Dispersive liquid-liquid microextraction of lead(II) as 5-(4-dimethylaminobenzylidene) rhodanine chelates from food and water samples
Abstract
A dispersive liquid-liquid microextraction procedure for lead(II) as its 5-(4-dimethylaminobenzylidene) rhodanine complex has been established prior to its microsampling flame atomic absorption spectrometric determination. The influences of various analytical parameters including pH, solvent type and volume, dispersive solvent type and volume, 5-(4-dimethylaminobenzylidene) rhodanine amount, salt effect, and centrifugation time and speed were investigated. The effects of certain alkali, alkaline earth, and transition metal ions on the quantitative extraction of lead(II) were also studied. Quantitative recoveries were obtained at pH 6. The enrichment factor was calculated as 125. The detection limit for lead is 1.1 μg/L. The accuracy of the method was tested with the additions recovery test and analysis of the standard reference materials (SPS-WW2 waste water, NIST SRM 1515 apple leaves, and TMDA-51.3 fortified water). Applications of the present procedure were tested by analyzing water and food samples.
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The separation and extraction of heavy metal ions from a sample solution depends on the pH of the medium due to complexation between metal ions and the ligand.
“The separation and extraction of heavy metal ions from a sample solution depends on the pH of the medium due to the complexation between metal ions and the ligand [23,43].”
From Deep Eutectic Solvent-Based Microextraction of Lead(II) Traces from Water and Aqueous Extracts before FAAS Measurements (2020) · cites this paper as [43]
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Ten years of dispersive liquid–liquid microextraction and derived techniques
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“The separation and extraction of heavy metal ions from a sample solution depends on the pH of the medium due to the complexation between metal ions and the ligand [23,43].”
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- Authors
- Alothman, Z. A., Al-Shaalan, N. H., Habila, M. A., Unsal, Y. E., Tuzen, M., & Soylak, M.
- Affiliations
- King Saud University (SA)
- Tokat Gaziosmanpaşa Üniversitesi (TR)
- Erciyes University (TR)
- Corresponding author
- Soylak, Mustafa
- Venue
- Environmental Monitoring and Assessment
- Published
- 2015-01-25
- Volume
- 187
- Issue
- 2
- Pages
- 9-9
- ISSN
- 0167-6369 (ISSN-L)
- 1573-2959
- OpenAlex
- W2070457598
- Cited by
- 22
- References
- 49
- Citations by year
- 2023: 1 · 2022: 1 · 2021: 4 · 2020: 2 · 2019: 4 · 2018: 3 · 2017: 1 · 2016: 4 · 2015: 1 · 2013: 1
- FWCI
- 2.33
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Environmental Monitoring and Assessment (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Chemistry › Electrochemistry › Electrochemical Analysis and Applications
- Physical Sciences › Environmental Science › Water Science and Technology › Environmental and Analytical Chemistry Studies
- Keywords
- dispersive liquid-liquid microextraction, lead(II) determination, preconcentration, food samples, water samples, flame atomic absorption spectrometry, enrichment factor
- MeSH terms
- Chelating Agents, Environmental Monitoring, Environmental Pollutants, Food Analysis, Food Contamination, Lead, Rhodanine, Water Pollutants, Chemical, Limit of Detection, Liquid Phase Microextraction, Wastewater
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