Crystallinity studies of PEKK and carbon fibre/PEKK composites: A review
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PEKK has a lower melt viscosity, making it easier to work with during printing, and its printing temperature is slightly lower than that of PEEK.
“Additionally, PEKK has a lower melt viscosity, making it easier to work with during printing. Furthermore, the printing temperature of PEKK is slightly lower than that of PEEK.”
From A comprehensive review of lunar-based manufacturing and construction (2024) · cites this paper as [217]
The Introduction (p. 4) says PEKK has a lower processing temperature than PEEK, which supports the temperature comparison broadly, but does not specifically compare printing temperatures or describe the difference as slight. Its viscosity discussion concerns different PEKK grades, not PEKK versus PEEK; the paper does not establish that lower melt viscosity makes PEKK easier to print. (LLM, conf=0.85)
Experimental — accuracy not yet measuredPEKK features an additional ketone group in its chemical structure compared to PEEK.
“In comparison to PEEK, PEKK features an additional ketone group in its chemical structure.”
From A comprehensive review of lunar-based manufacturing and construction (2024) · cites this paper as [217]
PEKK offers superior thermal stability with a higher glass transition temperature (Tg) at around 162°C, in contrast to PEEK's Tg of about 143°C.
“PEKK offers superior thermal stability, boasting a higher glass transition temperature (Tg) at around 162 ◦ C in contrast to PEEK, with a Tg of about 143 ◦ C.”
From A comprehensive review of lunar-based manufacturing and construction (2024) · cites this paper as [217]
The Introduction (p. 4) and Isothermal Crystallisation section (p. 18) compare PEKK and PEEK crystallisation, not their glass-transition temperatures or thermal stability. Searches for Tg, glass transition, 162°C and 143°C found no passage in our copy supporting the stated comparison. (LLM, conf=0.76)
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- Authors
- Pérez-Martín, H., Mackenzie, P., Baidak, A., Ó Brádaigh, C. M., & Ray, D.
- Affiliations
- University of Edinburgh (GB)
- Hexcel (United Kingdom) (GB)
- Corresponding author
- Ray, Dipa
- Venue
- Composites Part B Engineering
- Publisher
- Elsevier BV
- Published
- 2021-10
- Volume
- 223
- Pages
- 109127
- ISSN
- 1359-8368 (ISSN-L)
- OpenAlex
- W3182470399
- Cited by
- 212
- References
- 98
- Citations by year
- 2026: 45 · 2025: 57 · 2024: 43 · 2023: 40 · 2022: 23 · 2021: 4
- FWCI
- 9.74
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- Composites Part B Engineering (publishedVersion)
- White Rose Research Online (University of Leeds, The University of Sheffield, University of York) (acceptedVersion)
- Edinburgh Research Explorer (University of Edinburgh) (submittedVersion, other-oa)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Engineering › Mechanical Engineering › Fiber-reinforced polymer composites
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Keywords
- PEKK, carbon fiber composites, crystallinity, crystallization kinetics, transcrystallinity, fiber-matrix interface, autoclave processing, automated tape placement, 3D printing, high-performance thermoplastics
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