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Synergistic coupling of CoFe-LDH arrays with NiFe-LDH nanosheet for highly efficient overall water splitting in alkaline media

Yang, Rong, Zhou, Yimeng, Xing, Yingying, Li, Di, Jiang, Deli, Chen, Min, Shi, Weidong, Yuan, Shouqi·2019·Applied Catalysis B: Environmental

Abstract

Abstract Developing active, stable and cost-effective bifunctional electrocatalysts with earth-abundant metals (Ni, Fe, Co) is a prerequisite to achieve overall water splitting. In this work, a novel CoFe-layered double hydroxide (LDH) coupled with NiFe-LDH nanosheet array supported on nickel foam (denoted as CoFe@NiFe/NF) is developed through a facile hydrothermal and electrodeposition method. Remarkably, benefiting from strong synergistic effect between CoFe-LDH and NiFe-LDH and the unique structural features, the resulting CoFe@NiFe/NF architectures catalyst exhibits excellent activities and stabilities for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Furthermore, an efficient and stable alkali-electrolyzer using CoFe@NiFe/NF as both the cathode and anode achieve a voltage of 1.59 V at the current density of 10 mA cm−2, which is superior to many other state-of-the-art earth-abundant electrocatalysts. This work provides a facile method for enhancing the electrocatalytic activity by constructing hierarchical core-shell architectures using the LDH nanosheet materials.

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Metadata

Authors
Yang, R., Zhou, Y., Xing, Y., Li, D., Jiang, D., Chen, M., Shi, W., & Yuan, S.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2019-09
Volume
253
Pages
131-139
ISSN
0926-3373 (ISSN-L)
OpenAlex
W2936817455
Cited by
755
References
6
FWCI
18.24
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Synergistic coupling of CoFe-LDH arrays with NiFe-LDH nanosheet for highly efficient overall water splitting in alkaline media. https://app.cochat.ai/papers/10.1016/j.apcatb.2019.04.054
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Yang, R., Zhou, Y., Xing, Y., Li, D., Jiang, D., Chen, M., Shi, W., & Yuan, S. (2019). Synergistic coupling of CoFe-LDH arrays with NiFe-LDH nanosheet for highly efficient overall water splitting in alkaline media. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.04.054

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