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Bimetallic iron-iridium alloy nanoparticles supported on nickel foam as highly efficient and stable catalyst for overall water splitting at large current density

Shen, Fang, Wang, Yamei, Qian, Guangfu, Chen, Wei, Jiang, Wenjie, Luo, Lin, Yin, Shibin·2020·Applied Catalysis B: Environmental

Abstract

Abstract In this work, FeIr bimetallic alloy self-supported on nickel foam is prepared by hydrothermal method, with average particle size of 2.17 nm and the Ir-loading is only 0.936 wt.%. It displays ultralow overpotentials for OER (200 mV) and HER (16.6 mV) at 20 mA cm−2 in alkaline media, which is superior to the ever reported HER catalysts. For overall water splitting, it only needs 1.48 V to derive a current density of 10 mA cm−2, and it also demonstrates an outstanding long-term stability with an ignorable decline in performance after testing 504 h at the current density of 150 mA cm−2. The excellent performance is ascribed to the ultrasmall FeIr alloy, the 3D conductive substrate, and the ethylene-glycol ligand environment facilitates highly efficient HER through hydrogen spillover. Thus, this work undoubtedly provides a promising method for developing ultralow-loading noble metal catalysts with excellent performance at large current density for overall water splitting.

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Metadata

Authors
Shen, F., Wang, Y., Qian, G., Chen, W., Jiang, W., Luo, L., & Yin, S.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2020-12
Volume
278
Pages
119327
ISSN
0926-3373 (ISSN-L)
OpenAlex
W3041457154
Cited by
170
References
7
FWCI
5.73
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Bimetallic iron-iridium alloy nanoparticles supported on nickel foam as highly efficient and stable catalyst for overall water splitting at large current density. https://app.cochat.ai/papers/10.1016/j.apcatb.2020.119327
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Shen, F., Wang, Y., Qian, G., Chen, W., Jiang, W., Luo, L., & Yin, S. (2020). Bimetallic iron-iridium alloy nanoparticles supported on nickel foam as highly efficient and stable catalyst for overall water splitting at large current density. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2020.119327

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