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Contrasting molybdenum cycling and isotopic properties in euxinic versus non-euxinic sediments and sedimentary rocks: Refining the paleoproxies
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“By contrast, organic-rich black shales deposited under anoxic and sulfidic pore waters may become enriched in redox-sensitive trace metals, especially Mo (Algeo and Lyons, 2006;März et al., 2008;Scott and Lyons, 2012).”
From Trace elements at the intersection of marine biological and geochemical evolution (2016) · cites this paper as Scott and Lyons, 2012
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“5871 column (euxinia; Scott & Lyons, 2012).”
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“Particulate shuttling in redox stratified basins is suggested as a mechanism for sediment V (and Mo) enrichment in several studies due their adsorption affinities with solid Fe-Mn (oxyhydr)oxide surfaces [1,12,27,28].”
BackgroundInfluentialGoto, K. T., Sekine, Y., Ito, T., Suzuki, K., Anbar, A. D., Gordon, G. W., Harigane, Y., Maruoka, T., Shimoda, G., Kashiwabara, T., et al. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120116 · Cited by 19
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“Divisions are based on empirical values from Raiswell and Canfield (1998) and Scott and Lyons (2012).”
InfluentialTracking the evolution of seawater Mo isotopes through the Ediacaran–Cambrian transition
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“7 and 9) that indicate H2S was restricted to pore fluids (Scott and Lyons 2012), in concert with relatively low Ce/Ce* values of 0.72 to 0.91 although these values may, at least in part, reflect detrital phosphate and hence not be an accurate redox proxy for local bottom waters (compare Fig.”
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“Average TOC values of 1% in the Gwna Group black shale and an average Mo abundance of 64 ppm are indicative of intermittently euxinic depositional conditions (Scott & Lyons, 2012).”
BackgroundMolybdenum geochemistry in salt marsh pond sediments
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“According to studies on modern marine sediments, Mo concentrations in sediments can be up to or greater than 100 ppm under a continuous euxinic marine environment, while they are lower than 25 ppm under oxic or dysoxic environmental conditions (Scott & Lyons, 2012).”
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“Such enrichments are generally observed in sediments that are intermittently/seasonally overlain by euxinic waters (Scott and Lyons 2012).”
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“Sediment Mo content can also be used to track past bottom water redox conditions (Scott and Lyons, 2012).”
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“…concentrations of Mo greater than 100 ppm, are considered a strong indicator of water column euxinia with little to no complications discussed previous, that is, nonrestricted connection to open marine conditions and strongly euxinic redox chemistry (Hardisty et al., 2018; Scott & Lyons, 2012).”
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“As a result, sedimentary enrichments of Mo are widely applied to reconstruct bottom water redox conditions (Scott and Lyons 2012).”
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“With no Mo values reaching 100 ppm, however, the intervals are unlikely to represent persistently euxinic conditions (Scott and Lyons 2012).”
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“The diagonal line represent V: (V+Ni) = 0.54 and was taken from Jones and Manning (1994). ticle 875374 Scott and Lyons, 2012).”
Influential16 Good Golly, Why Moly? THE STABLE ISOTOPE GEOCHEMISTRY OF MOLYBDENUM
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“solution, leading to pronounced sedimentary enrichments (e.g., Bertine and Turekian, 1973; 198 Emerson and Huested, 1991; Crusius et al., 1996; Scott and Lyons, 2012).”
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“In unrestricted basins, for example, euxinic conditions (H 2 S > Fe 2 + ) typically result in Mo concentrations (Mo > 100 ppm; Scott and Lyons, 2012) that are enriched above crustal values (1 – 2 ppm; Taylor and McLennan, 1995).”
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“It has been proposed that sedimentary Mo contents above the crustal average (1−2 μg/g; Taylor & McLennan, 1985) and below 25 μg/g are a strong indicator that dissolved sulfide is restricted to the porewater (Scott & Lyons, 2012).”
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Simbo, C. W., Potra, A., & Samuelsen, J. R. (2019) · Ore Geology Reviews · doi:10.1016/j.oregeorev.2019.103029 · Cited by 14
Euxinia in the Neoarchean: The starting point for early oxygenation in a Brazilian Craton
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“…because RSEs show crustal concentration in the sediment due to their conservative behaviours, whereas in anoxic/euxic waters these elements are quickly removed from the ocean, leading to strong accumulation in the sediment (Algeo & Maynard, 2004; Scott & Lyons, 2012; Tribovillard et al., 2006).”
BackgroundGibson, T. M., Kunzmann, M., Poirier, A., Schumann, D., Tosca, N. J., & Halverson, G. P. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.04.013 · Cited by 14
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“Compilations of modern marine sedimentary data suggest that Mo concentrations >100 ppm, c. 25–100 ppm and 25 ppm are typical of persistently euxinic conditions, intermittently euxinic or Mo-limited permanently euxinic conditions, and non-euxinic conditions, respectively (Scott and Lyons 2012).”
BackgroundAlam, M., Tripti, M., Gurumurthy, G. P., Sohrin, Y., Tsujisaka, M., Singh, A. D., Takano, S., & Verma, K. K. (2021) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2021.110790 · Cited by 13
Metadata
- Authors
- Scott, C., & Lyons, T. W.
- Affiliations
- University of California, Riverside (US)
- Corresponding author
- Scott, Clint
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 2012-09
- Volume
- 324-325
- Pages
- 19-27
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2005604628
- Cited by
- 745
- References
- 80
- Citations by year
- 2026: 64 · 2025: 71 · 2024: 65 · 2023: 75 · 2022: 64 · 2021: 75 · 2020: 74 · 2019: 43 · 2018: 50 · 2017: 53 · 2016: 37 · 2015: 32 · 2014: 23 · 2013: 13 · 2012: 5
- FWCI
- 17.36
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Geology (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
- Keywords
- molybdenum isotopes, paleoredox proxies, black shales, total organic carbon, bottom water oxygenation, marine sediment, sedimentary rock
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