Application of zirconium (IV) acetylacetonate to the copolymerization of glycolide with ε-caprolactone and lactide
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Zirconium derivatives are 10 times less toxic than tin counterparts, and Zr-containing drugs and cosmetics are accepted by the Food and Drug Administration.
“Zirconium derivatives being 10 times less toxic than tin counterparts and Zr-containing drugs and cosmetics being accepted by the Food and Drug Administration [27], they were investigated for the polyesters synthesis.”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [27]
LA and CL were polymerized by Zr(acac)4 in the 100-150 °C range.
“LA and CL were polymerized by Zr (acac)4 in the 100-150 °C range [27,28].”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [27]
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Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆
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- Authors
- Bero, M., Dobrzyński, P., & Kasperczyk, J.
- Affiliations
- Polish Academy of Sciences (PL)
- Venue
- Polymer Bulletin
- Published
- 1999-03-03
- Volume
- 42
- Issue
- 2
- Pages
- 131-139
- ISSN
- 0170-0839 (ISSN-L)
- 1436-2449
- OpenAlex
- W2042900577
- Cited by
- 49
- References
- 1
- Citations by year
- 2025: 1 · 2024: 1 · 2023: 2 · 2021: 1 · 2020: 1 · 2019: 1 · 2017: 1 · 2015: 2 · 2014: 3 · 2013: 1 · 2012: 5
- FWCI
- 4.43
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Polymer Bulletin (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- zirconium acetylacetonate, glycolide, ε-caprolactone, lactide, copolymerization, ring-opening polymerization, polymerization initiators, transesterification, high molecular weight polymers
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