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Contrasting molybdenum cycling and isotopic properties in euxinic versus non-euxinic sediments and sedimentary rocks: Refining the paleoproxies
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“By contrast, organic-rich black shales deposited under anoxic and sulfidic pore waters may become enriched in redox-sensitive trace metals, especially Mo (Algeo and Lyons, 2006;März et al., 2008;Scott and Lyons, 2012).”
From Trace elements at the intersection of marine biological and geochemical evolution (2016) · cites this paper as Scott and Lyons, 2012
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“Proxy development and application have led to the ability to accurately identify sulfidic conditions, with the means to also delineate sulfidic water-column (euxinic) from sulfidic sedimentary pore fluids (Scott and Lyons, 2012; Hardisty et al., 2018).”
BackgroundA new vanadium species in black shales: Updated burial pathways and implications
Bian, L., Chappaz, A., Schovsbo, N. H., & Sanei, H. (2022) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2022.09.035 · Cited by 33
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Stepwise oxygenation of early Cambrian ocean controls early metazoan diversification
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The Re/Mo redox proxy reconsidered
Helz, G. R. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.10.029 · Cited by 32
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“For comparison, the upper part of the study interval (~130–200 m) is characterized by moderate to strong enrichments of Mo, U, and V, indicative of a locally anoxic and/or euxinic environments (Scott & Lyons, 2012; Tribovillard et al., 2006).”
BackgroundAbouelresh, M. O., Babalola, L., Bokhari, A., Omer, M., Koithan, T., & Boyde, D. (2019) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2019.05.001 · Cited by 31
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Global ocean redox changes before and during the Toarcian Oceanic Anoxic Event
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Dynamic redox and nutrient cycling response to climate forcing in the Mesoproterozoic ocean
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“2A), and Mo concentrations are relatively low compared to modern euxinic basins 32 .”
BackgroundDynamic evolution of the Ediacaran ocean across the Doushantuo Formation, South China
Han, T., & Fan, H.-F. (2015) · Chemical Geology · doi:10.1016/j.chemgeo.2015.09.021 · Cited by 28
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“Detrital dilution of sedimentary Mo auth and U auth signals through high sedimentation rates has repeatedly been suggested as a critical factor for the applicability of Mo-and U-based redox proxies (Lyons and Kashgarian, 2005; Scott and Lyons, 2012; Noordmann et al., 2015; Liu and Algeo, 2020).”
BackgroundResultInfluentialIvanić, M., Lojen, S., Grozić, D., Jurina, I., Skapin, S. D., Troskot-Čorbić, T., Mikac, N., Juračić, M., & Sondi, I. (2017) · Quaternary International · doi:10.1016/j.quaint.2017.03.050 · Cited by 31
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“…org and C org /P tot , sedimentary enrichment in Mo is a widely used proxy to determine the degree of oxygen depletion in marine sediments, with increasing sedimentary Mo concentrations pointing to more reducing conditions (e.g. Emerson and Huested, 1991; Helz et al., 1996; Scott and Lyons, 2012).”
InfluentialDahl, T. W., & Wirth, S. B. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2017.04.018 · Cited by 28
“…Baltic Sea (Scholz et al., 2013), where it produces substantial Mo enrichments (1–25 ppm) in the underlying sulfidic sediments relative to crustal rocks (but smaller enrichments than most sediments deposited in deep euxinic settings; i.e., 30–200 ppm) (Dahl et al., 2013b; Scott and Lyons, 2012).”
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“The predominance of anoxic and (mostly) non-sulfidic conditions in anoxic waters overlying the Ilgarari Formation is supported by muted enrichments in Mo, which requires the presence of sulfide in order to be sequestered in the sediment (Scott & Lyons, 2012).”
BackgroundWang, E., Feng, Y., Guo, T., Li, M., Xiong, L., Lash, G. G., Dong, X., Wang, T., & Ouyang, J. (2023) · Journal of Asian Earth Sciences · doi:10.1016/j.jseaes.2023.105825 · Cited by 28
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“16 (81,82), but in the absence of iron speciation data (the best available method for fingerprinting 360”
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A high-TOC shale in a low productivity world: The late Mesoproterozoic Arctic Bay Formation, Nunavut
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“Such enrichments likely indicate deposition in an intermittently euxinic environment (Lyons et al., 2009; Scott and Lyons, 2012).”
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Molybdenum speciation tracking hydrocarbon migration in fine-grained sedimentary rocks
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High-precision molybdenum isotope analysis of low-Mo igneous rock samples by MC–ICP–MS
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“The association between high values of this element and anoxia has been noted by several workers including Crusius et al. (1996), Craigie (1998), Lyons et al. (2003), Tribovillard et al. (2006), Scott and Lyons (2012) and Chappaz et al. (2014).”
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High-frequency redox variation across the Ordovician–Silurian transition, South China
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“…worthy of note that the magnitude of negative Mo isotopic values recorded in Mn carbonate-rich sediments is controlled by multiple factors including the redox conditions of ambient seawater, Mn oxide adsorption, and the presence and concentration of pore water H2S (Scott and Lyons 2012; Goto et al.”
BackgroundInfluentialGe, X., Chen, D., Zhang, G., Huang, T., Liu, M., & El‐Shafeiy, M. (2022) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2022.105633 · Cited by 24
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“4), suggests intermediate euxinia (Scott and Lyons 2012) or suboxic conditions (Algeo and Tribovillard 2009).”
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“~20 ppm during S1 and ~80 ppm during S3) suggest that bottom waters were intermittently euxinic during S1 and (semi)permanently euxinic during deposition of S3 (Scott and Lyons, 2012) (Fig.”
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Geochemical response to pulsed sedimentation: Implications for the use of Mo as a paleo-proxy
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Trace metal evidence for a poorly ventilated glacial Southern Ocean
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Mo marine geochemistry and reconstruction of ancient ocean redox states
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“A compilation of Mo abundance data for the modern ocean shows that the highest enrichment (>100 ppm) is associated with persistent euxinia, moderate enrichment (25–100 ppm) with intermittent euxinia, and weak enrichment ( 25 ppm) with oxic/suboxic sediments (Scott and Lyons, 2012).”
BackgroundLash, G. G. (2016) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2016.06.035 · Cited by 23
Coupled oceanic oxygenation and metazoan diversification during the early–middle Cambrian?
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“These small enrichments are consistent with sulfide restricted to sediment pore waters (cf. Scott and Lyons, 2012).”
BackgroundIsotope Fractionation Processes of Selected Elements
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“Molybdenum concentrations increased, [Hendy and Pedersen, 2005] but did not exceed 10 ppm, indicating that free dissolved sulfide and thiomolybdates were present but restricted to pore waters [Scott and Lyons, 2012] (Figure 4d).”
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Dunn, S. K., Pufahl, P. K., Murphy, J. B., & Lokier, S. W. (2021) · Frontiers in Earth Science · doi:10.3389/feart.2021.669476 · Cited by 21
“Ventilation of the deep ocean began during the Neoproterozoic Oxygenation Event (800 – 500 Ma; Och and Shields-Zhou, 2012; Scott & Lyons, 2012; Shields, 2017), but mounting evidence suggests that a persistently oxygenated deep ocean did not develop until the Permian (Elrick et al., 2011; Kah et…”
BackgroundWu, Y., Tian, H., Jia, W., Li, J., Li, T., Zhou, Q., Xie, L., & Peng, P. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120679 · Cited by 22
Nitrogen isotope evidence for oxygenated upper ocean during the Cryogenian interglacial period
Zhu, G., Li, T., Zhang, Z., Zhao, K., Song, H., Wang, P., Yan, H., & Song, H. (2022) · Chemical Geology · doi:10.1016/j.chemgeo.2022.120929 · Cited by 22
Fernández-Martínez, J., Ruíz, F., Rodríguez-tovar, F., Piñuela, L., García-Ramos, J., & Algeo, T. (2022) · Global and Planetary Change · doi:10.1016/j.gloplacha.2022.104026 · Cited by 21
Liu, W., Gao, P., Xiao, X.-M., Zhao, Y., Xing, Y.-J., & Li, J.-K. (2023) · Journal of Asian Earth Sciences · doi:10.1016/j.jseaes.2023.105874 · Cited by 21
Lash, G. G. (2015) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2015.10.002 · Cited by 22
Corella, J. P., Saiz‐Lopez, A., Sierra, M. J., Mata, M. P., Millán, R., Morellón, M., Cuevas, C. A., Moreno, A., & Valero-Garces, B. L. (2018) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2018.07.160 · Cited by 22
“Indeed, efficient Mo burial in the sediment under strong reducing conditions has been previously reported in different euxinic lacustrine and marine environments (Scott and Lyons, 2012; Wirth et al., 2013).”
BackgroundGao, P., He, Z., Lash, G. G., Li, S., & Zhang, R. (2020) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2020.104227 · Cited by 22
Overare, B., Azmy, K., Garzanti, E., Osokpor, J., Ogbe, O. B., & Avwenagha, E. O. (2021) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2020.104879 · Cited by 22
Extremely light molybdenum isotope signature of sediments in the Mariana Trench
Chen, S., Peng, X., Li, J., Lin, Z., Li, H., Wei, G., Li, X., Ta, K., Dasgupta, S., Xu, H., et al. (2022) · Chemical Geology · doi:10.1016/j.chemgeo.2022.120959 · Cited by 20
Lin, D., Xi, Z., Tang, S., Lash, G. G., Guo, Q., Wang, H., & Zhu, Y. (2023) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2023.111900 · Cited by 21
Globally limited but severe shallow-shelf euxinia during the end-Triassic extinction
Bond, A. D., Dickson, A., Ruhl, M., Bos, R., & van de Schootbrugge, B. (2023) · Nature Geoscience · doi:10.1038/s41561-023-01303-2 · Cited by 18
“Under oxic depositional conditions, Mo typically exhibits low sedimentary enrichments and isotopically light compositions, due principally to (Mn)oxyhy-droxide adsorption, with compositions ~3‰ lighter than coeval sea-water 16–18 .”
BackgroundXiao, B., Guo, D., Zhao, Z., Xiong, S., Feng, M., Zhao, Z., & Li, S. (2024) · ACS Omega · doi:10.1021/acsomega.4c01129 · Cited by 21
Reprint of: New Applications of Trace Metals as Proxies in Marine Paleoenvironments
Algeo, T. J., Morford, J. L., & Cruse, A. M. (2012) · Chemical Geology · doi:10.1016/j.chemgeo.2012.07.012 · Cited by 21
Metadata
- Authors
- Scott, C., & Lyons, T. W.
- Affiliations
- University of California, Riverside (US)
- Corresponding author
- Scott, Clint
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 2012-09
- Volume
- 324-325
- Pages
- 19-27
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2005604628
- Cited by
- 745
- References
- 80
- Citations by year
- 2026: 64 · 2025: 71 · 2024: 65 · 2023: 75 · 2022: 64 · 2021: 75 · 2020: 74 · 2019: 43 · 2018: 50 · 2017: 53 · 2016: 37 · 2015: 32 · 2014: 23 · 2013: 13 · 2012: 5
- FWCI
- 17.36
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Geology (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
- Keywords
- molybdenum isotopes, paleoredox proxies, black shales, total organic carbon, bottom water oxygenation, marine sediment, sedimentary rock
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