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Influence of crystal polymorphism on mechanical and barrier properties of poly(l-lactic acid)
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“The crystallite size of PLA in PLA/clay nanocomposite films were around 14 to 19 nm.61”
From Correlative characterization of stereocomplex formation in blends of aliphatic polyester P(PCL m - b -PLLA n ) multiblock-copolymers and PDLA (2026) · cites this paper as [61]
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“The crystalline structures and their morphology within a crystalline phase of PLA can be modified by subjecting it to thermal treatment [10,11].”
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“Interestingly, there is a correlation between the DSC analysis and DMA in the results of crystal polymorphism, which confirms the crystal structure of a-crystals, suggesting that the elastic modulus of the PLA/GTA-Ag-NPs samples in DMA is affected by the rearrangements of the molecular packing within the unit cell [31…”
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“Crystallites can decrease the amount of amorphous phase and increase the tortuosity of the transport path for gas molecules.[3,4] Therefore, altering the crystallinity and the crystalline morphology can adjust the barrier properties of PLA.”
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“According to the literature [11,14,54], these profiles are typical for a majority of α’ crystallites in samples crystallized at 75 ◦C and of α crystals in samples crystallized at 85 ◦C.”
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“This is because the amorphous phase transfers the load to the crystals and absorbs the imposed strain [32].”
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“[41] studied water vapor permeability of a PLA film and found that the enhancement of the barrier property is attributed to the increase in the fraction of orthorhombic ordered PLA crystals that produces a tighter molecular packing of PLA chain segments, resulting in the reduction of the adsorbed water vapor diffusion…”
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“Similarly, M. Cocca et al. [12] found that a reduced water vapor permeability correlates with an increased PLA crystallinity.”
Assessment of polylactide as optical material
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“The latter was characterized by peak duplication, as reported in previous papers [14,42].”
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A Relatively Simple Look at the Rather Complex Crystallization Kinetics of PLLA
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“Thus, considering other reports, the predominant crystal structure in the low range of t mperatures covered in this work is α′ [3].”
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Metadata
- Authors
- Cocca, M., Lorenzo, M. L. D., Malinconico, M., & Frezza, V.
- Affiliations
- National Research Council (IT)
- Corresponding author
- Cocca, Mariacristina
- Venue
- European Polymer Journal
- Publisher
- Elsevier BV
- Published
- 2011-05
- Volume
- 47
- Issue
- 5
- Pages
- 1073-1080
- ISSN
- 0014-3057 (ISSN-L)
- OpenAlex
- W2035512535
- Cited by
- 296
- References
- 0
- Citations by year
- 2026: 11 · 2025: 22 · 2024: 19 · 2023: 26 · 2022: 29 · 2021: 20 · 2020: 32 · 2019: 19 · 2018: 14 · 2017: 23 · 2016: 22 · 2015: 13 · 2014: 11 · 2013: 21 · 2012: 11
- FWCI
- 12.55
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- European Polymer Journal (publishedVersion)
- Funders
- HORTIBIOPACK (232551)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Nanocomposites and Properties
- Keywords
- poly(L-lactic acid), crystal polymorphism, water vapor barrier, mechanical properties, crystallinity, annealing, Young's modulus, elongation at break, chain packing, conformational disorder, mesophases, biodegradable films
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