Tunable aggregation of short-side-chain perfluorinated sulfonic acid ionomers for the catalyst layer in polymer electrolyte membrane fuel cells
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The aggregation size of short side-chain ionomers can be controlled by increasing the dipropylene glycol content because the hydrophobic backbone main chain becomes more mobile due to its high solvating power.
“The aggregation size of short side-chain ionomers can be controlled by increasing the dipropylene glycol (DPG) content (the solvent) because the hydrophobic backbone main chain of short side chain ionomers becomes more mobile due to their high solvating power.”
From Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly (2023) · cites this paper as [171]
Decreased ionomer aggregation leads to a more homogeneous ionomer distribution in the catalyst layer, which can facilitate proton transfer at low relative humidity conditions.
“Reasonably, the decreased ionomer aggregation leads to a more homogeneous ionomer distribution in the catalyst layer, which can facilitate proton transfer at low relative humidity (RH) conditions [171].”
From Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly (2023) · cites this paper as [171]
The solvent for the ionomer solution affects the aggregate size.
“The solvent for the ionomer solution affects the aggregate size.”
From Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly (2023) · cites this paper as [171]
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Sorted by citations
Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly
Mo, S., Du, L., Huang, Z., Chen, J., Zhou, Y., Wu, P., Meng, L., Wang, N., Xing, L., Zhao, M., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-023-00190-w · Cited by 277 · see citing works
“Reasonably, the decreased ionomer aggregation leads to a more homogeneous ionomer distribution in the catalyst layer, which can facilitate proton transfer at low relative humidity (RH) conditions [171].”
Liu, H., Ney, L., Zamel, N., & Li, X. (2022) · Applied Sciences · doi:10.3390/app12083776 · Cited by 85 · see citing works
- Authors
- So, S., Kang, H., Choi, D., & Oh, K.-H.
- Affiliations
- Korea Research Institute of Chemical Technology (KR)
- Korea Automotive Technology Institute (KR)
- Corresponding author
- Oh, Keun-Hwan
- Venue
- International Journal of Hydrogen Energy
- Publisher
- Elsevier BV
- Published
- 2020-07
- Volume
- 45
- Issue
- 38
- Pages
- 19891-19899
- ISSN
- 0360-3199 (ISSN-L)
- OpenAlex
- W3034986420
- Cited by
- 20
- References
- 3
- Citations by year
- 2026: 3 · 2025: 4 · 2024: 2 · 2023: 5 · 2022: 4 · 2021: 2
- FWCI
- 0.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- International Journal of Hydrogen Energy (publishedVersion)
- Funders
- Ministry of Trade, Industry and Energy
- National Research Foundation of Korea
- Ministry of Science and ICT, South Korea (- 2019M3E6A1064729, 20012133)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Advancements in Solid Oxide Fuel Cells
- Keywords
- proton exchange membrane fuel cells, catalyst layer porosity, surface morphology, humidity effects
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