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A mini review of NiFe-based materials as highly active oxygen evolution reaction electrocatalysts

Gong, Ming, Dai, Hongjie·2015·Nano Research
DOI 10.1007/s12274-014-0591-z
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Abstract

Oxygen evolution reaction (OER) electrolysis, as an important reaction involved in water splitting and rechargeable metal-air batteries, has attracted increasing attention for clean energy generation and efficient energy storage. Nickel/iron (NiFe)-based compounds have been known as active OER catalysts since the last century, and renewed interest has been witnessed in recent years on developing advanced NiFe-based materials for better activity and stability. In this review, we present the early discovery and recent progress on NiFe-based OER electrocatalysts in terms of chemical properties, synthetic methodologies and catalytic performances. The advantages and disadvantages of each class of NiFe-based compounds are summarized, including NiFe alloys, electrodeposited films and layered double hydroxide nanoplates. Some mechanistic studies of the active phase of NiFe-based compounds are introduced and discussed to give insight into the nature of active catalytic sites, which could facilitate further improving NiFe based OER electrocatalysts. Finally, some applications of NiFe-based compounds for OER are described, including the development of an electrolyzer operating with a single AAA battery with voltage below 1.5 V and high performance rechargeable Zn-air batteries.

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Metadata

Authors
Gong, M., & Dai, H.
Venue
Nano Research
Publisher
Tsinghua University Press
Published
2014-11-03
Volume
8
Issue
1
Pages
23-39
ISSN
  • 1998-0000 (ISSN-L)
  • 1998-0124
DOI
10.1007/s12274-014-0591-z
OpenAlex
W2066613146
Cited by
1,440
References
4
FWCI
30.02
Type
journal article
Language
en
Open access
closed
Licence
www.springer.com/tdm (tdm)

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