Cited by 69Analytical chemistry methods developmentChemical and Physical Properties in Aqueous SolutionsAnalytical Chemistry and Chromatography

The DOI matches its Crossref record; 277 of the 278 references it cites were found in a registry or an index.

Insights into coacervative and dispersive liquid-phase microextraction strategies with hydrophilic media – A review

Open access

Pacheco-Fernández, Idaira, González-Martín, Raúl, e Silva, Francisca A., Freire, Mara G., Pino, Verónica·2021·Analytica Chimica Acta

DOI 10.1016/j.aca.2020.08.022

Open this paper in CoChat — free account Open PDF

Abstract

Since the development of liquid-phase microextraction (LPME), different LPME modes depending on the experimental set-up to carry out the extraction have been described. Dispersive liquid-liquid microextraction (DLLME), in which a small amount of the water-insoluble extraction solvent is dispersed in the sample, is the most successful mode in terms of number of applications reported. Advances within DLLME have been mainly shifted to the incorporation of green, smart and tunable materials as extraction solvents to improve the sustainability and efficiency of the method. In this sense, hydrophilic media represent a promising alternative since the water-miscibility of these substances increases the mass transfer of the analytes to the extraction media, leading to higher extraction efficiencies. Considering the variety of hydrophilic media that have been incorporated in LPME approaches resembling DLLME, this review aims to classify these methods in order to clarify the confusing terminology used for some of the strategies. Hydrophilic media covered in this review comprise surfactants, polar organic solvents, deep eutectic solvents, ionic liquids, water-miscible polymers, and switchable solvents. Different physicochemical mechanisms of phase separation are discussed for each LPME method, including the coacervation phenomena and other driving forces, such as pH, temperature, salting-out effect, metathesis reaction and organic solvents. LPME modes are classified (in cloud-point extraction, coacervative extraction, aqueous biphasic systems, and different DLLME modes depending on the extraction medium) according to both the nature of the water-miscible extraction phase and the driving force of the separation. In addition, the main advances and analytical applications of these methods in the last three years are described.

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Integrity signals

Registry

Crossref · 10.1016/j.aca.2020.08.022

Cites

277 of 277 references verified0 citation errors · 0 not checkable

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Deep Eutectic Solvents (DESs) and Their Applications
Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378
Determination of organic compounds in water using dispersive liquid–liquid microextraction
Rezaee, M., Assadi, Y., Milani Hosseini, M.-R., Aghaee, E., Ahmadi, F., & Berijani, S. (2006) · Journal of Chromatography A · doi:10.1016/j.chroma.2006.03.007 · Cited by 3,402
Introduction: Ionic Liquids
Lei, Z., Chen, B., Koo, Y.-M., & MacFarlane, D. R. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00246 · Cited by 1,492
Controlling the Aqueous Miscibility of Ionic Liquids: Aqueous Biphasic Systems of Water-Miscible Ionic Liquids and Water-Structuring Salts for Recycle, Metathesis, and Separations
Gutowski, K. E., Broker, G. A., Willauer, H. D., Huddleston, J. G., Swatloski, R. P., Holbrey, J. D., & Rogers, R. D. (2003) · Journal of the American Chemical Society · doi:10.1021/ja0351802 · Cited by 1,038
Reversible nonpolar-to-polar solvent
Jessop, P. G., Heldebrant, D. J., Li, X., Eckert, C. A., & Liotta, C. L. (2005) · Nature · doi:10.1038/4361102a · Cited by 973
Aqueous two-phase system (ATPS): an overview and advances in its applications
Iqbal, M., Tao, Y., Xie, S., Zhu, Y., Chen, D., Wang, X., Huang, L., Peng, D., Sattar, A., Shabbir, M. A. B., et al. (2016) · Biological Procedures Online · doi:10.1186/s12575-016-0048-8 · Cited by 824
Aqueous biphasic systems: a boost brought about by using ionic liquids
Freire, M. G., Cláudio, A. F. M., Araújo, J. M. M., Coutinho, J. A. P., Marrucho, I. M., Lopes, J. N. C., & Rebelo, L. P. N. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35151j · Cited by 820
Self-citation
Extraction techniques with deep eutectic solvents
Cunha, S. C., & Fernandes, J. O. (2018) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2018.05.001 · Cited by 760
DESIGNER SOLVENTS
FREEMANTLE, M. (1998) · Chemical & Engineering News · doi:10.1021/cen-v076n013.p032 · Cited by 754
Complex coacervation: Principles, mechanisms and applications in microencapsulation
Timilsena, Y. P., Akanbi, T. O., Khalid, N., Adhikari, B., & Barrow, C. J. (2018) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2018.10.144 · Cited by 609
Modern approaches in dispersive liquid-liquid microextraction (DLLME) based on ionic liquids: a review
Rykowska, I., Ziemblińska, J., & Nowak, I. (2018) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2018.03.043 · Cited by 353
A solvent having switchable hydrophilicity
Jessop, P. G., Phan, L., Carrier, A. J., Robinson, S., Dürr, C. J., & Harjani, J. R. (2010) · Green Chemistry · doi:10.1039/b926885e · Cited by 329
Recent developments in homogeneous and dispersive liquid–liquid extraction for inorganic elements determination. A review
Anthemidis, A. N., & Ioannou, K.-I. G. (2009) · Talanta · doi:10.1016/j.talanta.2009.09.005 · Cited by 322
Partition of Proteins in Liquid Polymer–Polymer Two-Phase Systems
Albertsson, P. (1958) · Nature · doi:10.1038/182709a0 · Cited by 313
Liquid-phase microextraction – The different principles and configurations
Yamini, Y., Rezazadeh, M., & Seidi, S. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2018.06.010 · Cited by 309
Recent Advances in Hydrophobic Deep Eutectic Solvents for Extraction
Dwamena, A. (2019) · Separations · doi:10.3390/separations6010009 · Cited by 294
Green extraction techniques in green analytical chemistry
Armenta, S., Garrigues, S., Esteve-Turrillas, F. A., & de la Guárdia, M. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.03.016 · Cited by 290
Deep eutectic solvents are not only effective extractants
Shishov, A., Pochivalov, A., Nugbienyo, L., Andruch, V., & Bulatov, A. (2020) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2020.115956 · Cited by 278
Ionic liquids in dispersive liquid-liquid microextraction
Trujillo-Rodríguez, M. J., Rocío-Bautista, P., Pino, V., & Afonso, A. M. (2013) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2013.06.008 · Cited by 276
Self-citation
Deep eutectic solvents as novel extraction media for protein partitioning
Zeng, Q., Wang, Y., Huang, Y., Ding, X., Chen, J., & Xu, K. (2014) · The Analyst · doi:10.1039/c3an02235h · Cited by 263
Green solvents in analytical chemistry
Pacheco‐Fernández, I., & Pino, V. (2019) · Current Opinion in Green and Sustainable Chemistry · doi:10.1016/j.cogsc.2018.12.010 · Cited by 260
Self-citation
Design and evaluation of switchable-hydrophilicity solvents
Vanderveen, J. R., Durelle, J., & Jessop, P. G. (2014) · Green Chem. · doi:10.1039/c3gc42164c · Cited by 251
Advances of ionic liquids in analytical Chemistry
Trujillo-Rodríguez, M. J., Nan, H., Varona, M., Emaus, M. N., Souza, I. D., & Anderson, J. L. (2019) · Analytical Chemistry · doi:10.1021/acs.analchem.8b04710 · Cited by 248
Liquid–phase microextraction: A review of reviews
Rutkowska, M., Płotka-Wasylka, J., Sajid, M., & Andruch, V. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.103989 · Cited by 244
Are Aqueous Biphasic Systems Composed of Deep Eutectic Solvents Ternary or Quaternary Systems?
Passos, H., Tavares, D. J. P., Ferreira, A. M., Freire, M. G., & Coutinho, J. A. P. (2016) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.6b00485 · Cited by 225
Self-citation
Glossary of terms used in extraction (IUPAC Recommendations 2016)
Poole, C. F., Mester, Z., Miró, M., Pedersen‐Bjergaard, S., & Pawliszyn, J. B. (2016) · Pure and Applied Chemistry · doi:10.1515/pac-2015-0903 · Cited by 213
In situ solvent formation microextraction based on ionic liquids: A novel sample preparation technique for determination of inorganic species in saline solutions
Baghdadi, M., & Shemirani, F. (2008) · Analytica Chimica Acta · doi:10.1016/j.aca.2008.12.017 · Cited by 208
Dispersive liquid–liquid microextraction using an in situ metathesis reaction to form an ionic liquid extraction phase for the preconcentration of aromatic compounds from water
Yao, C., & Anderson, J. L. (2009) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-009-3078-0 · Cited by 204
Utilization of deep eutectic solvents in dispersive liquid-liquid micro-extraction
Li, G., & Row, K. H. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.115651 · Cited by 186
Emulsification liquid–liquid microextraction based on deep eutectic solvent: An extraction method for the determination of benzene, toluene, ethylbenzene and seven polycyclic aromatic hydrocarbons from water samples
Khezeli, T., Daneshfar, A., & Sahraei, R. (2015) · Journal of Chromatography A · doi:10.1016/j.chroma.2015.11.007 · Cited by 183
Surfactant-based extraction methods
Yazdi, A. S. (2011) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2011.02.010 · Cited by 172
Vortex assisted deep eutectic solvent (DES)-emulsification liquid-liquid microextraction of trace curcumin in food and herbal tea samples
Aydin, F., Yilmaz, E., & Soylak, M. (2018) · Food Chemistry · doi:10.1016/j.foodchem.2017.09.154 · Cited by 171
Recent advances in dispersive liquid-liquid microextraction for pesticide analysis
Ahmad, W., Al-Sibaai, A. A., Bashammakh, A. S., Alwael, H., & El-Shahawi, M. S. (2015) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2015.04.022 · Cited by 170
Membrane-based microextraction techniques in analytical chemistry: A review
Carasek, E., & Merib, J. D. O. (2015) · Analytica Chimica Acta · doi:10.1016/j.aca.2015.02.049 · Cited by 167
A simple and novel deep eutectic solvent based ultrasound-assisted emulsification liquid phase microextraction method for malachite green in farmed and ornamental aquarium fish water samples
Aydin, F., Yilmaz, E., & Soylak, M. (2017) · Microchemical Journal · doi:10.1016/j.microc.2017.02.014 · Cited by 165
Environment-Responsive Alkanol-Based Supramolecular Solvents: Characterization and Potential as Restricted Access Property and Mixed-Mode Extractants
Ballesteros‐Gómez, A., & Rubio, S. (2011) · Analytical Chemistry · doi:10.1021/ac2026207 · Cited by 164
Water-Induced Coacervation of Alkyl Carboxylic Acid Reverse Micelles: Phenomenon Description and Potential for the Extraction of Organic Compounds
Ruiz, F.-J., Rubio, S., & Pérez‐Bendito, D. (2007) · Analytical Chemistry · doi:10.1021/ac0708644 · Cited by 155
Selecting an extraction solvent for a greener liquid phase microextraction (LPME) mode-based analytical method
Kokosa, J. M. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.05.012 · Cited by 145
Cloud point extraction: A sustainable method of elemental preconcentration and speciation
Samaddar, P., & Sen, K. (2013) · Journal of Industrial and Engineering Chemistry · doi:10.1016/j.jiec.2013.10.033 · Cited by 144
Deep eutectic solvents: designer fluids for chemical processes
Wazeer, I., Hayyan, M., & Hadj-Kali, M. K. (2017) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.5491 · Cited by 143
Use of switchable solvents in the microextraction context
Lasarte‐Aragonés, G., Lucena, R., Cárdenas, S., & Valcárcel, M. (2014) · Talanta · doi:10.1016/j.talanta.2014.08.031 · Cited by 136
In situ ionic liquid dispersive liquid-liquid microextraction coupled to gas chromatography-mass spectrometry for the determination of organophosphorus pesticides
Cacho, J. I., Campillo, N., Viñas, P., & Hernández‐Córdoba, M. (2017) · Journal of Chromatography A · doi:10.1016/j.chroma.2017.12.059 · Cited by 133
Ultrasonic assisted dispersive liquid-liquid microextraction method based on deep eutectic solvent for speciation, preconcentration and determination of selenium species (IV) and (VI) in water and food samples
Panhwar, A. H., Tüzen, M., & Kazi, T. G. (2017) · Talanta · doi:10.1016/j.talanta.2017.07.063 · Cited by 128
A highly selective and sensitive ultrasonic assisted dispersive liquid phase microextraction based on deep eutectic solvent for determination of cadmium in food and water samples prior to electrothermal atomic absorption spectrometry
Zounr, R. A., Tuzen, M., Deligonul, N., & Khuhawar, M. Y. (2018) · Food Chemistry · doi:10.1016/j.foodchem.2018.01.167 · Cited by 127
Air assisted emulsification liquid-liquid microextraction based on deep eutectic solvent for preconcentration of methadone in water and biological samples
Lamei, N., Ezoddin, M., & Abdi, K. (2017) · Talanta · doi:10.1016/j.talanta.2016.11.036 · Cited by 123
Surfactant roles in modern sample preparation techniques: A review
Moradi, M., & Yamini, Y. (2012) · Journal of Separation Science · doi:10.1002/jssc.201200368 · Cited by 120
Application of ionic liquids in microextraction techniques: Current trends and future perspectives
Marcinkowska, R., Konieczna, K., Marcinkowski, Ł., Namieśnik, J., & Kloskowski, A. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.07.025 · Cited by 119
Current applications of different type of aqueous two-phase systems
Yau, Y. K., Ooi, C. W., Ng, E., Lan, J. C., Ling, T. C., & Show, P. L. (2015) · Bioresources and Bioprocessing · doi:10.1186/s40643-015-0078-0 · Cited by 113
Monitoring of some trace metals in honeys by flame atomic absorption spectrometry after ultrasound assisted-dispersive liquid liquid microextraction using natural deep eutectic solvent
Altunay, N., Elik, A., & Gürkan, R. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.03.003 · Cited by 111
Novel, energy efficient and green cloud point extraction: technology and applications in food processing
Arya, S. S., Kaimal, A. M., Chib, M., Sonawane, S. K., & Show, P. L. (2019) · Journal of Food Science and Technology · doi:10.1007/s13197-018-3546-7 · Cited by 109
Theory and recent applications of coacervate-based extraction techniques
Melnyk, A., Namieśnik, J., & Wolska, L. (2015) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2015.03.013 · Cited by 102
A novel and simple deep eutectic solvent based liquid phase microextraction method for rhodamine B in cosmetic products and water samples prior to its spectrophotometric determination
Yılmaz, E., & Soylak, M. (2018) · Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · doi:10.1016/j.saa.2018.04.073 · Cited by 102
A simple and green deep eutectic solvent based air assisted liquid phase microextraction for separation, preconcentration and determination of lead in water and food samples by graphite furnace atomic absorption spectrometry
Zounr, R. A., Tuzen, M., & Khuhawar, M. Y. (2018) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2018.03.034 · Cited by 96
Deep eutectic solvent based advance microextraction method for determination of aluminum in water and food samples: Multivariate study
Panhwar, A. H., Tuzen, M., & Kazi, T. G. (2018) · Talanta · doi:10.1016/j.talanta.2017.09.079 · Cited by 95
An automated homogeneous liquid-liquid microextraction based on deep eutectic solvent for the HPLC-UV determination of caffeine in beverages
Shishov, A., Volodina, N., Nechaeva, D., Gagarinova, S., & Bulatov, A. (2019) · Microchemical Journal · doi:10.1016/j.microc.2018.10.014 · Cited by 90
Combination of sequential cloud point extraction and hydride generation atomic fluorescence spectrometry for preconcentration and determination of inorganic and methyl mercury in water samples
Zheng, H., Hong, J., Luo, X., Li, S., Wang, M., Yang, B., & Wang, M. (2018) · Microchemical Journal · doi:10.1016/j.microc.2018.11.057 · Cited by 89
Switchable solvent based green liquid phase microextraction method for cobalt in tobacco and food samples prior to flame atomic absorption spectrometric determination
Memon, Z. M., Yılmaz, E., & Soylak, M. (2016) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.12.098 · Cited by 85
Biopolymers in sorbent-based microextraction methods
Pacheco‐Fernández, I., Allgaier-Díaz, D. W., Mastellone, G., Cagliero, C., Díaz, D. D., & Pino, V. (2020) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2020.115839 · Cited by 84
Self-citation
Vesicular supramolecular solvent-based microextraction followed by high performance liquid chromatographic analysis of tetracyclines
Gissawong, N., Boonchiangma, S., Mukdasai, S., & Srijaranai, S. (2019) · Talanta · doi:10.1016/j.talanta.2019.03.049 · Cited by 83
The application of an aqueous two-phase system combined with ultrasonic cell disruption extraction and HPLC in the simultaneous separation and analysis of solanine and Solanum nigrum polysaccharide from Solanum nigrum unripe fruit
Zhu, L., Lu, Y., Sun, Z., Han, J., & Tan, Z. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.125383 · Cited by 83
A novel fatty-acid-based in-tube dispersive liquid–liquid microextraction technique for the rapid determination of nonylphenol and 4-tert-octylphenol in aqueous samples using high-performance liquid chromatography–ultraviolet detection
Shih, H.-K., Shu, T.-Y., Ponnusamy, V. K., & Jen, J. (2014) · Analytica Chimica Acta · doi:10.1016/j.aca.2014.11.021 · Cited by 81
In-syringe dispersive liquid-liquid microextraction based on the solidification of ionic liquids for the determination of benzoylurea insecticides in water and tea beverage samples
Wang, H., Hu, L., Li, W., Yang, X., Lu, R., Zhang, S., Zhou, W., Gao, H., & Li, J. (2016) · Talanta · doi:10.1016/j.talanta.2016.10.035 · Cited by 81
pH-mediated dual-cloud point extraction as a preconcentration and clean-up technique for capillary electrophoresis determination of phenol and m-nitrophenol
Wei, W., Yin, X., & He, X. (2008) · Journal of Chromatography A · doi:10.1016/j.chroma.2008.07.015 · Cited by 78
Development of a new pH assisted homogeneous liquid-liquid microextraction by a solvent with switchable hydrophilicity: Application for GC-MS determination of methamphetamine
Shahvandi, S. K., Banitaba, M. H., & Ahmar, H. (2018) · Talanta · doi:10.1016/j.talanta.2018.02.115 · Cited by 76
Development of deep eutectic solvent-based aqueous biphasic system for the extraction of lysozyme
Xu, P., Wang, Y., Chen, J., Wei, X., Xu, W. J., Ni, R., Meng, J., & Zhou, Y. (2019) · Talanta · doi:10.1016/j.talanta.2019.04.053 · Cited by 76
Is It Possible To Create Ternary-like Aqueous Biphasic Systems with Deep Eutectic Solvents?
Farias, F. O., Passos, H., Lima, Á. S., Mafra, M. R., & Coutinho, J. A. P. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b02514 · Cited by 75
Validation of ultrasonic-assisted switchable solvent liquid phase microextraction for trace determination of hormones and organochlorine pesticides by GC–MS and combination with QuEChERS
Durak, B. Y., Chormey, D. S., Fırat, M., & Bakırdere, S. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.125487 · Cited by 75
Rapid and sensitive analysis of polychlorinated biphenyls and acrylamide in food samples using ionic liquid-based in situ dispersive liquid-liquid microextraction coupled to headspace gas chromatography
Zhang, C., Cagliero, C., Pierson, S. A., & Anderson, J. L. (2016) · Journal of Chromatography A · doi:10.1016/j.chroma.2016.12.013 · Cited by 74
Impact of pH and temperature on phase diagrams of different aqueous biphasic systems
Chakraborty, A., & Sen, K. (2016) · Journal of Chromatography A · doi:10.1016/j.chroma.2016.01.016 · Cited by 73
Speciation of mercury in water and biological samples by eco-friendly ultrasound-assisted deep eutectic solvent based on liquid phase microextraction with electrothermal atomic absorption spectrometry
Thongsaw, A., Udnan, Y., Ross, G. M., & Chaiyasith, W. C. (2019) · Talanta · doi:10.1016/j.talanta.2019.01.018 · Cited by 73
Magnetic ionic liquid aqueous two-phase system coupled with high performance liquid chromatography: A rapid approach for determination of chloramphenicol in water environment
Yao, T., & Yao, S. (2016) · Journal of Chromatography A · doi:10.1016/j.chroma.2016.12.039 · Cited by 71
An effervescence tablet-assisted switchable solvent-based microextraction: On-site preconcentration of steroid hormones in water samples followed by HPLC-UV determination
Shishov, A., Sviridov, I., Timofeeva, I., Chibisova, N., Moskvin, L., & Bulatov, A. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.09.120 · Cited by 70
In-situ ionic liquid dispersive liquid-liquid microextraction using a new anion-exchange reagent combined Fe 3 O 4 magnetic nanoparticles for determination of pyrethroid pesticides in water samples
Fan, C., Liang, Y., Dong, H., Ding, G., Zhang, W., Tang, G., Yang, J., Kong, D., Wang, D., & Cao, Y. (2017) · Analytica Chimica Acta · doi:10.1016/j.aca.2017.04.036 · Cited by 69
An effervescence-assisted dispersive liquid–liquid microextraction based on deep eutectic solvent decomposition: Determination of ketoprofen and diclofenac in liver
Shishov, A., Gerasimov, A., Nechaeva, D., Volodina, N., Bessonova, E., & Bulatov, A. (2020) · Microchemical Journal · doi:10.1016/j.microc.2020.104837 · Cited by 69
Microwave-assisted aqueous two-phase extraction coupled with high performance liquid chromatography for simultaneous extraction and determination of four flavonoids in Crotalaria sessiliflora L.
Xie, X., Zhu, D., Zhang, W., Wenbei, H., Wang, K., Huang, X., Zhou, L. M., & Fan, H. (2016) · Industrial Crops and Products · doi:10.1016/j.indcrop.2016.11.032 · Cited by 66
Ultrasonic assisted switchable solvent based on liquid phase microextraction combined with micro sample injection flame atomic absorption spectrometry for determination of some heavy metals in water, urine and tea infusion samples
Habibiyan, A., Ezoddin, M., Lamei, N., Abdi, K., Amini, M., & Ghazi‐Khansari, M. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.07.043 · Cited by 66
Extraction and separation of nickel chelate of 1-(2-thiazolylazo)-2-naphthol in nonionic surfactant solution
Miura, J., ISHII, H., & Watanabe, H. (1976) · BUNSEKI KAGAKU · doi:10.2116/bunsekikagaku.25.808 · Cited by 65
SUPRAS extraction approach for matrix-independent determination of amphetamine-type stimulants by LC-MS/MS
Accioni, F., García‐Gómez, D., Girela-López, E., & Rubio, S. (2018) · Talanta · doi:10.1016/j.talanta.2018.02.039 · Cited by 64
Innovative and practical deep eutectic solvent based vortex assisted microextraction procedure for separation and preconcentration of low levels of arsenic and antimony from sample matrix prior to analysis by hydride generation-atomic absorption spectrometry
Altunay, N., Elık, A., & Gürkan, R. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.05.019 · Cited by 64
Application of ultrasound-assisted cloud point extraction for preconcentration of antimony, tin and thallium in food and water samples prior to ICP-OES determination
Biata, N. R., Mashile, G. P., Ramontja, J., Mketo, N., & Nomngongo, P. N. (2018) · Journal of Food Composition and Analysis · doi:10.1016/j.jfca.2018.11.004 · Cited by 63
Ligandless switchable solvent based liquid phase microextraction of nickel from food and cigarette samples prior to its micro-sampling flame atomic absorption spectrometric determination
Reclo, M., Yilmaz, E., Soylak, M., Andruch, V., & Bazel, Y. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.04.066 · Cited by 62
Determination of Pb in environmental samples after cloud point extraction using crown ether
Blanchet-Chouinard, G., & Larivière, D. (2017) · Talanta · doi:10.1016/j.talanta.2017.11.015 · Cited by 62
In situ formation of hydrophobic magnetic ionic liquids for dispersive liquid-liquid microextraction
Trujillo‐Rodríguez, M. J., & Anderson, J. L. (2018) · Journal of Chromatography A · doi:10.1016/j.chroma.2018.12.032 · Cited by 60
Behavior of Triton X-114 cloud point in the presence of inorganic electrolytes
Santos‐Ebinuma, V. C., Lopes, A. M., Converti, A., Pessoa, A., & Rangel‐Yagui, C. D. O. (2013) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2013.09.053 · Cited by 58
Clear distinction between CAC and CMC revealed by high-resolution NMR diffusometry for a series of bis-imidazolium gemini surfactants in aqueous solutions
Szutkowski, K., Kołodziejska, Ż., Pietralik, Z., Zhukov, I., Skrzypczak, A., Materna, K., & Kozak, M. (2018) · RSC Advances · doi:10.1039/c8ra07081d · Cited by 57
Speciation of inorganic arsenic(III) and arsenic(V) by a facile dual-cloud point extraction coupled with inductively plasma-optical emission spectrometry
Wen, S., & Zhu, X. (2018) · Talanta · doi:10.1016/j.talanta.2017.12.083 · Cited by 56
Aqueous biphasic systems formed by deep eutectic solvent and new-type salts for the high-performance extraction of pigments
Zhang, H., Wang, Y., Zhou, Y., Chen, J., Wei, X., & Xu, P. (2018) · Talanta · doi:10.1016/j.talanta.2018.01.014 · Cited by 56
Extraction of DNA with magnetic ionic liquids using in situ dispersive liquid–liquid microextraction
Bowers, A. N., Trujillo‐Rodríguez, M. J., Farooq, M. Q., & Anderson, J. L. (2019) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-019-02163-9 · Cited by 56
Supramolecular Solvents for Green Chemistry
Caballo, C., Sicilia, M. D., & Rubio, S. (2017) · The Application of Green Solvents in Separation Processes · doi:10.1016/b978-0-12-805297-6.00005-x · Cited by 54
Cloud point extraction for simultaneous determination of 12 phenolic compounds by high performance liquid chromatography with fluorescence detection
Luo, X., Zheng, H., Zhang, Z., Wang, M., Yang, B., Huang, L., & Wang, M. (2017) · Microchemical Journal · doi:10.1016/j.microc.2017.09.026 · Cited by 54
A new portable switchable hydrophilicity microextraction method for determination of vanadium in microsampling micropipette tip syringe system couple with ETAAS
Naeemullah, & Tüzen, M. (2018) · Talanta · doi:10.1016/j.talanta.2018.10.052 · Cited by 54
Dual-cloud point extraction for speciation of mercury in water and fish samples by electrothermal atomic absorption spectrometry
Thongsaw, A., Sananmuang, R., Udnan, Y., Ross, G. M., & Chaiyasith, W. C. (2019) · Spectrochimica Acta Part B Atomic Spectroscopy · doi:10.1016/j.sab.2019.105685 · Cited by 54
Comparison of hydrophilic and hydrophobic deep eutectic solvents for pretreatment determination of sulfonamides from aqueous environments
Ma, Y., Wang, Q., & Zhu, T. (2019) · Analytical Methods · doi:10.1039/c9ay02244a · Cited by 54
Decomposition of deep eutectic solvents based on choline chloride and phenol in aqueous phase
Shishov, A. Y., Gorbunov, A. O., Москвин, Л. Н., & Bulatov, A. V. (2019) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2019.112380 · Cited by 54
An effervescence-assisted switchable fatty acid-based microextraction with solidification of floating organic droplet for determination of fluoroquinolones and tetracyclines in seawater, sediment, and seafood
Gao, M. J., Wang, J., Song, X., He, X., Dahlgren, R. A., Zhang, Z., Ru, S., & Wang, X. (2018) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-018-0942-9 · Cited by 53
Surfactant-mediated microextraction approach using switchable hydrophilicity solvent: HPLC-UV determination of Sudan dyes in solid food samples
Pochivalov, A., Davletbaeva, P., Cherkashina, K., Lezov, A. A., Vakh, C. S., & Bulatov, A. V. (2018) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2018.09.072 · Cited by 53
Cloud point extraction-flame atomic absorption spectrometry for pre-concentration and determination of trace amounts of silver ions in water samples
Yang, X., Jia, Z., Xiaocui, Y., Li, G., & Liao, X. (2017) · Saudi Journal of Biological Sciences · doi:10.1016/j.sjbs.2017.01.030 · Cited by 52
Ultrasound-assisted emulsification liquid phase microextraction method based on deep eutectic solvent as extraction solvent for determination of five pesticides in traditional Chinese medicine
Li, X., Wang, M., Zhao, J., Guo, H., Gao, X., Xiong, Z., & Zhao, L. (2019) · Journal of Pharmaceutical and Biomedical Analysis · doi:10.1016/j.jpba.2019.01.018 · Cited by 52
Switchable Hydrophilicity Solvent-Based Homogenous Liquid–Liquid Microextraction (SHS-HLLME) Combined with GC-FID for the Quantification of Methadone and Tramadol
Ahmar, H., Nejati‐Yazdinejad, M., Najafi, M., & Hasheminasab, K. S. (2018) · Chromatographia · doi:10.1007/s10337-018-3528-y · Cited by 51
Hexafluoroisopropanol/Brij-35 based supramolecular solvent for liquid-phase microextraction of parabens in different matrix samples
Chen, J., Deng, W., Li, X., Wang, X., & Xiao, Y. (2019) · Journal of Chromatography A · doi:10.1016/j.chroma.2019.01.030 · Cited by 51
Determination of Vitamin B12 and cobalt in egg yolk using vortex assisted switchable solvent based liquid phase microextraction prior to slotted quartz tube flame atomic absorption spectrometry
Tekin, Z. H., Erarpat, S., Şahin, A., Chormey, D. S., & Bakırdere, S. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.02.036 · Cited by 51
Switchable‐hydrophilicity solvent‐based microextraction combined with gas chromatography for the determination of nitroaromatic compounds in water samples
Rameshgar, J., Hasheminasab, K. S., Adlnasab, L., & Ahmar, H. (2017) · Journal of Separation Science · doi:10.1002/jssc.201700141 · Cited by 50
Development of different deep eutectic solvent aqueous biphasic systems for the separation of proteins
Meng, J., Wang, Y., Zhou, Y., Chen, J., Wei, X., Ni, R., Liu, Z., & Xu, F. (2019) · RSC Advances · doi:10.1039/c9ra00519f · Cited by 50
Extraction of chromium (VI) in water samples by dispersive liquid–liquid microextraction based on deep eutectic solvent and determination by UV–Vis spectrophotometry
Pourmohammad, M., Faraji, M., & Jafarinejad, S. (2019) · International Journal of Environmental & Analytical Chemistry · doi:10.1080/03067319.2019.1650920 · Cited by 50
A novel, green cloud point extraction and separation of phenols and flavonoids from pomegranate peel: An optimization study using RCCD
More, P. R., & Arya, S. S. (2019) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2019.103306 · Cited by 50
A green cloud-point microextraction method for spectrophotometric determination of Ni(II) ions with 1-[(5-benzyl-1,3-thiazol-2-yl)diazenyl]naphthalene-2-ol
Bazeľ, Y., Tupys, A. M., Ostapiuk, Y. V., Tymoshuk, O. S., & Matiychuk, V. S. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.07.047 · Cited by 49
Selective cloud point extraction of uranium from thorium and lanthanides using Cyanex 301 as extractant
Liang, H., Chen, Q., Xu, C., & Shen, X. (2018) · Separation and Purification Technology · doi:10.1016/j.seppur.2018.08.071 · Cited by 49
Switchable fatty acid based CO2-effervescence ameliorated emulsification microextraction prior to high performance liquid chromatography for efficient analyses of toxic azo dyes in foodstuffs
Hemmati, M., & Rajabi, M. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.01.197 · Cited by 49
An automated in-syringe switchable hydrophilicity solvent-based microextraction
Pochivalov, A., Vakh, C. S., Garmonov, S. Y., Москвин, Л. Н., & Bulatov, A. V. (2019) · Talanta · doi:10.1016/j.talanta.2019.120587 · Cited by 49
A new generation of nano-structured supramolecular solvents based on propanol/gemini surfactant for liquid phase microextraction
Feizi, N., Yamini, Y., Moradi, M., Karimi, M., Salamat, Q., & Amanzadeh, H. (2016) · Analytica Chimica Acta · doi:10.1016/j.aca.2016.11.007 · Cited by 48
Efficient and relatively safe emulsification microextraction using a deep eutectic solvent for influential enrichment of trace main anti-depressant drugs from complicated samples
Moghadam, A. G., Rajabi, M., & Asghari, A. (2017) · Journal of Chromatography B · doi:10.1016/j.jchromb.2017.09.042 · Cited by 48
Switchable-hydrophilicity solvent liquid–liquid microextraction of non-steroidal anti-inflammatory drugs from biological fluids prior to HPLC-DAD determination
Hassan, M., & Alshana, U. (2019) · Journal of Pharmaceutical and Biomedical Analysis · doi:10.1016/j.jpba.2019.06.023 · Cited by 48
Development of CO2-Mediated Switchable Hydrophilicity Solvent-Based Microextraction Combined with HPLC-UV for the Determination of Bisphenols in Foods and Drinks
Wang, X., Gao, M. J., Zhang, Z., Gu, H., Liu, T., Yu, N., Wang, X., & Wang, H. (2018) · Food Analytical Methods · doi:10.1007/s12161-018-1187-0 · Cited by 47
Ultrasound-Assisted Switchable Solvent in Determination of Quaternary Ammonium Herbicide Paraquat in Biological, Environmental Water, and Apple Juice Samples Using Chemical Reduction Process Coupled to GC–MS Detection
Lamei, N., Ezoddin, M., Kakavandi, N. R., Abdi, K., & Ghazi‐Khansari, M. (2018) · Chromatographia · doi:10.1007/s10337-018-3500-x · Cited by 47
Solid-phase extraction coupled with switchable hydrophilicity solvent-based homogeneous liquid–liquid microextraction for chloramphenicol enrichment in environmental water samples: a novel alternative to classical extraction techniques
Di, X., Wang, X., Liu, Y., Guo, X., & Di, X. (2018) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-018-1486-8 · Cited by 47
An environmentally friendly method based on micro-cloud point extraction for determination of trace amount of quercetin in food and fruit juice samples
Khani, R., Sheykhi, R., & Bagherzade, G. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.04.099 · Cited by 46
Emulsification liquid–liquid microextraction based on deep eutectic solvents: an extraction method for the determination of sulfonamides in water samples
Liu, L., & Zhu, T. (2017) · Analytical Methods · doi:10.1039/c7ay01332a · Cited by 45
Salicylic acid assisted cloud point extraction at room temperature: Application for preconcentration and spectrophotometric determination of molybdenum(VI)
Snigur, D. V., Чеботарев, А. Н., Dubovyi, V., Barbalat, D., & Bevziuk, K. (2018) · Microchemical Journal · doi:10.1016/j.microc.2018.07.010 · Cited by 45
Electrochemical determination of nitrazepam by switchable solvent based liquid-liquid microextraction combined with differential pulse voltammetry
Shahraki, S., Ahmar, H., & Nejati‐Yazdinejad, M. (2018) · Microchemical Journal · doi:10.1016/j.microc.2018.07.003 · Cited by 44
A simple methodology based on cloud point extraction prior to HPLC-PDA analysis for tetracycline residues in food samples
Saridal, K., & Ulusoy, H. İ. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.104170 · Cited by 44
Simultaneous separation, concentration and determination of trace fluoroquinolone antibiotics in environmental samples using a polymer aqueous two‐phase system coupled with HPLC
Sun, Z., Lu, Y., Zhu, L., Liu, W., Qu, Y., Nan, L., & Yu, P. (2019) · Journal of Chemical Technology & Biotechnology · doi:10.1002/jctb.6095 · Cited by 43
Enantioseparation and determination of triazole fungicides in vegetables and fruits by aqueous two-phase extraction coupled with online heart-cutting two-dimensional liquid chromatography
Zeng, H., Xie, X., Huang, Y., Chen, J., Liu, Y., Zhang, Y., Mai, X., Deng, J., Fan, H., & Zhang, W. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.125265 · Cited by 42
Determination of common ginsenosides in Kang'ai injection by aqueous two-phase extraction with deep eutectic solvents and HPLC-UV/DAD
Li, P., Zhao, P., Liu, W.-J., Jiang, Y.-F., Wang, W.-J., Bao, L.-Y., Jin, Y., & Li, X.-W. (2018) · Microchemical Journal · doi:10.1016/j.microc.2017.11.007 · Cited by 41
In situ generation of hydrophobic magnetic ionic liquids in stir bar dispersive liquid-liquid microextraction coupled with headspace gas chromatography
Trujillo‐Rodríguez, M. J., & Anderson, J. L. (2018) · Talanta · doi:10.1016/j.talanta.2018.12.071 · Cited by 41
Partitioning of cefazolin in aqueous two-phase systems containing poly (ethylene glycol) and sodium salts (citrate, tartrate, and sulphate)
Ghaffari, S., Shahrouzi, J. R., Towfighi, F., & Khoshfetrat, A. B. (2019) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2019.01.010 · Cited by 41
Flow method based on liquid-liquid extraction using deep eutectic solvent for the spectrofluorimetric determination of procainamide in human saliva
Nugbienyo, L., Shishov, A., Garmonov, S., Moskvin, L., Andruch, V., & Bulatov, A. (2017) · Talanta · doi:10.1016/j.talanta.2017.03.057 · Cited by 40
Cloud point microextraction involving graphene oxide for the speciation of very low amounts of chromium in waters
López‐García, I., Muñoz-Sandoval, M. J., & Hernández‐Córdoba, M. (2017) · Talanta · doi:10.1016/j.talanta.2017.05.017 · Cited by 40
Indirect spectrophotometric determination of sulfadiazine based on localized surface plasmon resonance peak of silver nanoparticles after cloud point extraction
Kazemi, E., Dadfarnia, S., Shabani, A. M. H., Fattahi, M. R., & Khodaveisi, J. (2017) · Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · doi:10.1016/j.saa.2017.06.023 · Cited by 40
Determination of Zinc, Copper, and Mercury in Water Samples by Using Novel Micro Cloud Point Extraction and UV-Vis Spectrophotometry
Ghasemi, E., & Kaykhaii, M. (2016) · Eurasian Journal of Analytical Chemistry · doi:10.12973/ejac.2017.00172a · Cited by 40
Determination of Trace Nickel in Water Samples by Graphite Furnace Atomic Absorption Spectrometry after Mixed Micelle-Mediated Cloud Point Extraction
Han, Q., Huo, Y., Long-hu, Y., Yang, X., He, Y., & Wu, J. (2018) · Molecules · doi:10.3390/molecules23102597 · Cited by 40
Stir membrane liquid phase microextraction of tetracyclines using switchable hydrophilicity solvents followed by high-performance liquid chromatography
Андреевна, Л. С., Vakh, C. S., Cherkashina, K., Pochivalov, A., Москвин, Л. Н., & Bulatov, A. V. (2019) · Journal of Chromatography A · doi:10.1016/j.chroma.2019.460743 · Cited by 40
Cloud point extraction and diffuse reflectance-Fourier transform infrared spectroscopic determination of chromium(VI): A probe to adulteration in food stuffs
Tiwari, S., Deb, M. K., & Sen, B. K. (2016) · Food Chemistry · doi:10.1016/j.foodchem.2016.10.034 · Cited by 39
Efficient method for determination of methylene blue dye in water samples based on a combined dispersive solid phase and cloud point extraction using Cu(OH)2 nanoflakes: central composite design optimization
Nekouei, F., Kargarzadeh, H., Nekouei, S., Keshtpour, F., & Hamdy, A. S. (2016) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-016-0026-7 · Cited by 39
Guanidinium ionic liquid-based surfactants as low cytotoxic extractants: Analytical performance in an in-situ dispersive liquid–liquid microextraction method for determining personal care products
Pacheco‐Fernández, I., Pino, V., Ayala, J. H., & Afonso, A. M. (2017) · Journal of Chromatography A · doi:10.1016/j.chroma.2017.04.061 · Cited by 39
Self-citation
Development of supramolecular solvent based microextraction prior to high performance liquid chromatography for simultaneous determination of phenols in environmental water
Seebunrueng, K., Dejchaiwatana, C., Santaladchaiyakit, Y., & Srijaranai, S. (2017) · RSC Adv. · doi:10.1039/c7ra07780g · Cited by 39 · cited 4×
“reported a coprecipitation-assisted CAE using Al2(SO4)3 as precursor of the coprecipitation agent for SDS [99], while AlCl3 has also been used to promote the coacervation in a mixed-micellar medium composed of SDS and tetrabutylammonium bromide (TBAB) [102].”
MethodInfluential
Simultaneous Determination of Fluoxetine, Estrone, Pesticides, and Endocrine Disruptors in Wastewater by Gas Chromatography–Mass Spectrometry (GC–MS) Following Switchable Solvent–Liquid Phase Microextraction (SS–LPME)
Erarpat, S., Çağlak, A., Bodur, S., Chormey, D. S., Engin, G. Ö., & Bakırdere, S. (2018) · Analytical Letters · doi:10.1080/00032719.2018.1505897 · Cited by 39
Novelty aqueous two-phase extraction system based on ionic liquid for determination of sulfonamides in blood coupled with high-performance liquid chromatography
Yu, W., Li, K., Liu, Z., Zhang, H., & Jin, X. (2017) · Microchemical Journal · doi:10.1016/j.microc.2017.03.053 · Cited by 38
Accurate and sensitive determination of selected hormones, endocrine disruptors, and pesticides by gas chromatography–mass spectrometry after the multivariate optimization of switchable solvent liquid‐phase microextraction
Chormey, D. S., Bodur, S., Baskın, D., Fırat, M., & Bakırdere, S. (2018) · Journal of Separation Science · doi:10.1002/jssc.201800223 · Cited by 38
Utility of ultrasound assisted-cloud point extraction and spectophotometry as a preconcentration and determination tool for the sensitive quantification of mercury species in fish samples
Altunay, N. (2017) · Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · doi:10.1016/j.saa.2017.08.033 · Cited by 37
Hexafluoroisopropanol-induced salt-free catanionic surfactant coacervate extraction method for determination of fluoroquinolones in milk samples
Xu, J. L., Li, X., Li, C., Chen, J., & Xiao, Y. (2017) · Food Chemistry · doi:10.1016/j.foodchem.2017.09.030 · Cited by 37
Simultaneous determination of dexamethasone and moxifloxacin in pharmaceutical formulations using stability indicating HPLC method
Razzaq, S. N., Ashfaq, M. A., Khan, I. U., Mariam, I., Razzaq, S. S., & Azeem, W. (2014) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2014.11.016 · Cited by 36
Pre-concentration and speciation of inorganic antimony in bottled water and natural water by cloud point extraction with Electrothermal Atomic Absorption Spectrometry
de Andrade, J. K., de Andrade, C. K., Felsner, M. L., Quináia, S. P., & dos Anjos, V. E. (2017) · Microchemical Journal · doi:10.1016/j.microc.2017.03.043 · Cited by 36
Indirect determination of the flavor enhancer maltol in foods and beverages through flame atomic absorption spectrometry after ultrasound assisted-cloud point extraction
Altunay, N., Gürkan, R., & Orhan, U. (2017) · Food Chemistry · doi:10.1016/j.foodchem.2017.05.066 · Cited by 36
Fluorescence detection of vitamin B12 in human plasma and urine samples using silver nanoparticles embedded in chitosan in micellar media
Pourreza, N., Mirzajani, R., & Burromandpiroze, J. (2017) · Analytical Methods · doi:10.1039/c7ay01297g · Cited by 36
Application of integrative cloud point extraction and concentration for the analysis of polyphenols and alkaloids in mulberry leaves
Guo, N., Jiang, Y., Kou, P., Liu, Z., Efferth, T., Li, Y.-Y., & Fu, Y. (2019) · Journal of Pharmaceutical and Biomedical Analysis · doi:10.1016/j.jpba.2019.02.002 · Cited by 36
Determination of total selenium in food samples by d-CPE and HG-AFS
Wang, M., Zhong, Y., Qin, J., Zhang, Z., Li, S., & Yang, B. (2016) · Food Chemistry · doi:10.1016/j.foodchem.2016.11.096 · Cited by 35
Choline derivative ionic liquids-based aqueous two-phase systems: Phase diagrams and partition of purine alkaloids
Jiao, R., Li, Z., Liu, J., Pei, Y., Wang, H., & Wang, J. (2017) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2017.10.017 · Cited by 35
Development of spectrophotometric method for iron determination in fortified wheat and maize flours
Silva, A. F. D. O. E., de Castro, W. V., & de Andrade, F. P. (2017) · Food Chemistry · doi:10.1016/j.foodchem.2017.08.110 · Cited by 34
Novel generation of nano-structured supramolecular solvents based on an ionic liquid as a green solvent for microextraction of some synthetic food dyes
Salamat, Q., Yamini, Y., Moradi, M., Karimi, M., & Nazraz, M. (2018) · New Journal of Chemistry · doi:10.1039/c8nj03943g · Cited by 34
Supramolecular solvents formation in aqueous solutions containing primary amine and monoterpenoid compound: Liquid phase microextraction of sulfonamides
Bogdanova, P., Pochivalov, A., Vakh, C. S., & Bulatov, A. V. (2020) · Talanta · doi:10.1016/j.talanta.2020.120992 · Cited by 34
Novel ultrasonic‐assisted deep eutectic solvent‐based dispersive liquid–liquid microextraction for determination of vanadium in food samples by electrothermal atomic absorption spectrometry: A multivariate study
Zounr, R. A., Tüzen, M., & Khuhawar, M. Y. (2017) · Applied Organometallic Chemistry · doi:10.1002/aoc.4144 · Cited by 33
Determination of silver nanoparticles in complex aqueous matrices by total reflection X-ray fluorescence spectrometry combined with cloud point extraction
Torrent, L., Iglesías, M., Hidalgo, M., & Marguí, E. (2017) · Journal of Analytical Atomic Spectrometry · doi:10.1039/c7ja00335h · Cited by 33
Vortex-assisted switchable liquid-liquid microextraction for the preconcentration of cadmium in environmental samples prior to its determination with flame atomic absorption spectrometry
Fırat, M., Bodur, S., Tışlı, B., Özlü, C., Chormey, D. S., Turak, F., & Bakırdere, S. (2018) · Environmental Monitoring and Assessment · doi:10.1007/s10661-018-6786-0 · Cited by 33
Performance Evaluation and Thermodynamic Studies for the Simultaneous Cloud Point Extraction of Erythrosine and Tartrazine Using Mixed Micelles in Food Samples
Nambiar, A. P., Sanyal, M., & Shrivastav, P. S. (2017) · Food Analytical Methods · doi:10.1007/s12161-017-0923-1 · Cited by 32
Determination of triazine herbicides in juice samples by microwave‐assisted ionic liquid/ionic liquid dispersive liquid–liquid microextraction coupled with high‐performance liquid chromatography
Su, R., Li, D., Wu, L., Han, J., Lian, W., Wang, K., & Yang, H. (2017) · Journal of Separation Science · doi:10.1002/jssc.201700270 · Cited by 32
Simultaneous extraction of pesticides of different polarity applying aqueous biphasic systems based on ionic liquids
Dimitrijević, A., Ignjatović, L. M., Tot, A. S., Vraneš, M., Zec, N., Gadžurić, S. B., & Trtić‐Petrović, T. M. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.08.077 · Cited by 32
Improved monitoring of aqueous samples by the preconcentration of active pharmaceutical ingredients using ionic-liquid-based systems
Almeida, H. F. D., Freire, M. G., & Marrucho, I. M. (2017) · Green Chemistry · doi:10.1039/c7gc01954h · Cited by 32
Self-citation
Development of a novel acidic task-specific ionic liquid-based effervescence-assisted microextraction method for determination of triazine herbicides in tea beverage
Piao, H., Jiang, Y., Qin, Z., Tao, S., Ma, P., Sun, Y. X., Wang, X., & Song, D. (2019) · Talanta · doi:10.1016/j.talanta.2019.120414 · Cited by 32
A novel temperature controlled switchable solvent based microextraction method: Application for the determination of phthalic acid esters in water samples
Shahvandi, S. K., Banitaba, M. H., Ahmar, H., & Karimi, P. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.104300 · Cited by 32
Simultaneous extraction and concentration of water pollution tracers using ionic-liquid-based systems
Dinis, T. B. V., Passos, H., Lima, D. L. D., Sousa, A. C. A., Coutinho, J. A. P., Esteves, V. I., & Freire, M. G. (2017) · Journal of Chromatography A · doi:10.1016/j.chroma.2017.07.084 · Cited by 31
Self-citation
A green ultrasonic-assisted liquid–liquid microextraction technique based on deep eutectic solvents for flame atomic absorption spectrometer determination of trace level of lead in tobacco and food samples
Memon, Z. M., Yılmaz, E., Shah, A. M., Kazi, T. G., Devrajani, B. R., & Soylak, M. (2018) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-018-1547-0 · Cited by 31
Natural deep eutectic solvent-based ultrasound-assisted-microextraction for extraction, pre-concentration and analysis of methylmercury and total mercury in fish and environmental waters by spectrophotometry
Altunay, N., Elık, A., & Gürkan, R. (2019) · Food Additives & Contaminants Part A · doi:10.1080/19440049.2019.1619939 · Cited by 31
Developing a new and simple natural deep eutectic solvent based ultrasonic-assisted microextraction procedure for determination and preconcentration of As and Se from rice samples
Elık, A., Demirbaş, A., & Altunay, N. (2019) · Analytical Methods · doi:10.1039/c9ay00916g · Cited by 31
Determination of endocrine disruptive phenolic compounds by gas chromatography mass spectrometry after multivariate optimization of switchable liquid-liquid microextraction and assessment of green profile
Karayaka, S., Chormey, D. S., Fırat, M., & Bakırdere, S. (2019) · Chemosphere · doi:10.1016/j.chemosphere.2019.06.079 · Cited by 31
Air-Agitated Cloud-Point Extraction Coupled with High-Performance Liquid Chromatography for Determination of Heterocyclic Aromatic Amines in Smoked Sausages
Vichapong, J., Burakham, R., & Srijaranai, S. (2016) · Food Analytical Methods · doi:10.1007/s12161-016-0733-x · Cited by 30
Rapid determination of alkaloids in Macleaya cordata using ionic liquid extraction followed by multiple reaction monitoring UPLC–MS/MS analysis
Li, L., Huang, M., Shao, J., Lin, B., & Shen, Q. (2016) · Journal of Pharmaceutical and Biomedical Analysis · doi:10.1016/j.jpba.2016.12.016 · Cited by 30
Graphite furnace atomic absorption spectrometric determination of vanadium after cloud point extraction in the presence of graphene oxide
López‐García, I., Marı́n-Hernández, J. J., & Hernández‐Córdoba, M. (2018) · Spectrochimica Acta Part B Atomic Spectroscopy · doi:10.1016/j.sab.2018.02.013 · Cited by 29
Simultaneous determination of silver and gold nanoparticles by cloud point extraction and total reflection X-ray fluorescence analysis
Bahadır, Z., Torrent, L., Hidalgo, M., & Marguí, E. (2018) · Spectrochimica Acta Part B Atomic Spectroscopy · doi:10.1016/j.sab.2018.07.016 · Cited by 29
Development of a Liquid–Liquid Microextraction Method Based on a Switchable Hydrophilicity Solvent for the Simultaneous Determination of 11 Drugs in Urine by GC–MS
Xu, F., Li, Q., Wei, W., Liu, L., & Li, H. (2018) · Chromatographia · doi:10.1007/s10337-018-3643-9 · Cited by 29
A sensitive and selective deep eutectic solvent-based ultrasound-assisted liquid phase microextraction procedure for separation-preconcentration and determination of copper in olive oil and water samples
Menghwar, P., Yılmaz, E., Sherazi, S. T. H., & Soylak, M. (2018) · Separation Science and Technology · doi:10.1080/01496395.2018.1547317 · Cited by 29
Green Choline Amino Acid Ionic Liquid Aqueous Two-Phase Extraction Coupled with HPLC for Analysis Sunset Yellow in Beverages
Li, Q., Liu, W., & Zhu, X. (2019) · Food Analytical Methods · doi:10.1007/s12161-019-01603-7 · Cited by 29
In situ solvent formation microextraction combined with magnetic dispersive micro‐solid‐phase extraction for the determination of benzoylurea insecticides in water samples
Zhang, Y., Yang, X., Wang, J., Zhou, W., Lu, R., Gao, H., & Zhang, S. (2016) · Journal of Separation Science · doi:10.1002/jssc.201600787 · Cited by 28
Salt-induced ionic liquid-based microextraction using a low cytotoxic guanidinium ionic liquid and liquid chromatography with fluorescence detection to determine monohydroxylated polycyclic aromatic hydrocarbons in urine
Pacheco‐Fernández, I., Pino, V., Lorenzo‐Morales, J., Ayala, J. H., & Afonso, A. M. (2018) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-018-0946-5 · Cited by 28
Self-citation
Non-aqueous phase cold vapor generation and determination of trace cadmium by atomic fluorescence spectrometry
Lei, Z., Chen, L., Hu, K., Yang, S., & Wen, X. (2018) · Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · doi:10.1016/j.saa.2018.06.020 · Cited by 28
An accurate determination method for cobalt in sage tea and cobalamin: Slotted quartz tube-flame atomic absorption spectrometry after preconcentration with switchable liquid-liquid microextraction using a Schiff base
Yazıcı, E., Fırat, M., Chormey, D. S., Bakırdere, E. G., & Bakırdere, S. (2019) · Food Chemistry · doi:10.1016/j.foodchem.2019.125336 · Cited by 27
Hexafluoroisopropanol-mediated cloud point extraction of organic pollutants in water with analysis by high-performance liquid chromatography
Xu, J. L., Li, Y., Li, C., Zhang, R., & Xiao, Y. (2017) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-017-0394-7 · Cited by 26
A simple method for point-of-need extraction, concentration and rapid multi-mycotoxin immunodetection in feeds using aqueous two-phase systems
Soares, R. R. G., Azevedo, A. M., Fernandes, P. C. D. B., Chu, V., Conde, J. P., & Aires-Barros, M. R. (2017) · Journal of Chromatography A · doi:10.1016/j.chroma.2017.07.004 · Cited by 26
The aqueous biphasic system based on cholinium ionic liquids and nonionic surfactant and its application for triazine-based herbicides extraction
Tian, H., Xu, C., Cai, J., & Xu, J. M. (2018) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2018.05.010 · Cited by 26
A Simple Pre-concentration Method for the Determination of Nickel(II) in Urine Samples Using UV-Vis Spectrophotometry and Flame Atomic Absorption Spectrometry Techniques
Khudhair, A. F., Hassan, M. K., Alesary, H. F., & Abbas, A. S. (2019) · Indonesian Journal of Chemistry · doi:10.22146/ijc.35681 · Cited by 26
Simultaneous concentration and chromatographic detection of water pesticides traces using aqueous two-phase system composed of tetrahydrofuran and fructose
Buarque, F. S., Soares, C. M. F., Marques, M. N., de Miranda, R. D. C. M., Cavalcanti, E. B., de Souza, R. L., & Lima, Á. S. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.03.033 · Cited by 26
Combination of cloud point extraction with single particle inductively coupled plasma mass spectrometry to characterize silver nanoparticles in soil leachates
Torrent, L., Laborda, F., Marguí, E., Hidalgo, M., & Iglesías, M. (2019) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-019-01914-y · Cited by 26
Dual-cloud point extraction coupled to high performance liquid chromatography for simultaneous determination of trace sulfonamide antimicrobials in urine and water samples
Nong, C., Niu, Z., Li, P., Wang, C., Li, W., & Wen, Y. (2017) · Journal of Chromatography B · doi:10.1016/j.jchromb.2017.02.031 · Cited by 25
Switchable solvent based liquid phase microextraction of palladium coupled with determination by flame atomic absorption spectrometry
Rečlo, M., Yılmaz, E., Bazeľ, Y., & Soylak, M. (2017) · International Journal of Environmental & Analytical Chemistry · doi:10.1080/03067319.2017.1413185 · Cited by 25
Synthesis and application of imidazolium-based ionic liquids as extraction solvent for pretreatment of triazole fungicides in water samples
Yang, J., Fan, C., Kong, D., Tang, G., Zhang, W., Dong, H., Liang, Y., Wang, D., & Cao, Y. (2018) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-017-0820-x · Cited by 25
Speciation and Determination of Low Concentration of Iron in Beer Samples by Cloud Point Extraction
Khalafi, L., Doolittle, P. S., & Wright, J. C. (2018) · Journal of Chemical Education · doi:10.1021/acs.jchemed.7b00544 · Cited by 25
Centrifugation free and air-assisted liquid-liquid microextraction based on deep eutectic solvent for determination of rare ginsenosides in Kang'ai injection
Li, P., Ye, J., Zhang, Y., Wang, Z., Ren, S., Li, X., & Jin, Y. (2018) · Microchemical Journal · doi:10.1016/j.microc.2018.07.012 · Cited by 25
A rapid synergistic cloud point extraction for nine alkylphenols in water using high performance liquid chromatography and fluorescence detection
Luo, X., Hong, J., Zheng, H., Qin, J., Wang, M., & Yang, B. (2019) · Journal of Chromatography A · doi:10.1016/j.chroma.2019.460606 · Cited by 25
Development of an in situ solvent formation microextraction and preconcentration method based on ionic liquids for the determination of trace cobalt (II) in water samples by flame atomic absorption spectrometry
Jamali, M. R., Soleimani, B., Rahnama, R., & Rahimi, S. H. A. (2012) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2012.08.004 · Cited by 24
Combination of in situ metathesis reaction with a novel “magnetic effervescent tablet-assisted ionic liquid dispersive microextraction” for the determination of endogenous steroids in human fluids
Wu, J., Xu, Z., Pan, Y., Shi, Y. F., Bao, X., Li, J., Yu, T., Tang, H., Ma, S., Wang, X., et al. (2018) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-018-0973-2 · Cited by 24
Application of switchable solvent-based liquid phase microextraction for preconcentration and trace detection of cadmium ions in baby food samples
Vessally, E., Kalhor, E. G., Hosseinzadeh‐Khanmiri, R., Babazadeh, M., Hosseinian, A., Omidi, F., & Ebrahimi, M. H. (2017) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-017-1249-z · Cited by 23
Determination of 4‐Nitrobenzaldehyde in Water Samples by Combination of Switchable Solvent Based Microextraction and Electrochemical Detection on MWCNTs Modified Electrode
Ahmar, H., & Shahvandi, S. K. (2019) · Electroanalysis · doi:10.1002/elan.201800451 · Cited by 23
Accurate and Sensitive Determination Method for Procymidone and Chlorflurenol in Municipal Wastewater, Medical Wastewater and Irrigation Canal Water by GC–MS After Vortex Assisted Switchable Solvent Liquid Phase Microextraction
Kapukıran, F., Fırat, M., Chormey, D. S., Bakırdere, S., & Özdoğan, N. (2019) · Bulletin of Environmental Contamination and Toxicology · doi:10.1007/s00128-019-02618-w · Cited by 23
A new ion-pair ultrasound assisted-cloud point extraction approach for determination of trace V(V) and V(IV) in edible vegetal oils and vinegar by spectrophotometry
Temel, N. K., Kuş, B., & Gürkan, R. (2019) · Microchemical Journal · doi:10.1016/j.microc.2019.104139 · Cited by 23
Coprecipitation‐assisted coacervative extraction coupled to high‐performance liquid chromatography: An approach for determining organophosphorus pesticides in water samples
Mammana, S. B., Bertón, P., Camargo, A. B., Lascalea, G. E., & Altamirano, J. C. (2017) · Electrophoresis · doi:10.1002/elps.201600335 · Cited by 22
New sample preparation method based on task-specific ionic liquids for extraction and determination of copper in urine and wastewater
Trtić-Petrović, T., Dimitrijević, A., Zdolšek, N., Đorđević, J., Tot, A., Vraneš, M., & Gadžurić, S. (2018) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-017-0705-z · Cited by 22
Determination of Tetracyclines in Milk, Eggs and Honey Using in-situ Ionic Liquid Based Dispersive Liquid–Liquid Microextraction
Kaynaker, M., Antep, M., & Merdıvan, M. (2018) · Journal of Analytical Chemistry · doi:10.1134/s1061934818010070 · Cited by 22
Separation, Preconcentration and Spectrophotometric Determination of Rhodamine B in Industrial, Cosmetic and Water Samples by Cloud Point and Solid Phase Extraction
Bişgin, A. T., Sürme, Y., Uçan, M., & Narin, İ. (2018) · Journal of Analytical Chemistry · doi:10.1134/s1061934818050040 · Cited by 22
Ultrasound assisted deep eutectic solvent based microextraction-slotted quartz tube-flame atomic absorption spectrometry for the determination of cadmium
Gösterişli, T. U., Tışlı, B., Tekin, Z. H., Çetin, G., & Bakırdere, S. (2019) · Spectrochimica Acta Part B Atomic Spectroscopy · doi:10.1016/j.sab.2019.03.001 · Cited by 22
Development of a New Methodology for Determination of Vitamin B9 at Trace Levels by Ultrasonic-Assisted Cloud Point Extraction Prior to HPLC
Ulusoy, H. İ., Acıdereli, H., Ulusoy, S., & Erdoğan, S. (2016) · Food Analytical Methods · doi:10.1007/s12161-016-0647-7 · Cited by 21
Sensitive quantification of uranium using cloud point extraction coupled with inductively coupled plasma-optical emission spectrometry
Akl, Z. F. (2017) · Journal of Radioanalytical and Nuclear Chemistry · doi:10.1007/s10967-017-5642-y · Cited by 21

Sorted by citations

A tool to assess analytical sample preparation procedures: Sample preparation metric of sustainability
González-Martín, R., Gutiérrez‐Serpa, A., Pino, V., & Sajid, M. (2023) · Journal of Chromatography A · doi:10.1016/j.chroma.2023.464291 · Cited by 288
Self-citation
Use of green alternative solvents in dispersive liquid‐liquid microextraction: A review
Grau, J., Azorín, C., Benedé, J. L., Chisvert, A., & Salvador, A. (2022) · Journal of Separation Science · doi:10.1002/jssc.202100609 · Cited by 131
Dispersive liquid-liquid microextraction: Evolution in design, application areas, and green aspects
Sajid, M. (2022) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2022.116636 · Cited by 125
Applications of (natural) deep eutectic solvents in liquid phase microextraction: A review
Mansour, F. R., Bedair, A., Hamed, M., Magdy, G., Ali, I., & Locatelli, M. (2024) · Microchemical Journal · doi:10.1016/j.microc.2024.110178 · Cited by 107
Green microextraction methodologies for sample preparations
Kokosa, J. M., & Przyjazny, A. (2022) · Green Analytical Chemistry · doi:10.1016/j.greeac.2022.100023 · Cited by 90

See all 69

Authors: Pacheco-Fernández, I., González-Martín, R., e Silva, F. A., Freire, M. G., & Pino, V.
Affiliations: Universidad de La Laguna (ES)
University of Aveiro (PT)
Corresponding author: Freire, Mara G.
Pino, Verónica
ORCID: González-Martín, Raúl
Freire, Mara G.
Pino, Verónica
Venue: Analytica Chimica Acta
Publisher: Elsevier BV
Published: 2021-01
Volume: 1143
Pages: 225-249
ISSN: 0003-2670 (ISSN-L)
DOI: 10.1016/j.aca.2020.08.022
OpenAlex: W3080922247
Cited by: 69
References: 278
Citations by year: 2026: 3 · 2025: 12 · 2024: 9 · 2023: 18 · 2022: 14 · 2021: 12
FWCI: 1.48
Type: journal article
Language: en
Open access: green
hdl.handle.net
Licence: cc-by-nc-nd
www.elsevier.com/tdm/userlicense/1.0/ (tdm)
www.elsevier.com/legal/tdmrep-license (tdm)
Locations: Analytica Chimica Acta (publishedVersion)
PubMed (publishedVersion)
Portuguese National Funding Agency for Science, Research and Technology (RCAAP Project by FCT) (submittedVersion, cc-by-nc-nd)
Funders: Ministério da Ciência, Tecnologia e Ensino Superior
Universidad de La Laguna
Agencia Canaria de Investigación, Innovación y Sociedad de la Información
Fundação para a Ciência e a Tecnologia
Ministerio de Educación, Cultura y Deporte
European Social Fund
Ministerio de Economía y Competitividad (MAT2017-89207-R, UIDB/50011/2020, UIDP/50011/2020)
Topics: Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
Physical Sciences › Chemistry › Analytical Chemistry › Analytical Chemistry and Chromatography
Keywords: liquid-phase microextraction, dispersive liquid-liquid microextraction, coacervation, surfactants, deep eutectic solvents, ionic liquids, switchable solvents, phase separation mechanism, cloud point extraction, aqueous two-phase systems, salting-out, metathesis, green solvents, extraction efficiency

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Insights into coacervative and dispersive liquid-phase microextraction strategies with hydrophilic media – A review

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Self-check

Citations

Cites

Cited by

Related

Metadata

Record

About these checks