Cited by 84biodegradable polymer synthesis and propertiesOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysis

Dinuclear vs. mononuclear complexes: accelerated, metal-dependent ring-opening polymerization of lactide

Normand, M., Roisnel, T., Carpentier, J.-F., Kirillov, E.·2013·Chemical Communications

Abstract

Dinuclear complexes of aluminum and indium with a bis(phenoxy-imine) platform have been synthesized and used in the polymerization of lactide. Kinetic studies demonstrate that the dialuminum precursor provides a more favorable reaction pathway in terms of activation free energy than that of directly related monoaluminum systems. No similar trend is observed with the corresponding diindium-monoindium systems, which is attributed to a dissimilar ROP mechanism.

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Crossref · 10.1039/c3cc47572g

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Authors
Normand, M., Roisnel, T., Carpentier, J.-F., & Kirillov, E.
Affiliations
Centre National de la Recherche Scientifique (FR)
Corresponding author
  • Carpentier, J.-F.
  • Kirillov, E.
Venue
Chemical Communications
Published
2013
Volume
49
Issue
99
Pages
11692
ISSN
  • 1359-7345 (ISSN-L)
  • 1364-548X
OpenAlex
W2111958604
Cited by
84
References
33
Citations by year
2026: 4 · 2025: 2 · 2024: 3 · 2023: 8 · 2022: 3 · 2021: 3 · 2020: 8 · 2019: 6 · 2018: 9 · 2017: 10 · 2016: 13 · 2015: 8 · 2014: 6
FWCI
3.43
Type
journal article
Language
en
Open access
closed
Locations
  • Chemical Communications (publishedVersion)
  • PubMed (publishedVersion)
  • HAL (submittedVersion)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
Keywords
ring-opening polymerization, lactide, dinuclear complexes, mononuclear complexes, polymerization kinetics, activation free energy, polymerization mechanism, metal-dependent catalysis

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