Isotope geochemistry of sedimentary sulfates
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The d34S sulfate variations in Phanerozoic oceans, based on evaporites, form an overall trough-like trend similar to strontium isotopes.
“The d34Ssulfate variations in 'Phanerozoic' oceans, based on evaporites (Claypool et al., 1980; Holser and Kaplan, 1966), form an overall trough-like trend similar to strontium isotopes (Figure 30).”
From Evolution of Sedimentary Rocks (2014) · cites this paper as Holser and Kaplan, 1966
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“The remaining record comprises 16 individual dS values for which the stratigraphic assignment is simply ‘‘Jurassic’’ (Claypool et al., 1980; Holser and Kaplan, 1966; Richardson and Hansen, 1991).”
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“This transfer isassociatedwithasmall sulphur isotopicfractionation of less than +2.4‰ ( Holser and Kaplan, 1966 ).”
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“Volcanism and hydrothermal activity are documented sources of isotopically depleted sulphate (d34 S = 0 to 3& but very variable) to the present-day world ocean (Holser & Kaplan, 1966; Walker, 1986; Paytan et al., 2004; Bottrell & Newton, 2006).”
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“Previous studies have shown that the δ(34)S value of seawater sulphate in the Early Middle Permian (Early Chihsia) was about 12‰ (Holser and Kaplan, 1966; Claypool et al., 1980; Strauss, 1997; Kirkland et al., 2000).”
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“The stratigraphic positions of the evaporites, together with the determinations of sulfur isotope ratios, are indicators for the geological age ( Holser and Kaplan 1966 ).”
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“Precambrian seawater at the time of Lower Roan deposition had a mean sulfate d34S value of +17.5±3& (Holser and Kaplan 1966; Claypool et al. 1980); data partly constrained by d34S anhydrite analyses from the Copperbelt which range from +14.2 to + 18.9& (Dechow and Jensen 1965; Claypool et al. 1980;…”
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“Sinks include burial of S-bearing phases such as bacterially mediated sedimentary sulfides (Berner and Raiswell, 1983; Berner, 1984; Kump;, 1989), precipitation of sulfur-bearing evaporite minerals in the shallow oceans (Holser and Kaplan, 1966; Raab and Spiro, 1991) and at mid-ocean ridge hydrothermal circulation sys…”
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“Determination of sulfur isotope ratios, which is used for evaporites containing sulfates of marine origin ( Holser and Kaplan 1966 ), confirmed a Permian or Triassic age for the Alpine salt deposits (Pak and Schauberger 1981).”
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“ozoic seawater at the time of deposition of the Roan Group ( Holser and Kaplan 1966; Holser 1977; Claypool et al. 1980; Hurtgen et al. 2002; Fig. 8). This value is supported by δ 34 S analyses on anhydrite from the Roan Group,”
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“can be explained by (1) precipitation of evaporites in a restricted basin in the presence of organic matter (McKibben and Eldridge, 1989; Utrilla et al., 1992); and/or (2) supply of sulfates of continental origin to the restricted basin that would enrich the basin in light S-isotopes ( Holster and Kaplan, 1966 ).”
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The rise of oxygen and siderite oxidation during the Lomagundi Event
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“for the isotopic composition of limestones as a function of the siderite oxidation flux (see SI Appendix): δcarb1⁄2‰ = Fsid δsid + e α′ Fin + α′ F w sid [10] where α′= 13 7 − 6 7 α.”
- Authors
- Holser, W. T., & Kaplan, I. R.
- Affiliations
- University of California System (US)
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 1966
- Volume
- 1
- Pages
- 93-135
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2019135021
- Cited by
- 550
- References
- 0
- Citations by year
- 2026: 10 · 2025: 11 · 2024: 7 · 2023: 7 · 2022: 16 · 2021: 13 · 2020: 15 · 2019: 12 · 2018: 11 · 2017: 10 · 2016: 9 · 2015: 5 · 2014: 9 · 2013: 10 · 2012: 10
- FWCI
- 12.91
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Geology (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Keywords
- anhydrite, gypsum, sulfur isotopes, δ34S, paleoceanography, sulfur cycling, Late Paleozoic, Mesozoic, Tertiary, Late Permian, evaporites, paleogeography, tectonic change
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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