Formation and solid solution behavior of Ca-rhodochrosites in marine muds of the Baltic deeps
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Baltic carbonates are predominantly Mn carbonates with a substantial contribution of Ca.
“Data from the literature (Jakobsen and Postma, 1989; Sternbeck and Sohlenius, 1997; Lepland and Stevens, 1998; Huckriede and Meischner 1996; Kulik et al., 2000) suggest that Baltic carbonates are predominantly Mn carbonates with a substantial contribution of Ca.”
From Are recent changes in sediment manganese sequestration in the euxinic basins of the Baltic Sea linked to the expansion of hypoxia? (2015) · cites this paper as Jakobsen and Postma, 1989
Formation of Mn-bearing carbonates in the Gotland Basin and Landsort Deep is generally described as ubiquitous after inflows.
“Formation of Mn-bearing carbonates in the Gotland Basin and Landsort Deep is generally described as being ubiquitous after inflows (e.g. Jakobsen and Postma, 1989).”
From Are recent changes in sediment manganese sequestration in the euxinic basins of the Baltic Sea linked to the expansion of hypoxia? (2015) · cites this paper as Jakobsen and Postma, 1989
From phase relationships in anoxic marine muds, a0 is estimated to be −3.5 at 5 °C.
“From the phase relationships in anoxic marine muds, a0 is estimated to be − 3.5 (5 °C) [18]”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [18]
Literature reports widely differing a0 values for the (Ca,Mn)CO3 solid solution, including +3.23 at 25 °C, −1 ± 3 at 20 °C, −3.5 at 5 °C, and <2 at 25 °C.
“For example, a theoretically derived a0 = +3.23 (25 °C) was proposed [10], while a0 = − 1 ± 3 at 20 °C was calculated from experimental solubility data [4]. A negative value of a0 (− 3.5 at 5 °C) was also estimated from observations on natural phase relations in marine anoxic sediments [18]. The a0 parameter was calculated from the miscibility gap [15] to be a0 < 2 at 25 °C [16].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [18]
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- Authors
- Jakobsen, R., & Postma, D.
- Affiliations
- Geological Survey of Denmark and Greenland (DK)
- Technical University of Denmark (DK)
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 1989-10
- Volume
- 53
- Issue
- 10
- Pages
- 2639-2648
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W1970269733
- Cited by
- 96
- References
- 56
- Citations by year
- 2026: 3 · 2025: 2 · 2022: 2 · 2021: 3 · 2020: 4 · 2019: 2 · 2018: 2 · 2017: 1 · 2016: 2 · 2015: 3 · 2014: 3 · 2013: 2 · 2012: 2
- FWCI
- 2.28
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Environmental Science › Environmental Chemistry › Methane Hydrates and Related Phenomena
- Keywords
- rhodochrosite, authigenic carbonates, solid solutions, organic matter decomposition, anoxic basins, recrystallization, ion exchange, manganese carbonate, calcite
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