The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water
Open accessAbstract
Abstract Using porous electrodes containing redox-active nickel hexacyanoferrate (NiHCF) nanoparticles, we construct and test a device for capacitive deionization in a two flow-channel device where the intercalation electrodes are in direct contact with an anion-exchange membrane. Upon reduction of NiHCF, cations intercalate into it and the water in its vicinity is desalinated; at the same time water in the opposing electrode becomes more saline upon oxidation of NiHCF in that electrode. In a cyclic process of charge and discharge, fresh water is continuously produced, alternating between the two channels in sync with the direction of applied current. We present proof-of-principle experiments of this technology for single salt solutions, where we analyze various levels of current and cycle durations. We analyze salt removal rate and energy consumption. In desalination experiments with salt mixtures we find a threefold enhancement for K+ over Na+-adsorption, which shows the potential of NiHCF intercalation electrodes for selective ion separation from mixed ionic solutions.
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Cites
Qu, Y., Campbell, P. G., Gu, L., Knipe, J. M., Dzenitis, E., Santiago, J. G., & Stadermann, M. (2016) · Desalination · doi:10.1016/j.desal.2016.09.014 · Cited by 159
Cited by
Comparison of energy consumption in desalination by capacitive deionization and reverse osmosis
Qin, M., Deshmukh, A., Epsztein, R., Patel, S. K., Owoseni, O. M., Walker, W. S., & Elimelech, M. (2019) · Desalination · doi:10.1016/j.desal.2019.01.003 · Cited by 292
Energy Efficiency of Capacitive Deionization
Wang, L., Dykstra, J. E., & Lin, S. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.8b04858 · Cited by 292
Water Desalination with Energy Storage Electrode Materials
Suss, M. E., & Presser, V. (2018) · Joule · doi:10.1016/j.joule.2017.12.010 · Cited by 283
Review of Concepts and Applications of Electrochemical Ion Separation (EIONS) Process
Yoon, H., Lee, J., Kim, S., & Yoon, J. (2019) · Separation and Purification Technology · doi:10.1016/j.seppur.2018.12.071 · Cited by 133
Narendra Kumar, A. V., Li, Y., Yu, H., Yin, S., Xue, H., Xu, Y., Li, X., Wang, H., & Wang, L. (2018) · Electrochimica Acta · doi:10.1016/j.electacta.2018.08.103 · Cited by 42
Metadata
- Authors
- Porada, S., Shrivastava, A., Bukowska, P., Biesheuvel, P. M., & Smith, K. C.
- Venue
- Electrochimica Acta
- Publisher
- Elsevier BV
- Published
- 2017-11
- Volume
- 255
- Pages
- 369-378
- ISSN
- 0013-4686 (ISSN-L)
- OpenAlex
- W2752681981
- Cited by
- 284
- References
- 1
- FWCI
- 13.73
- Type
- journal article
- Language
- en
- Open access
- green
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- Porada, S., Shrivastava, A., Bukowska, P., Biesheuvel, P. M., & Smith, K. C. (2017). Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water. Electrochimica Acta. https://doi.org/10.1016/j.electacta.2017.09.137
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