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Fabrication strategies and surface tuning of hierarchical gold nanostructures for electrochemical detection and removal of toxic pollutants
Abstract
The intensive research on the synthesis and characterization of gold (Au) nanostructures has been extensively documented over the last decades. These investigations allow the researchers to understand the relationships between the intrinsic properties of Au nanostructures such as particle size, shape, morphology, and composition to synthesize the Au nano/hybrid nanostructures with novel physicochemical properties. By tuning the properties above, these nanostructures are extensively employed to detect and remove trace amounts of toxic pollutants from the environment. This review attempts to document the achievements and current progress in Au-based nanostructures, general synthetic and fabrication strategies and their utilization in electrochemical sensing and environmental remediation applications. Additionally, the applications of Au nanostructures (e.g., as adsorbents, sensing platforms, catalysts, and electrodes) and advancements in the field of electrochemical sensing of different target analytes (e.g., proteins, nucleic acids, heavy metals, small molecules, and antigens) are summarized. The literature survey concludes the existing methods for the detection of toxic contaminants at various concentration levels. Finally, the existing challenges and future research directions on electrochemical sensing and degradation of toxic contaminants using Au nanostructures are defined.
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PLA and PLI differ in terms of the interaction of the incident laser beam on the surface of the target source.
“PLA and PLI differ in terms of the interaction of the incident laser beam on the surface of the target source.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [11]
Upon laser irradiation in liquid, solvated electrons and free radicals such as H• and OH• are generated, and e−liquid and H• act as reducing agents for reduction of metal salts into corresponding metal NPs.
“Upon laser irradiation in liquid (solvents: water or organic solvents), solvated electrons (e−liquid) and free radicals such as H•, and OH• are generated (Eq. (1)), where e−liquid and H• act as reducing agents for the reduction of metal salts into corresponding metal NPs, as shown in Eq. (2)1,11.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [11]
During PLI, formation of metal or alloy NPs via irradiation of nonfocused laser beams on metal salts as precursor solution is ascribed to optically induced decomposition of solvents without utilizing any other chemical reducing agents (photoreduction).
“During the PLI process, the formation of metal or alloy NPs via irradiation of nonfocused laser beams on the concerning metal salts as the precursor solution is ascribed to the optically induced decomposition of solvents without utilizing any other chemical reducing agents, which is called photoreduction.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [11]
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Zhu, C., Du, D., Eychmüller, A., & Lin, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00255 · Cited by 672
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Theerthagiri, J., Karuppasamy, K., Lee, S. J., Shwetharani, R., Kim, H.-S., Pasha, S. K. K., Ashokkumar, M., & Choi, M. Y. (2022) · Light: Science & Applications · doi:10.1038/s41377-022-00904-7 · Cited by 461
Self-citationLi, S., Qi, J., Zhou, B., Guo, J., Tong, Y., Zhou, Q., Jiang, L., Yang, R., Chen, C., Zhang, Y., et al. (2022) · Chemosphere · doi:10.1016/j.chemosphere.2022.134185 · Cited by 13
Metadata
- Authors
- Theerthagiri, J., Lee, S. J., Karuppasamy, K., Park, J., Yu, Y., Kumari, M. L. A., Chandrasekaran, S., Kim, H.-S., & Choi, M. Y.
- Affiliations
- Gyeongsang National University (KR)
- Dongguk University (KR)
- M S Ramaiah University of Applied Sciences (IN)
- King Abdulaziz University (SA)
- Corresponding author
- Choi, Myong Yong
- ORCID
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2021-10
- Volume
- 420
- Pages
- 126648
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W3180932404
- Cited by
- 85
- References
- 1
- Citations by year
- 2026: 5 · 2025: 8 · 2024: 14 · 2023: 16 · 2022: 28 · 2021: 14
- FWCI
- 1.31
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Journal of Hazardous Materials (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Electrochemistry › Electrochemical Analysis and Applications
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Gold and Silver Nanoparticles Synthesis and Applications
- Physical Sciences › Chemistry › Analytical Chemistry › Electrochemical sensors and biosensors
- Keywords
- gold nanostructures, hierarchical nanostructures, electrochemical sensing, environmental remediation, gold electrode, adsorbents, heavy metal detection, nucleic acid detection, protein detection, antigen detection, surface functionalization
- MeSH terms
- Catalysis, Electrodes, Environmental Pollutants, Gold, Biosensing Techniques, Nanostructures, Electrochemical Techniques
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