Nanoferrites heterogeneous catalysts for biodiesel production from soybean and canola oil: a review
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Fossil fuel depletion and pollution are calling for alternative, renewable energies such as biofuels. Actual challenges include the design of efficient processes and catalysts to convert various feedstocks into biofuels. Here, we review nanoferrites heterogeneous catalysts to produce biodiesel from soybean and canola oil. For that, transesterification is the main synthesis route and offers simplicity, cost-effectiveness, better process control, and high conversion yield. Catalysis with nanoferrites and composites allow to obtain yields higher than 95% conversion with less than 5.0 wt.% of catalyst loading at 80 °C in 1-2 h. More than 90% conversion yields can be achieved with a moderate alcohol/oil molar ratio, i.e., between 12:1 to 16:1. Catalyst recovery is easy due to the magnetic properties of nanoferrite, which can be effectively reused up to 4 times with less than 10% loss of catalytic efficiency.
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It is not feasible to substitute fossil-based fuels with wind, solar, geothermal, marine and hydropower; hence biomass utilisation to produce fuel and chemicals is required.
“Thus, it is not feasible to substitute fossil-based fuels with the aforementioned sustainable energy sources; hence, biomass utilisation to produce fuel and chemicals is required (Bharti et al. 2021).”
From Conversion of biomass to biofuels and life cycle assessment: a review (2021) · cites this paper as Bharti et al. 2021
The Introduction (page unavailable) calls for cleaner alternatives to fossil fuels, and the Categories of biofuels section describes biomass-derived fuels. The paper does not say that wind, solar, geothermal, marine, or hydropower cannot replace fossil fuels, or that this makes biomass use necessary for producing fuels and chemicals. (LLM, conf=0.85)
Experimental — accuracy not yet measuredSecond-generation biofuels, primarily derived from non-edible sources, are more sustainable than first-generation biofuels.
“Second-generation biofuels, primarily derived from non-edible sources, such as switchgrass, poplar, straw, and food waste, are more sustainable than the first generation.”
From Microalgae biofuels: illuminating the path to a sustainable future amidst challenges and opportunities (2024) · cites this paper as [9]
Both first- and second-generation biofuels face limitations due to grain, land, and water resources.
“However, both face limitations due to grain, land, and water resources [9].”
From Microalgae biofuels: illuminating the path to a sustainable future amidst challenges and opportunities (2024) · cites this paper as [9]
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- Authors
- Naagar, M., Chalia, S., Thakur, P., Sridhara, S. N., Thakur, A., & Sharma, P. B.
- Affiliations
- Amity University (IN)
- Amity University Gurugram (IN)
- Hindustan Institute of Technology and Science (IN)
- Corresponding author
- Naagar, Manish
- Venue
- Environmental Chemistry Letters
- Published
- 2021-05-04
- Volume
- 19
- Issue
- 5
- Pages
- 3727-3746
- ISSN
- 1610-3653 (ISSN-L)
- 1610-3661
- PMC
- PMC8094988
- OpenAlex
- W3157891966
- Cited by
- 93
- References
- 126
- Citations by year
- 2026: 11 · 2025: 16 · 2024: 21 · 2023: 27 · 2022: 10 · 2021: 8
- FWCI
- 1.40
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Environmental Chemistry Letters (publishedVersion)
- PubMed Central (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Biodiesel Production and Applications
- Physical Sciences › Engineering › Mechanical Engineering › Catalysis and Hydrodesulfurization Studies
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Synthesis and Reactions
- Keywords
- ferrite nanoparticles, heterogeneous catalysis, biodiesel production, transesterification, soybean oil, canola oil, magnetic catalyst, catalyst recycling, catalyst reusability, alcohol to oil molar ratio, biofuels
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