Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles
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SMILES transfers the optical properties of typical cationic dyes directly and reliably from solution to high-density molecular crystals.
“This small-molecule ionic isolation lattices (SMILES) transfers the optical properties of typical cationic dyes directly and reliably from solution to high-density molecular crystals (Figure 8a).157,158”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [157]
SMILES crystals are formed with most cationic dyes, including cyanines, oxazines, and rhodamines, which deliver predictable optical properties and high fluorescence brightness with high dye densities (one dye per ∼4 nm3).
“SMILES crystals are formed with most cationic dyes, including cyanines, oxazines, and rhodamines, which deliver predictable optical properties and high fluorescence brightness with high dye densities (one dye per ∼4 nm3).”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [157]
An alternative approach is based on hierarchical coassembly using a scaffold ensuring spatial and electronic isolation to prohibit fluorescence quenching in an aggregate state.
“An alternative approach is based on hierarchical coassembly using a scaffold ensuring spatial and electronic isolation to prohibit fluorescence quenching in an aggregate state.”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [157]
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Aggregate Science: from Molecules, beyond Molecules
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Engineering Soluble Diketopyrrolopyrrole Chromophore Stacks from a Series of Pd(II)‐Based Ravels**
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Switchable Supramolecular Jalousie Constructed from a Fluorenone Macrocycle
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J‐Aggregate Promoting NIR‐II Emission for Fluorescence/Photoacoustic Imaging‐Guided Phototherapy
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The use of crude carbon dots as novel antioxidants for natural rubber
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Control of the fluorescence lifetime in dye based nanoparticles
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Self-citationDesign of Aurone‐Based Dual‐State Emissive (DSE) Fluorophores
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Real-time monitoring of mercury(II) in water and food samples using a quinoline-based ionic probe
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Temperature‐Triggered Supramolecular Assembly of Organic Semiconductors
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Lighting Up Nonemissive Azobenzene Derivatives by Pressure
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Counterion-insulated near-infrared dyes in biodegradable polymer nanoparticles for in vivo imaging
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Construction of Metal–Organic Framework Films via Crosslinking‐Induced Assembly
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Self-citationLight‐Harvesting Nanomaterials Based on Dyes for Energy Transfer and Amplified Biosensing
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Photoinduced Charge Transfer at Discrete Molecular Interfaces in Cocrystals
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A Portable Fluorescence Sensor with Improved Performance for Aniline Monitoring
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Fluorescence emission enhancement of a T-shaped benzimidazole with a mechanically-interlocked ‘suit’
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Tetraphenylethene-based macrocycles with dual-ring topology: synthesis, structures, and applications
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Modifications and applications of heptamethine cyanine (Cy7) dyes as near-infrared photosensitizers
Long, L., Cao, X., Shi, X., Zhang, J., & Shi, C. (2025) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2025.216780 · Cited by 18 · see citing works
Rescuing the solid-state fluorescence of perylene diimide dyes by host–guest isolation
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Fluorescent Amphiphilic Quaternized β-Chitin: Antibacterial Mechanism and Cell Imaging
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Advancing Cancer Treatment: Innovative Materials in PDT and Diagnostic Integration
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Anion receptors with nitrone C–H hydrogen bond donors
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Metal–organic framework-based self-healing hydrogel fiber random lasers
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Trapping Anions within Stacks of Tetra-Urea Macrocycles
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Carbon-rich macrocycles and carbon nanoribbons as unique optical materials
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Sulfate Recognition in Water via Charge‐Assisted Hydrogen Bonding
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Fluorophore Multimerization as an Efficient Approach towards Bright Protein Labels
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Thermally-induced atropisomerism promotes metal-organic cage construction
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Plug-and-Play Molecular Approach for Room Temperature Polariton Condensation
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Transparent Wood Biocomposite of Well-Dispersed Dye Content for Fluorescence and Lasing Applications
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Supramolecular dye polymers for aggregation-induced photocatalysis
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Luminescence in macrocyclic supramolecular systems
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Terpyridine-Based Metal–Organic Cage with Enhanced Emission via Coordination-Induced Rigidity
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Biomimetic Synthesis of Organic Molecular‐Doped Fluorescent Guanine Crystals with Pearlescence
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Ligand and Gold(I) Fluorescein–AIEgens as Photosensitizers in Solution and Doped Polymers
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- Authors
- Benson, C. R., Kacenauskaite, L., VanDenburgh, K. L., Zhao, W., Qiao, B., Sadhukhan, T., Pink, M., Chen, J., Borgi, S., Chen, C.-H., Davis, B. J., Simon, Y. C., Raghavachari, K., Laursen, B. W., & Flood, A. H.
- Affiliations
- Indiana University Bloomington (US)
- University of Copenhagen (DK)
- University of Southern Mississippi (US)
- Corresponding author
- Laursen, Bo W.
- Flood, Amar H.
- ORCID
- Venue
- Chem
- Publisher
- Elsevier BV
- Published
- 2020-08
- Volume
- 6
- Issue
- 8
- Pages
- 1978-1997
- ISSN
- 2451-9294 (ISSN-L)
- OpenAlex
- W3047531788
- Cited by
- 226
- References
- 63
- Citations by year
- 2026: 13 · 2025: 41 · 2024: 47 · 2023: 42 · 2022: 39 · 2021: 40 · 2020: 3
- FWCI
- 12.06
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Chem (publishedVersion)
- Research at the University of Copenhagen (University of Copenhagen) (publishedVersion, cc-by-nc-nd)
- Aquila Digital Community (University of Southern Mississippi) (submittedVersion)
- Funders
- Forskerakademiet (DFF-6111-00483)
- National Science Foundation (DMR-1533988, DGE-149999)
- College of Arts and Sciences, Boston University
- Københavns Universitet
- Indiana University
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Physical Sciences › Chemistry › Organic Chemistry › Supramolecular Chemistry and Complexes
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Crystallography and molecular interactions
- Keywords
- fluorescent dyes, fluorescence quenching, concentration quenching, organic light-emitting diodes, polymer additives, xanthene, oxazines, cyanine dyes, wide band gap, optical materials
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