The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
In the absence of catalytic metals ascorbate does not autoxidize at pH 7: ascorbate as a test for catalytic metals
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Metal catalysis in the depolymerization of hyaluronic acid by autoxidants
Harris, M. J., Herp, A., & Pigma, W. (1972) · Journal of the American Chemical Society · doi:10.1021/ja00776a047 · Cited by 44
Research works printed but not linked: 38
- Barron, 1936, Studies on biological oxidations. V. Copper and hemochromogens as catalysts for the oxidation of ascorbic acid. The mechanism of the oxidation, J. Biol. Chem., 112, 625, 10.1016/S0021-9258(18)74946-6 · doi:10.1016/s0021-9258(18)74946-6
- Noguchi, 1961, Citric acid fermentation of sugars purified with chelating resin, J. Bacteriol., 82, 538, 10.1128/jb.82.4.538-541.1961 · doi:10.1128/jb.82.4.538-541.1961
- Morell, 1962, Is ceruloplasmin as ascorbate acid oxidase?, J. Biol. Chem., 237, 3455, 10.1016/S0021-9258(19)70838-2 · DOI
- McDermott, 1968, Role of iron in the oxidase activity of ceruloplasmin, Biochim. Biophys. Acta, 151, 541, 10.1016/0005-2744(68)90001-6 · DOI
- Binder, 1970, Complex formation of collagen with copper and its application to the quantitative determination of collagen, Anal. Biochem., 37, 129, 10.1016/0003-2697(70)90267-8 · doi:10.1016/0003-2697(70)90267-8
- Poyer, 1971, Reduced triphosphopyridine nucleotide oxidase-catalyzed alterations of membrane phospholipids, J. Biol. Chem., 246, 263, 10.1016/S0021-9258(18)62558-X · DOI · Paper page
- Jacobsen, 1972, A Bacillus ribonucleic acid phosphodiesterase with associated 5′-nucleotidase activity, J. Biol. Chem., 247, 5811, 10.1016/S0021-9258(19)44830-8 · doi:10.1016/s0021-9258(19)44830-8
- Rayment, 1972, Biological and chemical comparisons of methods for removing copper from macronutrient solutions used for plant growth investigations, Plant Soil, 36, 547, 10.1007/BF01373506 · doi:10.1007/bf01373506
- Buettner, 1978, The effect of iron on the distribution of superoxide and hydroxyl radicals as seen by spin trapping and on the superoxide dismutase assay, Photochem. Photobiol., 28, 693, 10.1111/j.1751-1097.1978.tb07001.x · DOI · Paper page
- Wong, 1981, The role of superoxide and hydroxyl radicals in the degradation of hyaluronic acid induced by metal ions and ascorbic acid, J. Inorg. Biochem., 14, 127, 10.1016/S0162-0134(00)80033-1 · DOI · Paper page
- Borg, 1984, Cytotoxicity from coupled redox cycling of autoxidizing xenobiotics and metals, Isr. J. Chem., 24, 38, 10.1002/ijch.198400007 · DOI · Paper page
- Sutton, 1984, Chelated iron-catalyzed OH formation from paraquat radicals and H2O2. Mechanism of formate oxidation, Arch. Biochem. Biophys., 235, 106, 10.1016/0003-9861(84)90259-5 · DOI
- Chiou, 1985, Specific cleavages of DNA by ascorbate in the presence of copper ion or copper chelates, J. Biochem., 98, 1723, 10.1093/oxfordjournals.jbchem.a135445 · doi:10.1093/oxfordjournals.jbchem.a135445
- Buettner, 1986, Ascorbate autoxidation in the presence of iron and copper chelates., Free Rad. Res. Commun., 1, 349, 10.3109/10715768609051638 · DOI · Paper page
- Gutteridge, 1987, A method for removal of trace iron contamination from biological buffers, FEBS Lett., 214, 362, 10.1016/0014-5793(87)80088-1 · DOI
- Grinstead, 1960, The oxidation of ascorbic acid by hydrogen peroxide. Catalysis by ethyllenediaminetetraaceto-iron(III)_, J. Am. Chem. Soc., 82, 3464, 10.1021/ja01498a057 · doi:10.1021/ja01498a057
- Khan, 1967, Metal ion and metal chelate catalyzed oxidation of ascorbic acid by molecular oxygen. I. Cupric and ferric ion catalyzed oxidation, J. Am. Chem. Soc., 89, 4176, 10.1021/ja00992a036 · DOI · Paper page
- Underwood, 1958, Spectroscopic determination of iron with ethylenediaminedi(o-hydroxy-phenyl acetic acid), Anal. Chem., 30, 33, 10.1021/ac60133a010 · doi:10.1021/ac60133a010
- Buettner, 1987, The reaction of superoxide, formate radical, and hydrated electron with transferrin and its model compound, Fe(III)-ethylenediamine N,N′-bis[2-(2-hydroxyphenyl) acetic acid] as studied by pulse radiolysis, J. Biol. Chem., 262, 11995, 10.1016/S0021-9258(18)45308-2 · DOI
- Buettner, 1987, The kinetics of the reaction of ferritin with superoxide., Free Rad. Res. Commun., 2, 369, 10.3109/10715768709065304 · DOI
- Mapson, 1945, Influence of halides on the oxidation of ascorbic acid 2. Action of Cl− on the cupric-cuprous system, Biochem. J., 39, 228, 10.1042/bj0390228 · doi:10.1042/bj0390228
- Scaife, 1959, The catalysis of ascorbic acid oxidation by copper and its complexes with amino acids, peptides, and proteins, Can. J. Biochem. Physiol., 37, 1049, 10.1139/y59-113 · doi:10.1139/y59-113
- Weissberger, 1944, Oxidation processes. XVII. The autoxidation of ascorbic acid in the presence of copper, J. Am. Chem. Soc., 66, 700, 10.1021/ja01233a011 · doi:10.1021/ja01233a011
- Weissberger, 1943, Oxidation processes. XVI. The autoxidation of ascorbic acid, J. Am. Chem. Soc., 65, 1934, 10.1021/ja01250a038 · DOI
- Fong, 1987, Factors affecting ascorbate oxidation in aqueous humor, Curr. Eye Res., 6, 357, 10.3109/02713688709025188 · doi:10.3109/02713688709025188
- Gutteridge, 1981, Superoxide-dependent formation of hydroxyl radicals in the presence of iron salts. Detection of ‘free’ iron in biological systems by using bleomycin-dependent degradation of DNA, Biochem. J., 199, 263, 10.1042/bj1990263 · DOI · Paper page
- Scarpa, 1983, Superoxide ion as active intermediate in the autoxidatio of ascorbate by molecular oxygen: Effect of superoxide dismutase, J. Biol. Chem., 258, 6695, 10.1016/S0021-9258(18)32271-3 · DOI · Paper page
- Kovachich, 1982, Inhibition of ascorbate autoxidation by a rat brain cortical factor, Neurosci. Lett., 34, 83, 10.1016/0304-3940(82)90096-9 · doi:10.1016/0304-3940(82)90096-9
- Misra, 1983, Inhibition of ascorbate autoxidation by the dialyzed soluble fraction of mammalian nervous tissues, Neurosci. Lett., 43, 103, 10.1016/0304-3940(83)90136-2 · doi:10.1016/0304-3940(83)90136-2
- Kovachich, 1984, Stabilization of ascorbic acid and norepinephrine in vitro by the subcellular fractions of rat cerebral cortex, Neurosci. Lett., 52, 153, 10.1016/0304-3940(84)90366-5 · doi:10.1016/0304-3940(84)90366-5
- Mishra, 1984, Inhibition of ascorbate autoxidation by a dialyzed, heat-denatured extract of plant tissues, Life Sci., 34, 2207, 10.1016/0024-3205(84)90322-9 · doi:10.1016/0024-3205(84)90322-9
- Mishra, 1984, Inhibition of the autoxidation of ascorbate and norepinephrine by extracts of Clostridium butyricum, Megasphaera elsdenii and Escherichiacoli, Life Sci., 35, 849, 10.1016/0024-3205(84)90410-7 · doi:10.1016/0024-3205(84)90410-7
- Matsumara, 1965, Catalytic role of iron in the depolymerization of hyaluronic acid by ascorbic acid, Arch. Biochem. Biophys., 110, 526, 10.1016/0003-9861(65)90446-7 · DOI · Paper page
- Yamazaki, 1962, The reduction of cytochrome c by enzyme-generated ascorbate free radical, J. Biol. Chem., 237, 224, 10.1016/S0021-9258(18)81390-4 · doi:10.1016/s0021-9258(18)81390-4
- Weis, 1975, Ascorbic acid and electron transport, Ann. NY Acad. Sci., 258, 190, 10.1111/j.1749-6632.1975.tb29279.x · doi:10.1111/j.1749-6632.1975.tb29279.x
- Beauchamp, 1970, A mechanism for the production of ethylene from methional. The generation of the hydroxyl radical by xanthine oxidase, J. Biol. Chem., 245, 4641, 10.1016/S0021-9258(18)62842-X · DOI · Paper page
- Fong, 1973, Evidence that peroxidation of lysosomal membranes is initiated by hydroxyl free radicals produced during flavin enzyme activity, J. Biol. Chem., 248, 7792, 10.1016/S0021-9258(19)43258-4 · DOI · Paper page
- Fong, 1976, Evidence for superoxide-dependent reduction of Fe(III) and its role in enzyme-generated hydoxyl radical formation, Chem.-Biol. Interact., 15, 77, 10.1016/0009-2797(76)90130-7 · DOI · Paper page
Cited by
Vitamins C and E: Beneficial effects from a mechanistic perspective
Traber, M. G., & Stevens, J. F. (2011) · Free Radical Biology and Medicine · doi:10.1016/j.freeradbiomed.2011.05.017 · Cited by 1,076
Hempel, S. L., Buettner, G. R., O’Malley, Y. Q., Wessels, D. A., & Flaherty, D. M. (1999) · Free Radical Biology and Medicine · doi:10.1016/s0891-5849(99)00061-1 · Cited by 740
Self-citationTransition metals as catalysts of “autoxidation” reactions
Miller, D. (1990) · Free Radical Biology and Medicine · doi:10.1016/0891-5849(90)90148-c · Cited by 739
Schoenfeld, J. D., Sibenaller, Z. A., Mapuskar, K. A., Wagner, B. A., Cramer-Morales, K. L., Furqan, M., Sandhu, S., Carlisle, T. L., Smith, M. C., Abu Hejleh, T., et al. (2017) · Cancer Cell · doi:10.1016/j.ccell.2017.02.018 · Cited by 443
Self-citationYin, X., Chen, K., Cheng, H., Chen, X., Feng, S., Song, Y., & Liang, L. (2022) · Antioxidants · doi:10.3390/antiox11010153 · Cited by 369
Metadata
- Authors
- Buettner, G. R.
- Venue
- Journal of Biochemical and Biophysical Methods
- Publisher
- Elsevier BV
- Published
- 1988-05
- Volume
- 16
- Issue
- 1
- Pages
- 27-40
- ISSN
- 0165-022X (ISSN-L)
- OpenAlex
- W2071267404
- Cited by
- 509
- References
- 1
- FWCI
- 16.74
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.elsevier.com/tdm/userlicense/1.0/ (tdm)
- www.elsevier.com/legal/tdmrep-license (tdm)
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: In the absence of catalytic metals ascorbate does not autoxidize at pH 7: ascorbate as a test for catalytic metals. https://app.cochat.ai/papers/10.1016/0165-022x(88)90100-5
- The paper
- Buettner, G. R. (1988). In the absence of catalytic metals ascorbate does not autoxidize at pH 7: ascorbate as a test for catalytic metals. Journal of Biochemical and Biophysical Methods. https://doi.org/10.1016/0165-022x(88)90100-5
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.