Mechanistic origins of the high-pressure inhibition of methanol dehydration rates in small-pore acidic zeolites
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At Brønsted acid sites, DME can be formed via a concerted and a stepwise mechanism.
“AtBrønstedacidsites,DMEcanbeformedviatheconcertedandthestepwisemechanism.”
From Reactivity of Surface Lewis and Brønsted Acid Sites in Zeolite Catalysis: A Computational Case Study of DME Synthesis Using H-SSZ-13 (2022) · cites this paper as [95]
In the stepwise mechanism, DME is formed through reaction of a surface methoxyspecies (SMS) with MeOH.
“Inthestepwisemechanism,DMEisformed throughreactionofasurfacemethoxyspecies(SMS)with MeOH.”
From Reactivity of Surface Lewis and Brønsted Acid Sites in Zeolite Catalysis: A Computational Case Study of DME Synthesis Using H-SSZ-13 (2022) · cites this paper as [95]
In the concerted mechanism, two adsorbed MeOH react directly.
“Intheconcertedmechanism,twoadsorbedMeOH reactdirectly.”
From Reactivity of Surface Lewis and Brønsted Acid Sites in Zeolite Catalysis: A Computational Case Study of DME Synthesis Using H-SSZ-13 (2022) · cites this paper as [95]
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Probing Monomer and Dimer Adsorption Trends in the MFI Framework
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Self-citationGlycerol etherification with ethanol over Beta zeolites of varied void polarity
Kimpiab, E. E., Hur, Y. G., Ezendu, S., Foster, S. E., Degenstein, J. C., Tomasoa, V. M., Blackstock, S. C., Szilvási, T., Bara, J. E., & Harris, J. W. (2026) · Journal of Catalysis · doi:10.1016/j.jcat.2026.117130
- Authors
- Di Iorio, J. R., Hoffman, A. J., Nimlos, C. T., Nystrom, S., Hibbitts, D., & Gounder, R.
- Affiliations
- University of Florida (US)
- Purdue University West Lafayette (US)
- Corresponding author
- Hibbitts, David
- Gounder, Rajamani
- Venue
- Journal of Catalysis
- Publisher
- Elsevier BV
- Published
- 2019-12
- Volume
- 380
- Pages
- 161-177
- ISSN
- 0021-9517 (ISSN-L)
- OpenAlex
- W2982597574
- Cited by
- 61
- References
- 60
- Citations by year
- 2026: 4 · 2025: 9 · 2024: 9 · 2023: 11 · 2022: 8 · 2021: 13 · 2020: 7
- FWCI
- 2.62
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Journal of Catalysis (acceptedVersion)
- Funders
- American Chemical Society Petroleum Research Fund (57079DNI5, CTS160041)
- National Science Foundation (1552517-CBET, ACI-1548562, SSZ-13)
- Purdue University
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Oxidation Reactions
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Keywords
- methanol dehydration, dimethyl ether, small-pore zeolites, Brønsted acid catalysis, methanol clusters, kinetic inhibition, CHA zeolite, zeolite A, kinetic model
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