Spontaneous formation of optically active substances
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Under conditions of rare crystal nucleation, rapid growth, and fast racemization in solution, only monomers with chirality matching the primary nuclei crystallize, leading to SMSB.
“Under these circumstances, only monomers with matching chirality to the primary nuclei crystallize leading to SMSB.55,355”
From Possible chemical and physical scenarios towards biological homochirality (2022) · cites this paper as [355]
Havinga's experiments with N,N,N-allylethylmethylanilinium iodide gave crystals that were in 12 of 14 cases more dextrorotatory.
“Fourteen supersaturated solutions were gently heated in sealed tubes, then stored at 0 1C to give crystals which were in 12 cases inexplicably more dextrorotatory”
From Possible chemical and physical scenarios towards biological homochirality (2022) · cites this paper as [355]
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- Authors
- Havinga, E.
- Corresponding author
- Havinga, E.
- Venue
- Biochimica et Biophysica Acta
- Publisher
- Elsevier BV
- Published
- 1954-01
- Volume
- 13
- Issue
- 2
- Pages
- 171-174
- ISSN
- 0006-3002 (ISSN-L)
- OpenAlex
- W1973584973
- Cited by
- 221
- References
- 5
- Citations by year
- 2026: 4 · 2025: 6 · 2024: 4 · 2023: 3 · 2022: 8 · 2021: 10 · 2020: 10 · 2019: 9 · 2018: 3 · 2017: 5 · 2016: 6 · 2015: 10 · 2014: 6 · 2013: 7 · 2012: 3
- FWCI
- 3.38
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Biochimica et Biophysica Acta (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Physics and Astronomy › Astronomy and Astrophysics › Origins and Evolution of Life
- Physical Sciences › Chemistry › Organic Chemistry › Chemistry and Stereochemistry Studies
- Physical Sciences › Chemistry › Spectroscopy › Molecular spectroscopy and chirality
- Keywords
- optical activity, chiral molecules, closed systems, origin of life
- MeSH terms
- Chemistry, Organic, Eye, Organic Chemistry Phenomena
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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