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Contrasting molybdenum cycling and isotopic properties in euxinic versus non-euxinic sediments and sedimentary rocks: Refining the paleoproxies
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“By contrast, organic-rich black shales deposited under anoxic and sulfidic pore waters may become enriched in redox-sensitive trace metals, especially Mo (Algeo and Lyons, 2006;März et al., 2008;Scott and Lyons, 2012).”
From Trace elements at the intersection of marine biological and geochemical evolution (2016) · cites this paper as Scott and Lyons, 2012
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“Mo concentrations can be taken as a proxy for bottom wa‐ ter conditions (Scott and Lyons, 2012).”
BackgroundZhang, B., Yao, S., Poulton, S., Wignall, P., He, T.-C., Xiong, Y.-J., & Hu, W.-X. (2023) · Global and Planetary Change · doi:10.1016/j.gloplacha.2023.104273 · Cited by 10
Mass Extinction Coincided With Expanded Continental Margin Euxinia During the Cambrian Age 4
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“Subsequent re-sequestration of the released Mo by sulfidic sediments can thus produce a light sedimentary δ 98 Mo record (Morford et al., 2005; Scholz et al., 2013; Scott & Lyons, 2012).”
BackgroundTurner, A., Algeo, T., Peng, Y.-B., & Herrmann, A. (2019) · Palaeogeography, Palaeoclimatology, Palaeoecology · doi:10.1016/j.palaeo.2018.12.008 · Cited by 13
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“The Mo content for these F0 mudstones (mean 71 ± 46 ppm, SD) in combination with DOP values of the Vendomdalen Member (mean 0.43 ± 0.07, SD) from Krajewski (2013) further indicate frequent and intermittent euxinia (Scott & Lyons, 2012).”
BackgroundInfluentialBhuyan, N., & Hazarika, P. (2022) · Geological Journal · doi:10.1002/gj.4562 · Cited by 13
Pattan, J., Parthiban, G., Garg, A., & Moraes, N. R. C. (2017) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2017.03.034 · Cited by 14
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A shallow-water oxygen minimum zone in an oligotrophic Tonian basin
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“Based on the threshold values proposed by Scott and Lyons 64 and the EF model proposed by Algeo and Tribovillard 66 , Cycles 1 and 2 have high Mo concentrations (50–180 ppm), thus suggesting euxinic to periodic euxinic conditions in the water column (Fig.”
Zhai, L., Wan, S., Tada, R., Zhao, D., Shi, X., Yin, X., Tan, Y., & Li, A. (2019) · Geological Magazine · doi:10.1017/s0016756819000554 · Cited by 12
“Both elements exist as conservative oxyanions in oxic environments, but their different behaviour under reducing conditions can potentially result in remarkably different levels of enrichment (Algeo & Tribovillard, 2009; Scott & Lyons, 2012; Azrieli-Tal et al. 2014).”
BackgroundO'Sullivan, E., Nagler, T., & Babechuk, M. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2020.120039 · Cited by 13
Persistent deep water anoxia in the eastern South Atlantic during the last ice age
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Local versus seaway-wide trends in deoxygenation in the Late Cretaceous Western Interior Seaway
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Estuaries house Earth’s oldest known non-marine eukaryotes
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“In fully oxic conditions, Mo would be mainly adsorbed to Mn-oxides, and little Mo enrichment below sedimentwater interface [10].”
BackgroundMethodFerraro, S., Coccioni, R., Sabatino, N., Core, M. D., & Sprovieri, M. (2019) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2019.109384 · Cited by 11
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“The highest enrichments seen in the Lower Sappington do not occur outside euxinic environments in the modern ocean (Scott and Lyons, 2012).”
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“Mo EF < 25 for the Tal shale hint at an anoxic bottom-water condition with sulfidic condition restricted to pore waters (Kendall et al., 2017; Scott & Lyons, 2012).”
BackgroundMu, L., Zhang, B., Cao, J., Suping, Y., Hu, W., Lang, X., Xing, F., Liao, Z., Li, Y., & Yang, J. (2023) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2023.111967 · Cited by 10
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Benthic redox conditions and nutrient dynamics in the ca. 2.1 Ga Franceville sub-basin
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Trace metals as a redox proxy in Arabian Sea sediments in and below the oxygen minimum zone
Vollebregt, A., van Helmond, N. A. G. M., Pit, S., Kraal, P., & Slomp, C. P. (2023) · Chemical Geology · doi:10.1016/j.chemgeo.2022.121300 · Cited by 9
“Nevertheless, various quantitative thresholds have been proposed for the interpretation of trace metal records in the context of bottom water redox conditions (e.g. Scott and Lyons, 2012; Moffitt et al., 2015).”
BackgroundYuan, L., Zhou, Y., Chen, X., Zhu, M., Poulton, S. W., Tian, Z., Li, D., THIRLWALL, M. F., & Shields, G. (2023) · Precambrian Research · doi:10.1016/j.precamres.2023.107004 · Cited by 12
“The findings are generally consistent with other RSE studies (e.g., Scott et al., 2008; Sahoo et al., 2016), and is supported by U isotope data from South China, Siberia, USA (Zhang et al., 2019) and Namibia (Tostevin et al., 2019), and by Cr isotope data from the Wuhe section (Xu et al., 2022).”
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“Mo is typically enriched in H 2 S-rich euxinic conditions through the formation of authigenic sulfides (Tribovillard et al., 2006; Scott and Lyons, 2012).”
BackgroundHatem, E., Tribovillard, N., Averbuch, O., Bout‐Roumazeilles, V., Trentesaux, A., Deçoninck, J., Baudin, F., & Adatte, T. (2017) · Bulletin de la Société Géologique de France · doi:10.1051/bsgf/2017193 · Cited by 10
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“Frontiers in Marine Science 20 content under euxinic condition with free H2S exceeds 60 mg/kg and can even reach 100 mg/kg in sediments (Scott and Lyons, 2012; Chen et al., 2016).”
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Setting the stage for the genesis of the giant Bendigo ore system
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“17), the levels of enrichment are significantly less than reported for recent marine anoxic and euxinic environments (Scott & Lyons 2012; Tribovillard et al. 2006).”
BackgroundMethodThem, T., Owens, J. D., Marroquín, S., Caruthers, A., Trabucho-Alexandre, J., & Gill, B. (2022) · AGU Advances · doi:10.1029/2022av000671 · Cited by 6
“Molybdenum accumulation in these environments is slow, but much of the Mo lost from the oceans today leaves through this sink since these sediments cover a large portion of the modern seafloor (Bertine & Turekian, 1973; Scott & Lyons, 2012).”
BackgroundInfluentialReconstructing redox variation in a young, expanding ocean basin (Cretaceous Central Atlantic)
Bonazzi, M., Bonacina, G., Massara, E. P., Piva, A., Scotti, P., Viaggi, P., & Sanfilippo, A. (2023) · Cretaceous research (Print) · doi:10.1016/j.cretres.2023.105681 · Cited by 7
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Application of Thallium Isotopes: Tracking Marine Oxygenation through Manganese Oxide Burial
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Isotope Fractionation Processes of Selected Elements
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“High Mo enrichment in reducing settings are often linked to sulfidic conditions (Scott & Lyons, 2012).”
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Chemical Speciation and Metallomics
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“nently Mo-depleted euxinic conditions or intermittently/seasonally euxinic conditions, and >100 ppm for permanently euxinic conditions [74].”
BackgroundEffects of Emeishan Large Igneous Province on organic matter accumulation, Sichuan Basin, China
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“The rest of Mo (50–65%) deposites in sulfidic conditions at a rate of 2–3 orders of magnitude higher than in oxic conditions [36].”
BackgroundOrganic matter the major sink of redox-sensitive trace elements in Upper Devonian black shale
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Climatic-oceanic destabilization facilitated the euxinic expansion in the early Cambrian oceans
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Sub-millimeter molybdenum and uranium isotopes track millennial redox events in the Cambrian ocean
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“Also, theAlumShalemudwasdepositedexceedinglyslowly(~1 – 4 mm kyr − 1 post-compaction 35,36 ), and even euxinic sediments deposited ~10 4 times faster also capture high Mo concentrations 14,56 .”
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Different integrated mechanisms drove the two pulses of the Late Ordovician mass extinction
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Jarvis, I., Atar, E., Gröcke, D. R., HERRINGSHAW, L. G., & Trabucho‐Alexandre, J. (2024) · Geological Magazine · doi:10.1017/s0016756824000244 · Cited by 7
Rico, K. I., Sheldon, N., & Kinsman-Costello, L. E. (2020) · Geobiology · doi:10.1111/gbi.12388 · Cited by 7
“The absolute concentrations of Mo in MIS samples are 1 ppm, values too low to be considered to be even anoxic according to the threshold of 20 ppm designated by Scott and Lyons (2012), in spite of measured dissolved O2 levels consistent with anoxia (Ruberg et al., 2008).”
BackgroundHints, R., Pajusaar, S., Urtson, K., Liiv, M., & Kallaste, T. (2021) · Proceedings of the Estonian Academy of Sciences Geology · doi:10.3176/earth.2021.04 · Cited by 7
Lin, D., Tang, S., Xi, Z., Zhang, B., & Ye, Y. (2021) · Minerals · doi:10.3390/min11070710 · Cited by 7
“In the modern ocean, Mo concentrations greater than 100 ppm represent an euxinia environment, concentrations between 25 and 100 ppm represent an intermittent euxinia environment, and concentrations less than 25 ppm represent a non-euxinic environment [29].”
BackgroundBond, A. D., Dickson, A. J., Ruhl, M., & Raine, R. J. (2022) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2022.111018 · Cited by 7
Kendall, B., Wang, S., Lillis, P. G., Xing, L., Zheng, W., & Zhu, C. (2022) · Chemical Geology · doi:10.1016/j.chemgeo.2022.121244 · Cited by 8
Fang, C., Zhang, C., Huang, N., Teng, L., Li, C., Shao, W., & Zeng, M. (2023) · Minerals · doi:10.3390/min13091195 · Cited by 7
Redox changes in the Iapetus Ocean during the Late Ordovician extinction crises
Sánchez-Roda, A., Wignall, P. B., Xiong, Y., & Poulton, S. W. (2024) · Journal of the Geological Society · doi:10.1144/jgs2023-195 · Cited by 7
Dirksen, J. P., Hennekam, R., Geerken, E., & Reichart, G. (2019) · Paleoceanography and Paleoclimatology · doi:10.1029/2018pa003458 · Cited by 7
“Mo/Ti is a proxy for bottom water anoxia (e.g., Scott & Lyons, 2012; Tribovillard et al., 2006).”
BackgroundTakahashi, S., Nakada, R., Watanabe, Y., & Takahashi, Y. (2018) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2018.12.014 · Cited by 7
Adeboye, O. O., Riedinger, N., Wu, T., Grammer, G. M., & Quan, T. M. (2020) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2020.104345 · Cited by 7
Molybdenum isotope heterogeneity of metal sulfides from magmatic hydrothermal systems
Tang, W., Xu, J., Cao, K. H., Li, J., & Chen, J. (2023) · Chemical Geology · doi:10.1016/j.chemgeo.2023.121742 · Cited by 6
Metadata
- Authors
- Scott, C., & Lyons, T. W.
- Affiliations
- University of California, Riverside (US)
- Corresponding author
- Scott, Clint
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 2012-09
- Volume
- 324-325
- Pages
- 19-27
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2005604628
- Cited by
- 745
- References
- 80
- Citations by year
- 2026: 64 · 2025: 71 · 2024: 65 · 2023: 75 · 2022: 64 · 2021: 75 · 2020: 74 · 2019: 43 · 2018: 50 · 2017: 53 · 2016: 37 · 2015: 32 · 2014: 23 · 2013: 13 · 2012: 5
- FWCI
- 17.36
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Geology (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
- Keywords
- molybdenum isotopes, paleoredox proxies, black shales, total organic carbon, bottom water oxygenation, marine sediment, sedimentary rock
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