Anilido-aldimine aluminum complexes: Synthesis, characterization and lactide polymerization
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Trinuclear Zn complex 38 exhibited higher catalytic activity than did mononuclear complex 40.
“In rac-LA polymerization, trinuclear Zn complex 38 exhibited higher catalytic activity than did mononuclear complex 40”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [81]
The producing rac-PLAs catalyzed by trinuclear Zn complexes had accurate Mn GPC values that were similar with theoretical values, but their broad Ð values were observed.
“In addition, the producing rac-PLAs catalyzed by trinuclear Zn complexes had accurate Mn GPC values that were similar with theoretical values, but their broad Ð values were observed.”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [81]
Trinuclear Zn complex 39 also had higher catalytic activity than did mononuclear complex 41.
“and trinuclear Zn complex 39 also had higher catalytic activity than did mononuclear complex 41.”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [81]
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- Authors
- Allan, L. E. N., Bélanger, J. A., Callaghan, L. M., Cameron, D. J. A., Decken, A., & Shaver, M. P.
- Affiliations
- University of Prince Edward Island (CA)
- University of New Brunswick (CA)
- Corresponding author
- Shaver, Michael P.
- ORCID
- Shaver, Michael P.
- Venue
- Journal of Organometallic Chemistry
- Publisher
- Elsevier BV
- Published
- 2012-06
- Volume
- 706-707
- Pages
- 106-112
- ISSN
- 0022-328X (ISSN-L)
- OpenAlex
- W2023062863
- Cited by
- 22
- References
- 22
- Citations by year
- 2024: 2 · 2023: 1 · 2022: 2 · 2017: 2 · 2015: 4 · 2014: 1 · 2013: 8 · 2012: 1
- FWCI
- 1.81
- Type
- journal article
- Language
- en
- Open access
- Licence
- Locations
- Journal of Organometallic Chemistry (publishedVersion)
- Research Explorer (The University of Manchester) (submittedVersion)
- Edinburgh Research Explorer (University of Edinburgh) (submittedVersion, other-oa)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- ring-opening polymerization, rac-lactide, polylactic acid, crystal structure, polymerization kinetics, molecular weight distribution
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