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Novel electrodialysis cation exchange membrane prepared by 2-acrylamido-2-methylpropane sulfonic acid; heavy metal ions removal
Abstract
In the present work a novel heterogeneous cation exchange membrane (CEM) composed of poly vinyl chloride (PVC) and 2-acrylamido-2-methylpropane sulfonic acid based hydrogel (AMAH) was prepared. The membranes were fabricated with different fractions of AMAH to optimize the performance in desalination. The hydrogel was characterized by FT-IR to prove the successful synthesis. The membrane properties such as permselectivity, ionic permeability, flux, water content, electrical resistance, morphology, contact angle and dimensional stability were evaluated. Modified membranes showed acceptable dimensional stabilities, more hydrophilic surface, higher water content and porosity. SEM images revealed the formation of a more porous membrane structure. Membrane permselectivity and transport number showed a relatively constant then decreasing trend in Na+ and Ba 2+ solutions. The experimental results showed that the incorporation of AMAH into the PVC matrix obviously improved ionic permeability and flux of Na (∼9%) and Ba (∼23%). Membrane electrical resistance was declined about 36% by adding AMAH in the membrane structure. Membranes' performance in potassium and heavy metal ions removal showed a remarkable separation capacity of K+ (99.9%), Pb 2+ (99.9%) and Ni 2+ (96.9%). Membranes showed desirable potential for scaling removal.
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“ED has been used to separate Ni 2+ , Pb 2+, and K + from synthetic solution through a novel ED heterogeneous CEM (consisting of 2acrylamido-2-methyl propane sulfonic acid-based hydrogel and PVC) to attain extraction efficiency of 96.9%, 99.9%, and 99.9% for Ni 2+ , Pb 2+, and K + , respectively 67 .”
From Removal of heavy metal ions from wastewater: a comprehensive and critical review (2021) · cites this paper as [67]
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Metadata
- Authors
- Nemati, M., Hosseini, S. M., & Shabanian, M.
- Affiliations
- Arak University (IR)
- Standard Research Institute (IR)
- Corresponding author
- Hosseini, S.M.
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2017-09
- Volume
- 337
- Pages
- 90-104
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W2611023773
- Cited by
- 175
- References
- 45
- Citations by year
- 2026: 8 · 2025: 13 · 2024: 23 · 2023: 17 · 2022: 24 · 2021: 23 · 2020: 22 · 2019: 25 · 2018: 15 · 2017: 5
- FWCI
- 8.27
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Hazardous Materials (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Arak University
- Topics
- Physical Sciences › Chemical Engineering › Filtration and Separation › Membrane-based Ion Separation Techniques
- Physical Sciences › Environmental Science › Water Science and Technology › Membrane Separation Technologies
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Electrostatics and Colloid Interactions
- Keywords
- electrodialysis, cation exchange membrane, 2-acrylamido-2-methylpropane sulfonic acid, polyvinyl chloride, hydrogels, heavy metal ion removal, potassium removal, lead removal, nickel removal, desalination, permselectivity, ion permeability, membrane resistance
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