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Insights into coacervative and dispersive liquid-phase microextraction strategies with hydrophilic media – A review
Open accessAbstract
Since the development of liquid-phase microextraction (LPME), different LPME modes depending on the experimental set-up to carry out the extraction have been described. Dispersive liquid-liquid microextraction (DLLME), in which a small amount of the water-insoluble extraction solvent is dispersed in the sample, is the most successful mode in terms of number of applications reported. Advances within DLLME have been mainly shifted to the incorporation of green, smart and tunable materials as extraction solvents to improve the sustainability and efficiency of the method. In this sense, hydrophilic media represent a promising alternative since the water-miscibility of these substances increases the mass transfer of the analytes to the extraction media, leading to higher extraction efficiencies. Considering the variety of hydrophilic media that have been incorporated in LPME approaches resembling DLLME, this review aims to classify these methods in order to clarify the confusing terminology used for some of the strategies. Hydrophilic media covered in this review comprise surfactants, polar organic solvents, deep eutectic solvents, ionic liquids, water-miscible polymers, and switchable solvents. Different physicochemical mechanisms of phase separation are discussed for each LPME method, including the coacervation phenomena and other driving forces, such as pH, temperature, salting-out effect, metathesis reaction and organic solvents. LPME modes are classified (in cloud-point extraction, coacervative extraction, aqueous biphasic systems, and different DLLME modes depending on the extraction medium) according to both the nature of the water-miscible extraction phase and the driving force of the separation. In addition, the main advances and analytical applications of these methods in the last three years are described.
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“In 2019, Altunay et al. [65] employed for the first time a DESs synthesized by 'natural' components, termed as 'natural DES' (NADES) [66], for a DLLME application.”
From Use of green alternative solvents in dispersive liquid‐liquid microextraction: A review (2022) · cites this paper as [66]
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Items 201–277 of 277
Hamid, Y., & Fat’hi, M. R. (2018) · Food Analytical Methods · doi:10.1007/s12161-018-1186-1 · Cited by 21
Fırat, M., & Bakırdere, E. G. (2019) · Environmental Monitoring and Assessment · doi:10.1007/s10661-019-7252-3 · Cited by 21
Martinefski, M., Feizi, N., Lunar, L., & Rubio, S. (2019) · Chemosphere · doi:10.1016/j.chemosphere.2019.124525 · Cited by 21
Tian, H., Fu, H., Xu, C., & Xu, C. (2019) · Chromatographia · doi:10.1007/s10337-019-03781-2 · Cited by 21
Ulusoy, S., & Akcay, M. E. (2017) · Food Analytical Methods · doi:10.1007/s12161-017-0996-x · Cited by 20
Sürme, Y., Bişgin, A. T., Uçan, M., & Narin, İ. (2018) · Journal of Analytical Chemistry · doi:10.1134/s1061934818020120 · Cited by 20
Kachangoon, R., Vichapong, J., Burakham, R., Santaladchaiyakit, Y., & Srijaranai, S. (2018) · Molecules · doi:10.3390/molecules23051165 · Cited by 20
de Assis, R. C., Faria, B. A. D. A., Caldeira, C. L., Mageste, A. B., de Lemos, L. R., & Rodrigues, G. D. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.03.058 · Cited by 20
Soylak, M., Deryol, S., & Uzcan, F. (2019) · International Journal of Environmental & Analytical Chemistry · doi:10.1080/03067319.2019.1685092 · Cited by 20
Mortada, W. I., Kenawy, I. M. M., El-Gamal, G. G., & Moalla, S. M. N. (2017) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1007/s10967-017-5281-3 · Cited by 19
Bogdanov, M. G., & Svinyarov, I. (2018) · Journal of Chromatography A · doi:10.1016/j.chroma.2018.01.007 · Cited by 19
Yee, M. F., Emmel, G. N., Yang, E. J., Lee, E., Paek, J. H., Wu, B. M., & Kamei, D. T. (2018) · Frontiers in Chemistry · doi:10.3389/fchem.2018.00486 · Cited by 19
Zare, F., Ghaedi, M., Jannesar, R., & Tayebi, L. (2018) · New Journal of Chemistry · doi:10.1039/c7nj04576j · Cited by 18
Kojro, G., Rudzki, P. J., Pisklak, D. M., & Giebułtowicz, J. (2019) · Journal of Chromatography A · doi:10.1016/j.chroma.2019.01.031 · Cited by 18
Ravi Kumar, K., & Shyamala, P. (2019) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2019.103119 · Cited by 18
Wang, H., Xia, M., Ling, Y., Qian, F., Xu, J., Wang, Z., Li, J., & Wang, X. (2019) · Food Additives & Contaminants Part A · doi:10.1080/19440049.2019.1644458 · Cited by 18
Wang, K., Jiang, J., Kang, M., Li, D., Zang, S., Tian, S., Zhang, H., Yu, A., & Zhang, Z. (2017) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-017-0201-5 · Cited by 17
Bazeľ, Y., Rečlo, M., & Šandrejová, J. (2017) · Journal of Analytical Chemistry · doi:10.1134/s1061934817080032 · Cited by 17
Temel, N. K., & Gürkan, R. (2018) · Acta chimica slovenica · doi:10.17344/acsi.2017.3724 · Cited by 17
Hamid, Y., & Fat’hi, M. R. (2018) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-018-1378-z · Cited by 17
Pierson, S. A., Trujillo‐Rodríguez, M. J., & Anderson, J. L. (2018) · Journal of Separation Science · doi:10.1002/jssc.201800415 · Cited by 17
Jawad, S. K., Kadhium, M., & Azooz, E. A. (2018) · Eurasian Journal of Analytical Chemistry · doi:10.29333/ejac/94973 · Cited by 17
Saha, A., Neogy, S., Dumpala, R. M. R., Deb, S. B., Saxena, M. K., & Tomar, B. S. (2019) · Microchimica Acta · doi:10.1007/s00604-019-3292-1 · Cited by 17
Yıldız, D., & Demir, M. (2019) · Journal of Analytical Chemistry · doi:10.1134/s1061934819050022 · Cited by 17
Xu, J. L., Niu, M., & Xiao, Y. (2016) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-016-0054-3 · Cited by 16
Chen, L., Lei, Z., Hu, K., Yang, S., & Wen, X. (2017) · Microchemical Journal · doi:10.1016/j.microc.2017.11.016 · Cited by 16
Chen, C.-W., Liao, F.-Y., Lin, Y., Hsieh, T., Weng, J., & Feng, C. (2019) · Talanta · doi:10.1016/j.talanta.2019.02.091 · Cited by 16
Babaee, S., Daneshfar, A., & Sahraei, R. (2019) · Analytical Methods · doi:10.1039/c8ay02719f · Cited by 16
Ali, J., Tüzen, M., & Kazi, T. G. (2019) · Food Analytical Methods · doi:10.1007/s12161-019-01468-w · Cited by 16
Lv, Y., Bai, H., Yang, J., He, Y., & Ma, Q. (2019) · Analytical Chemistry · doi:10.1021/acs.analchem.9b00597 · Cited by 16
González-Martín, R., Pacheco‐Fernández, I., Ayala, J. H., Afonso, A. M., & Pino, V. (2019) · Talanta · doi:10.1016/j.talanta.2019.05.083 · Cited by 16
Self-citationVieira, A. W., Molina, G., Mageste, A. B., Rodrigues, G. D., & de Lemos, L. R. (2019) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2019.111775 · Cited by 16
Heydari, F., & Ramezani, M. (2019) · Journal of Analytical Chemistry · doi:10.1134/s1061934819110054 · Cited by 16
Zare-Shahabadi, V., Asaadi, P., Abbasitabar, F., & Shirmardi, A. (2016) · Journal of the Brazilian Chemical Society · doi:10.21577/0103-5053.20160241 · Cited by 15
Molaei, S., Seidi, S., Saleh, A., & Ghoulipour, V. (2017) · Analytical Methods · doi:10.1039/c7ay01270e · Cited by 15
Khiat, M., Pacheco‐Fernández, I., Pino, V., Benabdallah, T., Ayala, J. H., & Afonso, A. M. (2018) · Analytical Methods · doi:10.1039/c8ay00022k · Cited by 15
Self-citationArain, M. S., Kazi, T. G., Afridi, H. I., Khan, N., & Ali, J. (2017) · Applied Organometallic Chemistry · doi:10.1002/aoc.4157 · Cited by 14
Abdel-Fadeel, M. A., Al‐Saidi, H. M., El-Bindary, A. A., El‐Sonbati, A. Z., & Alharthi, S. S. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.11.138 · Cited by 14
Boukhelkhal, A., Benkortbi, O., & Hamadache, M. (2018) · Environmental Technology · doi:10.1080/09593330.2018.1472301 · Cited by 14
Sha, O., Wang, Y., Chen, X., Chen, J., & Chen, L. (2018) · Journal of Analytical Chemistry · doi:10.1134/s1061934818090083 · Cited by 14
Karadaş, C., & Kara, D. (2018) · Water Science & Technology Water Supply · doi:10.2166/ws.2018.133 · Cited by 14
Removal of Arsenazo-III from liquid radioactive waste by cloud point extraction
Hamed, M. M., & Aglan, R. F. (2019) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1007/s10967-019-06669-5 · Cited by 14
Li, X., Song, N., Feng, W., & Jia, Q. (2017) · Analytical Methods · doi:10.1039/c7ay00421d · Cited by 13
Gui, J., Huang, C., Yuan, J., Huang, Q., Long, F., Ma, A., & Pan, J. (2018) · Microchemical Journal · doi:10.1016/j.microc.2018.01.013 · Cited by 13
Hosseininejad, M. S., Faraji, H., & Jamshidi, A. (2018) · Water Science & Technology · doi:10.2166/wst.2018.480 · Cited by 13
Yıldırım, E., Gürkan, R., & Altunay, N. (2016) · Food Analytical Methods · doi:10.1007/s12161-016-0737-6 · Cited by 12
Bertón, P., Mammana, S. B., Locatelli, D. A., Lana, N. B., Hapon, M. B., Camargo, A. B., & Altamirano, J. C. (2016) · Electrophoresis · doi:10.1002/elps.201600247 · Cited by 12
de Amorim, K. P., & Andrade, L. S. (2017) · Analytical Methods · doi:10.1039/c7ay00047b · Cited by 12
Sadeghi, S., & Sarrafi, N. (2018) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-018-1388-x · Cited by 12
Hu, S., Xue, J., Yang, X., Chen, X., Wang, R., & Bai, X. (2018) · Journal of Separation Science · doi:10.1002/jssc.201800285 · Cited by 12
Makukha, O. G., Ivashchenko, L. A., Zaporozhets, O. A., & Doroschuk, V. O. (2018) · Chemical Papers · doi:10.1007/s11696-018-0618-0 · Cited by 12
Ma, L., Tong, W., Du, L., Huang, S., Wei, J., & Xiao, D. (2019) · Journal of Food Protection · doi:10.4315/0362-028x.jfp-18-594 · Cited by 12
Temel, N. K., & Gürkan, R. (2017) · Food Analytical Methods · doi:10.1007/s12161-017-0973-4 · Cited by 11
Iturbide-Casas, M., Molina‐Recio, G., & Cámara‐Martos, F. (2018) · Food Analytical Methods · doi:10.1007/s12161-018-1268-0 · Cited by 11
Serfor-Armah, Y., Carboo, D., Akuamoah, R. K., & Chatt, A. (2018) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1007/s10967-018-6194-5 · Cited by 11
Fırat, M., Chormey, D. S., Bakırdere, S., & Turak, F. (2019) · Environmental Monitoring and Assessment · doi:10.1007/s10661-019-7797-1 · Cited by 11
Gürkan, R., Altunay, N., & Gürkan, N. Z. (2017) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-017-1053-9 · Cited by 10
Aswathi, M., Mathai, S., Joseph, S. C., & Biju, V. M. (2017) · Separation Science and Technology · doi:10.1080/01496395.2017.1324491 · Cited by 10
Ziemblińska-Bernart, J., Nowak, I., & Rykowska, I. (2018) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-018-1543-4 · Cited by 10
Lara, A. B., Caballo, C., Sicilia, M. D., & Rubio, S. (2019) · Journal of Chromatography A · doi:10.1016/j.chroma.2019.04.058 · Cited by 10
Mukhopadhyay, C. K., Suba, M. A., Sivakumar, D., Dhamodharan, K., & Rao, R. V. S. (2019) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1007/s10967-019-06704-5 · Cited by 10
Urio, R. D. P., & Masini, J. C. (2016) · Analytical Letters · doi:10.1080/00032719.2016.1212203 · Cited by 9
Antep, H. M., Mumcu, T., Bostancı, K., Bozkurt, S. S., & Merdıvan, M. (2017) · TURKISH JOURNAL OF CHEMISTRY · doi:10.3906/kim-1611-51 · Cited by 9
Han, Q., Huo, Y., Wu, J., He, Y., Yang, X., & Long-hu, Y. (2017) · Molecules · doi:10.3390/molecules22040487 · Cited by 8
Han, Q., Huo, Y., Yang, X., He, Y., Wu, J., & Cai, H. (2017) · Analytical Methods · doi:10.1039/c7ay02522j · Cited by 8
Abbasi-Daronjoughi, F., Tamaddon, A., & Panahi, H. A. (2018) · Separation Science and Technology · doi:10.1080/01496395.2018.1448416 · Cited by 8
Zeeb, M., & Farahani, H. (2018) · Analytical and bioanalytical chemistry research · doi:10.22036/abcr.2018.98757.1164 · Cited by 8
Guo, D., Ni, L., Wang, L., & Shao, L. (2019) · Chirality · doi:10.1002/chir.23080 · Cited by 8
Shokrollahi, A., & Refahi, M. (2018) · Química Nova · doi:10.21577/0100-4042.20170303 · Cited by 7
Doroschuk, V. O., Маценко, І., Mandzyuk, Y. S., Makukha, O. G., & Grytsyk, N. O. (2019) · Journal of Analytical Chemistry · doi:10.1134/s1061934819070025 · Cited by 7
Masrournia, M., & Vaziry, A. (2018) · Journal of Analytical Chemistry · doi:10.1134/s1061934818020077 · Cited by 6
Analysis and Cloud Point Extraction of Trace Copper (II) in Urine of Occupational Workers
Hassan, M. K., & Khudhair, A. F. (2018) · Asian Journal of Chemistry · doi:10.14233/ajchem.2019.21567 · Cited by 6
Praikaew, W., Kiatkittipong, W., Kiatkittipong, K., Assabumrungrat, S., Aiouache, F., & Najdanovic‐Visak, V. (2019) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.9b00376 · Cited by 6
Kazi, T. G., Samejo, S., Afridi, H. I., Akhtar, A., & Baig, J. A. (2019) · Applied Organometallic Chemistry · doi:10.1002/aoc.5263 · Cited by 6
Guo, D., Ni, L., Wang, L., & Shao, L. (2019) · Chemical Research in Chinese Universities · doi:10.1007/s40242-019-8216-4 · Cited by 4
Tarhan, F. T., Antep, M., & Merdıvan, M. (2019) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1007/s10967-019-06464-2 · Cited by 4
Zhu, X., Chen, S., & Fu, H. (2017) · Food Analytical Methods · doi:10.1007/s12161-017-0844-z · Cited by 3
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Grau, J., Azorín, C., Benedé, J. L., Chisvert, A., & Salvador, A. (2022) · Journal of Separation Science · doi:10.1002/jssc.202100609 · Cited by 131
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Sajid, M. (2022) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2022.116636 · Cited by 125
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Mansour, F. R., Bedair, A., Hamed, M., Magdy, G., Ali, I., & Locatelli, M. (2024) · Microchemical Journal · doi:10.1016/j.microc.2024.110178 · Cited by 107
Green microextraction methodologies for sample preparations
Kokosa, J. M., & Przyjazny, A. (2022) · Green Analytical Chemistry · doi:10.1016/j.greeac.2022.100023 · Cited by 90
Metadata
- Authors
- Pacheco-Fernández, I., González-Martín, R., e Silva, F. A., Freire, M. G., & Pino, V.
- Affiliations
- Universidad de La Laguna (ES)
- University of Aveiro (PT)
- Corresponding author
- Freire, Mara G.
- Pino, Verónica
- Venue
- Analytica Chimica Acta
- Publisher
- Elsevier BV
- Published
- 2021-01
- Volume
- 1143
- Pages
- 225-249
- ISSN
- 0003-2670 (ISSN-L)
- OpenAlex
- W3080922247
- Cited by
- 69
- References
- 278
- Citations by year
- 2026: 3 · 2025: 12 · 2024: 9 · 2023: 18 · 2022: 14 · 2021: 12
- FWCI
- 1.48
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- Analytica Chimica Acta (publishedVersion)
- PubMed (publishedVersion)
- Portuguese National Funding Agency for Science, Research and Technology (RCAAP Project by FCT) (submittedVersion, cc-by-nc-nd)
- Funders
- Ministério da Ciência, Tecnologia e Ensino Superior
- Universidad de La Laguna
- Agencia Canaria de Investigación, Innovación y Sociedad de la Información
- Fundação para a Ciência e a Tecnologia
- Ministerio de Educación, Cultura y Deporte
- European Social Fund
- Ministerio de Economía y Competitividad (MAT2017-89207-R, UIDB/50011/2020, UIDP/50011/2020)
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical Chemistry and Chromatography
- Keywords
- liquid-phase microextraction, dispersive liquid-liquid microextraction, coacervation, surfactants, deep eutectic solvents, ionic liquids, switchable solvents, phase separation mechanism, cloud point extraction, aqueous two-phase systems, salting-out, metathesis, green solvents, extraction efficiency
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