Cited by 175Membrane-based Ion Separation TechniquesMembrane Separation TechnologiesElectrostatics and Colloid Interactions

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Novel electrodialysis cation exchange membrane prepared by 2-acrylamido-2-methylpropane sulfonic acid; heavy metal ions removal

Nemati, M., Hosseini, S.M., Shabanian, M.·2017·Journal of Hazardous Materials

DOI 10.1016/j.jhazmat.2017.04.074

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Abstract

In the present work a novel heterogeneous cation exchange membrane (CEM) composed of poly vinyl chloride (PVC) and 2-acrylamido-2-methylpropane sulfonic acid based hydrogel (AMAH) was prepared. The membranes were fabricated with different fractions of AMAH to optimize the performance in desalination. The hydrogel was characterized by FT-IR to prove the successful synthesis. The membrane properties such as permselectivity, ionic permeability, flux, water content, electrical resistance, morphology, contact angle and dimensional stability were evaluated. Modified membranes showed acceptable dimensional stabilities, more hydrophilic surface, higher water content and porosity. SEM images revealed the formation of a more porous membrane structure. Membrane permselectivity and transport number showed a relatively constant then decreasing trend in Na+ and Ba 2+ solutions. The experimental results showed that the incorporation of AMAH into the PVC matrix obviously improved ionic permeability and flux of Na (∼9%) and Ba (∼23%). Membrane electrical resistance was declined about 36% by adding AMAH in the membrane structure. Membranes' performance in potassium and heavy metal ions removal showed a remarkable separation capacity of K+ (99.9%), Pb 2+ (99.9%) and Ni 2+ (96.9%). Membranes showed desirable potential for scaling removal.

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Authors: Nemati, M., Hosseini, S. M., & Shabanian, M.
Affiliations: Arak University (IR)
Standard Research Institute (IR)
Corresponding author: Hosseini, S.M.
ORCID: Hosseini, S.M.
Shabanian, M.
Venue: Journal of Hazardous Materials
Publisher: Elsevier BV
Published: 2017-09
Volume: 337
Pages: 90-104
ISSN: 0304-3894 (ISSN-L)
DOI: 10.1016/j.jhazmat.2017.04.074
OpenAlex: W2611023773
Cited by: 175
References: 45
Citations by year: 2026: 8 · 2025: 13 · 2024: 23 · 2023: 17 · 2022: 24 · 2021: 23 · 2020: 22 · 2019: 25 · 2018: 15 · 2017: 5
FWCI: 8.27
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Journal of Hazardous Materials (publishedVersion)
PubMed (publishedVersion)
Funders: Arak University
Topics: Physical Sciences › Chemical Engineering › Filtration and Separation › Membrane-based Ion Separation Techniques
Physical Sciences › Environmental Science › Water Science and Technology › Membrane Separation Technologies
Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Electrostatics and Colloid Interactions
Keywords: electrodialysis, cation exchange membrane, 2-acrylamido-2-methylpropane sulfonic acid, polyvinyl chloride, hydrogels, heavy metal ion removal, potassium removal, lead removal, nickel removal, desalination, permselectivity, ion permeability, membrane resistance

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Novel electrodialysis cation exchange membrane prepared by 2-acrylamido-2-methylpropane sulfonic acid; heavy metal ions removal

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