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Manganese (II) oxidation at mineral surfaces: A microscopic and spectroscopic study

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Junta, Jodi L., Hochella, Michael F.·1994·Geochimica et Cosmochimica Acta
DOI 10.1016/0016-7037(94)90226-7
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Abstract

The products of the heterogeneous oxidation of Mn(II)aq at hematite, goethite, and albite surfaces were studied, using Scanning Force Microscopy (SFM), X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM), Auger Electron Spectroscopy (AES), Scanning Auger Microscopy (SAM), and X-ray Diffraction (XRD). Oxidation experiments were conducted at room temperature in aerated solutions containing 4.0–26.7 ppm Mn(II)aq at pHs ranging from 7.8 to 8.7. Exposure times ranged from a few minutes up to six months. Through this study, it was found that steps are the most reactive sites for initiating the adsorption-oxidation reaction, independent of the mineral surface used. After the initial oxidation of Mn(II) at or near these sites, the continued adsorption-oxidation process is mineral surface dependent resulting in two types of growth paths, substrate and precipitate controlled growth. Substrate controlled growth (hematite and goethite) is characterized by the formation of a thin coating of protocrystallites that grows across the mineral surface away from the initial adsorption-oxidation site. In contrast, precipitate controlled growth (albite) is characterized by the development of precipitate ridges along a step edge. These two surface-controlled growth processes influence the distribution of the precipitates found with SEM and in hand-samples. However, independent of the mineral surface used in the experiments, the resulting precipitates consisted of Mn(III) bearing oxyhydroxides, predominately β-MnOOH.

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Metadata

Authors
Junta, J. L., & Hochella, M. F.
Venue
Geochimica et Cosmochimica Acta
Publisher
Elsevier BV
Published
1994-11
Volume
58
Issue
22
Pages
4985-4999
ISSN
0016-7037 (ISSN-L)
DOI
10.1016/0016-7037(94)90226-7
OpenAlex
W1975576984
Cited by
329
References
0
FWCI
15.64
Type
journal article
Language
en
Open access
hybrid
Licence

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Junta, J. L., & Hochella, M. F. (1994). Manganese (II) oxidation at mineral surfaces: A microscopic and spectroscopic study. Geochimica et Cosmochimica Acta. https://doi.org/10.1016/0016-7037(94)90226-7

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