Dinuclear vs. mononuclear complexes: accelerated, metal-dependent ring-opening polymerization of lactide
Abstract
Dinuclear complexes of aluminum and indium with a bis(phenoxy-imine) platform have been synthesized and used in the polymerization of lactide. Kinetic studies demonstrate that the dialuminum precursor provides a more favorable reaction pathway in terms of activation free energy than that of directly related monoaluminum systems. No similar trend is observed with the corresponding diindium-monoindium systems, which is attributed to a dissimilar ROP mechanism.
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The CL polymerization activity of a dinuclear Al complex (complex 7) was more effective than that of a mononuclear Al complex (complex 8) because of the cooperation between two Al centers (Al-Al distance of complex 7 was 7.814 Å).
“illustrating that the CL polymerization activity of a dinuclear Al complex (complex 7) was more effective than that of a mononuclear Al complex (complex 8) because of the cooperation between two Al centers (Al-Al distance of complex 7 was 7.814 Å).”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [73]
Dinuclear complex 7 also exhibited superior controllability of producing PCL with a narrow Ð (1.19).
“In addition, dinuclear complex 7 also exhibited superior controllability of producing PCL with a narrow Ð (1.19).”
From Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers (2023) · cites this paper as [73]
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- Authors
- Normand, M., Roisnel, T., Carpentier, J.-F., & Kirillov, E.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Carpentier, J.-F.
- Kirillov, E.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 49
- Issue
- 99
- Pages
- 11692
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2111958604
- Cited by
- 84
- References
- 33
- Citations by year
- 2026: 4 · 2025: 2 · 2024: 3 · 2023: 8 · 2022: 3 · 2021: 3 · 2020: 8 · 2019: 6 · 2018: 9 · 2017: 10 · 2016: 13 · 2015: 8 · 2014: 6
- FWCI
- 3.43
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- ring-opening polymerization, lactide, dinuclear complexes, mononuclear complexes, polymerization kinetics, activation free energy, polymerization mechanism, metal-dependent catalysis
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