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Benzylamine oxidation boosted electrochemical water-splitting: Hydrogen and benzonitrile co-production at ultra-thin Ni2P nanomeshes grown on nickel foam

Ding, Yu, Miao, Bo-Qiang, Li, Shu-Ni, Jiang, Yu-Cheng, Liu, Yan-Yan, Yao, Hong-Chang, Chen, Yu·2020·Applied Catalysis B: Environment and Energy

Abstract

Abstract In this work, ultra-thin Ni2P nanomeshes (1.9 nm thickness) on nickel foam (NF) substrate (denoted as Ni2P-UNMs/NF) are successfully achieved through phosphidation treatment using ultra-thin Ni(OH)2 nanomeshes on NF substrate (denoted as Ni(OH)2-UNMs/NF) as reaction precursor. Because of the sufficient active sites in edge of the holes, high specific surface area, porous framework and high conductivity of NF substrate, Ni2P-UNMs/NF nanocomposites show the outstanding activity for both hydrogen evolution reaction (HER) and benzylamine oxidation reaction (BOR) in alkaline electrolyte. Importantly, Ni2P-UNMs/NF nanocomposites can directly act as a bifunctional electrocatalyst for the electrochemical water-splitting in two electrode system in the presence of benzylamine, which only requires an electrolysis voltage of 1.41 V to achieve the 10 mA cm-2 current density in alkaline electrolyte, accompanying with H2 production at cathode and value-added benzonitrile production at anode. Obviously, the BOR boosted electrochemical water-splitting provides an energy-saving and cost-competitive H2 production method.

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Metadata

Authors
Ding, Y., Miao, B.-Q., Li, S.-N., Jiang, Y.-C., Liu, Y.-Y., Yao, H.-C., & Chen, Y.
Venue
Applied Catalysis B: Environment and Energy
Publisher
Elsevier BV
Published
2020-07
Volume
268
Pages
118393
ISSN
0926-3373 (ISSN-L)
OpenAlex
W2983007138
Cited by
160
References
10
FWCI
3.71
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Benzylamine oxidation boosted electrochemical water-splitting: Hydrogen and benzonitrile co-production at ultra-thin Ni2P nanomeshes grown on nickel foam. https://app.cochat.ai/papers/10.1016/j.apcatb.2019.118393
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Ding, Y., Miao, B.-Q., Li, S.-N., Jiang, Y.-C., Liu, Y.-Y., Yao, H.-C., & Chen, Y. (2020). Benzylamine oxidation boosted electrochemical water-splitting: Hydrogen and benzonitrile co-production at ultra-thin Ni2P nanomeshes grown on nickel foam. Applied Catalysis B: Environment and Energy. https://doi.org/10.1016/j.apcatb.2019.118393

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