The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Surface and Interface Engineering in Copper-Based Bimetallic Materials for Selective CO2 Electroreduction
Open accessAbstract
Summary The electrochemical CO 2 reduction reaction (CO 2 RR) can couple carbon-capture storage with renewable energy to convert CO 2 into chemical feedstocks. For this process, copper is the only metal known to catalyze the CO 2 RR to hydrocarbons with adequate efficiency, but it suffers from poor selectivity. Copper bimetallic materials have recently shown an improvement in CO 2 RR selectivity compared with that of copper, such that the secondary metal is likely to play an important role in altering inherent adsorption energetics. This review explores the fundamental role of the secondary metal with a focus on how oxygen (O) and hydrogen (H) affinity affect selectivity in bimetallic electrocatalysts. Here, we identify four metal groups categorized by O and H affinities to determine their CO 2 RR selectivity trends. By considering experimental and computational studies, we link the effects of extrinsic chemical composition and physical structure to intrinsic intermediate adsorption and reaction pathway selection. After this, we summarize some general trends and propose design strategies for future electrocatalysts.
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Cites
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Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
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Electrocatalytic reduction of CO2 and CO to multi-carbon compounds over Cu-based catalysts
Ma, W., He, X., Wang, W., Xie, S., Zhang, Q., & Wang, Y. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00535a · Cited by 721
Defect engineering in earth-abundant electrocatalysts for CO2 and N2 reduction
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Metadata
- Authors
- Vasileff, A., Xu, C., Jiao, Y., Zheng, Y., & Qiao, S.-Z.
- Venue
- Chem
- Publisher
- Elsevier BV
- Published
- 2018-08
- Volume
- 4
- Issue
- 8
- Pages
- 1809-1831
- ISSN
- 2451-9294 (ISSN-L)
- OpenAlex
- W2803362190
- Cited by
- 901
- References
- 22
- FWCI
- 17.70
- Type
- journal article
- Language
- en
- Open access
- bronze
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