect of chlorophyll on the autoxidation of oils in the dark, antioxidant activities of several derivatives of chlorophyll were compared. Antioxidant activities were observed in chlorophyll derivatives such as protopor‐phyrin methyl ester and its magnesium chelated compound. Porphyrin seems to be an essential chemical structure for the antioxidant activity of chlorophyll. Chlorophyll did not decompose the hydroperoxides, but reduced free radicals such as 1,1‐diphenyl‐2‐picrylhydrazyl. Electron spin resonance spectrum of the π‐cation radical was recorded during the oxidation of chlorophyll in methyl linoleate solution. These observations suggest that chlorophyll may act as a hydrogen donor to break the chain reaction.

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Metadata

Authors
Endo, Y., Usuki, R., & Kaneda, T.
Venue
Journal of the American Oil Chemists' Society
Publisher
Wiley
Published
1985-09
Volume
62
Issue
9
Pages
1387-1390
ISSN
  • 0003-021X (ISSN-L)
  • 1558-9331
OpenAlex
W1987094032
Cited by
159
References
0
FWCI
2.27
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Antioxidant effects of chlorophyll and pheophytin on the autoxidation of oils in the dark. II. The mechanism of antioxidative action of chlorophyll. https://app.cochat.ai/papers/10.1007/bf02545965
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Endo, Y., Usuki, R., & Kaneda, T. (1985). Antioxidant effects of chlorophyll and pheophytin on the autoxidation of oils in the dark. II. The mechanism of antioxidative action of chlorophyll. Journal of the American Oil Chemists' Society. https://doi.org/10.1007/bf02545965

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