The bifurcation behavior of tubular reactors
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The dynamics of the reactant concentration can be described by the PDE given in Equation (1), belonging to the class of second order parabolic PDEs commonly used to characterize diffusion-convection-reaction systems.
“By applying first-principle modelling through relevant mass balance relations on an infinitesimally small section of the reactor, the dynamics of the reactant concentration can be described by the PDE given in Equation ( 1), belonging to the class of second order parabolic PDEs commonly used to characterize diffusion-convection-reaction systems [25] in chemical engineering.”
From Optimal control of axial dispersion tubular reactors with recycle: Addressing state‐delay through transport <scp>PDEs</scp> (2025) · cites this paper as [25]
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“Coupled with the nonlinearity of the reaction rate, the positive feedback can lead to state multiplicity even in stand-alone reactors (Jensen & Ray, 1982; Weisz & Hicks, 1962).”
BackgroundMultiplicity of conversion in a cascade of imperfectly stirred tank reactors
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Catalytic reactions and reactors: A surface science approach
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Intelligent Process Control with Supervisory Knowledge-Based Systems
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Intelligent process control with supervisory knowledge-based systems
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The bifurcation behavior of an autothermal packed bed tubular reactor
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Bifurcation analysis of chemical reactors and reacting flows
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“The tubular reactor where an exothermic reaction A ! B occurs [ 49 ] was used as an illustrative case study to demonstrate the capabilities of RPRH since it has a rich parametric behaviour including a number of bifurcations (turning points, Hopf points), instabilities and multiple steady states making the optimisation…”
MethodMultiple Model Predictive Control of Dissipative PDE Systems
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“The model for the reactor consists of two parabolic PDEs [25] ∂x1 ∂ t = 1 Pe1 ∂2x1 ∂y2 − ∂x1 ∂y − Da · x1 exp ( γ x2 1 + x2 ) ∂x2 ∂ t = 1 Pe2 ∂2x2 ∂y2 − ∂x2 ∂y + C Da · x1 exp ( γ x2 1 + x2 ) +β(x2w − x2) (22) where y is the dimensionless longitudinal coordinate, r is the recycle ratio, Da is the Damköhler number, Pe1…”
MethodInfluentialJaree, A., Hudgins, R. R., Budman, H. M., Silveston, P. L., Yakhnin, V. Z., & Menzinger, M. (2003) · Chemical Engineering Science · doi:10.1016/s0009-2509(02)00614-0 · Cited by 21 · see citing works
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Flatness of Semilinear Parabolic PDEs—A Generalized Cauchy–Kowalevski Approach
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“, [33] for model details and to [12] for the considered normalization process.”
BackgroundMoving hot spots and resonance in adiabatic packed‐bed reactors
Yakhnin, V. Z., & Menzinger, M. (1998) · AIChE Journal · doi:10.1002/aic.690440521 · Cited by 20 · see citing works
Kinetically induced multiplicity of steady states in integral catalytic reactors
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Phase transition and steady-state multiplicity in a trickle-bed reactor
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Differential flow instability of the exothermic standard reaction in a tubular cross-flow reactor
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Model predictive control of a non-isothermal axial dispersion tubular reactor with recycle
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Backstepping-Forwarding Designs for Doubly- Distributed Delay-PDE-ODE Systems
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Efficient modeling of the nonlinear dynamics of tubular heterogeneous reactors
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“…reaction for which the equations of the pseudohomogeneous axial dispersion model are two coupled nonlinear parabolic PDEs which, in dimension-less form are (Jensen & Ray, 1982): with boundary conditions: Here x 1 and x 2 are the con v ersion and the dimension-less temperature, respecti v ely.”
BackgroundMethodLee, C. K., Morbidelli, M., & Varma, A. (1987) · Chemical Engineering Science · doi:10.1016/0009-2509(87)80164-1 · Cited by 18 · see citing works
Closed-loop monitoring systems for detecting impending instability
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“Examples include electric power system voltage collapse [18], chemical reactor runaway [ 12 ], jet engine stall [13], aircraft stall at high angle-of-attack [5], and laser system instability [8].”
BackgroundFront initiation on microdesigned composite catalysts
Li, X., Kevrekidis, I. G., Pollmann, M., Papathanasiou, A. G., & Rotermund, H. H. (2002) · Chaos An Interdisciplinary Journal of Nonlinear Science · doi:10.1063/1.1452739 · Cited by 17 · see citing works
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A Heterogeneous Multiscale Dynamic Model for Simulation of Catalytic Reforming Reactors
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Optimization Strategies in a Fixed-Bed Reactor for HCl Oxidation
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The Differential Flow Instabilities
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An Input/Output Model Reduction-Based Optimization Scheme for Large-Scale Systems
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“This system exhibits a highly nonlinear behavior, as shown in [22], and its rich parametric space leads to D ow nl oa de d 01 /0 4/ 13 to 1 29 .”
BackgroundMethodModel reduction-based optimization using large-scale steady-state simulators
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Novel Multiplicity and Stability Criteria for Non-Isothermal Fixed-Bed Reactors
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Complex Nonlinear Behavior in the Full-Scale High-Impact Polystyrene Process
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“Well-known examples concern (bio-)chemical tubular and fixed-bed reactors for production or degradation with complex dynamical behaviour and multiple steady states [1,2].”
BackgroundIdentification of low-order parameter-varying models for large-scale systems
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Input constrained adaptive tracking for a nonlinear distributed parameter tubular reactor
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“Varma and Amundson [9], Jensen and Ray [6], Margolis [11] and Hlavacek, Hofmann and Kubicek [10] observe oscillations for "diffusion-convection-reaction" problems.”
BackgroundMethodClosed-loop monitoring systems for detecting incipient instability
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“Examples include electric power system voltage collapse [ll], chemical reactor runaway [ 6 ], jet engine stall [7], aircraft stall at high angle-of-attack [2], and laser system instability [4].”
BackgroundIgnition–extinction analysis of catalytic reactor models
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Control of an exothermic packed-bed tubular reactor
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Exploring the Steady Operation of a Continuous Pilot Plant for the Di‐Nitration Reaction
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Estimating spectral properties of the thermal instability in packed-bed reactors
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Forced periodic operation of tubular reactors
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Absolute instability of a tubular packed-bed reactor with recycling
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A Reduced Input/Output Dynamic Optimisation Method for Macroscopic and Microscopic Systems
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“It is a tubular reactor with pseudohomogeneous axial dispersion, where a simple exothermic irreversible first order reaction, A → B, occurs [67].”
BackgroundThe role of surface inhomogeneities in pattern formation on catalytic surfaces
Jensen, K. F. (1983) · Chemical Engineering Science · doi:10.1016/0009-2509(83)80006-2 · Cited by 9 · see citing works
Self-citationSørensen, M. D. P. (2013) · Chemical Engineering Science · doi:10.1016/j.ces.2013.11.012 · Cited by 8 · see citing works
- Authors
- Jensen, K. F., & Ray, W. H.
- Affiliations
- University of Wisconsin–Madison (US)
- Corresponding author
- Ray, W.Harmon
- ORCID
- Jensen, Klavs F.
- Venue
- Chemical Engineering Science
- Publisher
- Elsevier BV
- Published
- 1982
- Volume
- 37
- Issue
- 2
- Pages
- 199-222
- ISSN
- 0009-2509 (ISSN-L)
- OpenAlex
- W2065214383
- Cited by
- 180
- References
- 86
- Citations by year
- 2026: 2 · 2025: 5 · 2024: 5 · 2022: 3 · 2021: 4 · 2020: 4 · 2019: 5 · 2018: 3 · 2017: 4 · 2016: 3 · 2015: 6 · 2014: 1 · 2013: 7 · 2012: 2
- FWCI
- 5.55
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Engineering Science (publishedVersion)
- Defense Technical Information Center (DTIC) (submittedVersion)
- Topics
- Physical Sciences › Engineering › Computational Mechanics › Heat and Mass Transfer in Porous Media
- Physical Sciences › Computer Science › Computer Networks and Communications › Nonlinear Dynamics and Pattern Formation
- Physical Sciences › Mathematics › Geometry and Topology › Advanced Differential Equations and Dynamical Systems
- Keywords
- tubular reactor, bifurcation analysis, Hopf bifurcation, steady-state profiles, axial dispersion, first-order irreversible reaction, multiple steady states, periodic solutions, Lewis number, Peclet number, fixed-bed reactor, reaction-diffusion systems, two-phase model
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