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The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.

Understanding High-Energy-Density Sn4P3 Anodes for Potassium-Ion Batteries

Open access
Zhang, Wenchao, Pang, Wei Kong, Sencadas, Vitor, Guo, Zaiping·2018·Joule

Abstract

Summary Phosphorus-based anodes for alkali metal-ion batteries are attractive due to their high theoretical-specific capacity. However, their poor electrochemical performance caused by relatively large volume variations during cycling, low electrical conductivity, and severe electrolyte decomposition due to highly reactive phosphide surface hinder their potential applications. Herein, we confine Sn 4 P 3 in N-doped carbon fibers as anode for potassium-ion batteries with enhanced cycling stability and high rate capability (160.7 mA hr g −1 after 1,000 cycles at 500 mA g −1 ). The Sn 4 P 3 anodes undergo a sequential conversion (P to K 3 P 11 , K 3 P) and alloying (Sn to KSn) reactions with synergistic K-storage mechanisms. Also, the electrolyte with potassium bis(fluorosulfonyl)imide salt can effectively suppress the dendrite growth in K stripping/plating, stabilize the solid-electrolyte interphase (SEI) layer, and avoid excessive side reactions, thus enhancing the electrode stability. This work provides a feasible approach to overcome the durability bottlenecks of K-ion batteries through regulating dendrite growth and SEI formation.

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Crossref · 10.1016/j.joule.2018.04.022

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Metadata

Authors
Zhang, W., Pang, W. K., Sencadas, V., & Guo, Z.
Venue
Joule
Publisher
Elsevier BV
Published
2018-08
Volume
2
Issue
8
Pages
1534-1547
ISSN
2542-4351 (ISSN-L)
OpenAlex
W2803798942
Cited by
555
References
24
FWCI
31.52
Type
journal article
Language
en
Open access
bronze

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Zhang, W., Pang, W. K., Sencadas, V., & Guo, Z. (2018). Understanding High-Energy-Density Sn4P3 Anodes for Potassium-Ion Batteries. Joule. https://doi.org/10.1016/j.joule.2018.04.022

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