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Influence of crystal polymorphism on mechanical and barrier properties of poly(l-lactic acid)
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“The crystallite size of PLA in PLA/clay nanocomposite films were around 14 to 19 nm.61”
From Correlative characterization of stereocomplex formation in blends of aliphatic polyester P(PCL m - b -PLLA n ) multiblock-copolymers and PDLA (2026) · cites this paper as [61]
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“The increase in crystallinity leads to a decrease in the WVP because the decreased amorphous content increases the tortuous path for water diffusion.9 Cocca et al.10 have studied how the α and α0 crystal forms affect PLLA film barrier properties by annealing at different crystallization temperatures.”
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“This ability to undergo the deformation has been reported in the literature for small-sized crystals, like those generated at 80 ◦C, and explained by their aptitude to transfer the stress more successfully than big crystalline lamellae [18].”
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“most intense diffractions, the (110)/(200) and the (203) ones, and by the appearance of some other specific weak reflections [17,45,46].”
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Peng, Q., Li, R., Yin, S., Tang, Q., Sun, R. Y., Chang, G., & Kang, M. (2024) · Polymer Science Series B · doi:10.1134/s156009042460089x
Haese, M. D., Geeraert, H., Gerets, B., Brande, N. P. V. D., Graulus, G., & Pitet, L. M. (2026) · Polymer Chemistry · doi:10.1039/d6py00419a
Optimierung des Eigenschaftsprofils von schmelzgesponnenen Polylactid-Multifilamentgarnen
Tarkhanov, E. (2019) · doi:10.14279/depositonce-8585
“[117], dass in Gegenwart der α‘Struktur geringere E-Moduln und höhere Bruchdehnungen als im Fall der α-Struktur vorliegen.”
BackgroundEstudio de la viabilidad del reciclado mecánico del poli(ácido láctico) y sus nanocomposites
González, F. (2018) · doi:10.20868/upm.thesis.50944
“81 a la literatura, dichos picos corresponden a los planos (010), (110/200) y (203) del PLA cristalino [35,96,118].”
BackgroundInfluential
Metadata
- Authors
- Cocca, M., Lorenzo, M. L. D., Malinconico, M., & Frezza, V.
- Affiliations
- National Research Council (IT)
- Corresponding author
- Cocca, Mariacristina
- Venue
- European Polymer Journal
- Publisher
- Elsevier BV
- Published
- 2011-05
- Volume
- 47
- Issue
- 5
- Pages
- 1073-1080
- ISSN
- 0014-3057 (ISSN-L)
- OpenAlex
- W2035512535
- Cited by
- 296
- References
- 0
- Citations by year
- 2026: 11 · 2025: 22 · 2024: 19 · 2023: 26 · 2022: 29 · 2021: 20 · 2020: 32 · 2019: 19 · 2018: 14 · 2017: 23 · 2016: 22 · 2015: 13 · 2014: 11 · 2013: 21 · 2012: 11
- FWCI
- 12.55
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- European Polymer Journal (publishedVersion)
- Funders
- HORTIBIOPACK (232551)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Nanocomposites and Properties
- Keywords
- poly(L-lactic acid), crystal polymorphism, water vapor barrier, mechanical properties, crystallinity, annealing, Young's modulus, elongation at break, chain packing, conformational disorder, mesophases, biodegradable films
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