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Enhanced performance of Li-ion cell with LiBF4-PC based electrolyte by addition of small amount of LiBOB

Zhang, S.S., Xu, K., Jow, T.R.·2006·Journal of Power Sources

DOI 10.1016/j.jpowsour.2005.04.023

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Shanbedi, M., Shahali, H., Polycarpou, A. A., & Amiri, A. (2025) · EES batteries. · doi:10.1039/d5eb00013k · Cited by 25
“188 Zhang et al. 189,190 also synthesized LiODFB, which demonstrated high capacity retention at − 30 °C. Adding 0.02 mol L − 1 LiBOB to LiBF 4 -based electrolytes enhances SEI formation and improves cycling performance at − 40 °C. Recently, LiTFSI and other organic lithium salts have gained popularity in ether-based a…”
Influential
Operation of rechargeable metal-ion batteries in low-temperature environments
Shi, X., Li, G., Zhang, R., Esan, O. C., Huo, X., Wu, Q., & An, L. (2023) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2023.113861 · Cited by 25
Research progress on preparation and purification of fluorine-containing chemicals in lithium-ion batteries
Liu, X., Gao, Z., Cheng, J., Gong, J., & Wang, J. (2021) · Chinese Journal of Chemical Engineering · doi:10.1016/j.cjche.2021.09.007 · Cited by 23
A high precision study of the electrolyte additives vinylene carbonate, vinyl ethylene carbonate and lithium bis(oxalate)borate in LiCoO 2 /graphite pouch cells
Wang, D. Y., Sinha, N., Burns, J. C., Petibon, R., & Dahn, J. R. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.07.053 · Cited by 23
The effect of LiBF4 concentration on the discharge and stability of LiMn2O4 half cell Li ion batteries
Karaal, Ş., Köse, H., Aydın, A. O., & Akbulut, H. (2015) · Materials Science in Semiconductor Processing · doi:10.1016/j.mssp.2015.04.018 · Cited by 22
Ultrathin LiF-rich solid electrolyte interphase for stable long-life cycling stabilization of lithium metal anodes
Zhang, D., Lv, P., Qin, W., & He, Y. (2024) · Electrochimica Acta · doi:10.1016/j.electacta.2024.144224 · Cited by 20
Recent progress in constructing fluorinated solid-electrolyte interphases for stable lithium metal anodes
Zhang, D., Lv, P., Qin, W., He, X., & He, Y. (2024) · International Journal of Minerals Metallurgy and Materials · doi:10.1007/s12613-024-2996-3 · Cited by 19
Nonaqueous Electrolytes: Advances in Lithium Salts
Henderson, W. (2014) · Modern aspects of electrochemistry · doi:10.1007/978-1-4939-0302-3_1 · Cited by 20
Comparative study on the ionic conductivities and redox properties of LiPF6 and LiTFSI electrolytes and the characteristics of their rechargeable lithium ion batteries
Septiana, A. R., Honggowiranto, W., Sudaryanto, S., Kartini, E., & Hidayat, R. (2018) · IOP Conference Series Materials Science and Engineering · doi:10.1088/1757-899x/432/1/012061 · Cited by 17
Surprising Dependence of the Exfoliation of Graphite During Formation on Electrolyte Composition
Zhang, N., Eldesoky, A., Dressler, R. A., & Dahn, J. R. (2023) · Journal of The Electrochemical Society · doi:10.1149/1945-7111/ace65c · Cited by 15
Synthesis, Water‐Removing Method and Influences of Trace Water for LiBF 4
Zhao, D., Lei, D., Wang, P., Li, S., Zhang, H., & Cui, X. (2019) · ChemistrySelect · doi:10.1002/slct.201900046 · Cited by 14
The effect of LiBF4 salt concentration in EC-DMC based electrolyte on the stability of nanostructured LiMn2O4 cathode
Dombaycıoğlu, Ş., Köse, H., Aydın, A. O., & Akbulut, H. (2016) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2016.03.165 · Cited by 14
Microemulsion Engineering Reconciles Propylene Carbonate Electrolytes and Graphite Anodes for All‐Climate Lithium‐Ion Batteries
Li, Z., Hu, X., Ji, H., Liao, Y., Dai, S., Kong, Y., Hao, S., Deng, X., Xie, Z., Fan, Y., et al. (2025) · Angewandte Chemie International Edition · doi:10.1002/anie.202516984 · Cited by 13
Lithium Difluoro(dioxalato) Phosphate as an Electrolyte Additive for NMC811/Graphite Li-ion Pouch Cells
Song, W., Gauthier, R., Taskovic, T., Ouyang, D., Ingham, H., Eldesoky, A., Azam, S. M., Zsoldos, E. S., Deng, Z., Heino, D., et al. (2022) · Journal of The Electrochemical Society · doi:10.1149/1945-7111/ac96aa · Cited by 13
Exploring the Effects of Dopamine and DMMP Additives on Improving the Cycle Boosting and Nonflammability of Electrolytes in Full-Cell Lithium-Ion Batteries (18650)
Ajdari, F. B., Zonouz, A. F., Heydari, A., Mehrabani, H., Shakourian‐Fard, M., Kamath, G., Ghasemi, F., & Kahrizi, M. (2023) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.2c08293 · Cited by 12
Elucidating Failure Mechanisms in Li-ion Batteries Operating at 100 °C
Hawkins, B. E., Asare, H., Chen, B., Messinger, R. J., West, W. C., & Jones, J. (2023) · Journal of The Electrochemical Society · doi:10.1149/1945-7111/acfc36 · Cited by 12
Assessment of the formation process effect on the lithium-ion battery performance at low temperatures
Zarei-Jelyani, M., Babaiee, M., Baktashian, S., Eqra, R., & Shirani-Faradonbeh, H. (2023) · Journal of materials science. Materials in electronics · doi:10.1007/s10854-023-11311-y · Cited by 12
“Zhang et al. [35] considerably enhanced the SEI formation ability of LiBF 4 on graphite anode using 1–5% bis(oxalate)borate (LiBOB).”
Method
A novel Et4NBF4 and LiPF6 blend salts electrolyte for supercapacitor battery
Liu, S., Liu, J., Ke-long, H., Liu, J., Li, Y., Fang, D., Wang, H., & Xia, Y. (2011) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-011-1573-7 · Cited by 12
Potential-Controlled Switchable-Resistance Polymer Layer for Enhanced Safety of Lithium-Ion Batteries with NMC-Type Cathodes
Beletskii, E. V., Volkov, A. I., Alekseeva, E. V., Anishchenko, D. V., Konev, A. S., & Levin, O. V. (2023) · ACS Applied Energy Materials · doi:10.1021/acsaem.3c02145 · Cited by 10
“Within this approach, specific electrolyte additives prevent lithium dendrite formation, 8 − 10 either polymerizable electrolyte additives 11 − 13 or fusible separators 14 − 16 trigger the device shutdown at thermal extremes, while voltage-sensitive separators 17,18 and redox shuttle electrolyte…”
Background
A review on electrode and electrolyte for lithium ion batteries under low temperature
Li, Y., Zheng, G., Liu, G., Yuan, Z., Huang, X., & Li, Y. (2023) · Electroanalysis · doi:10.1002/elan.202300042 · Cited by 9
Effect of covalently bonded polysiloxane multilayers on the electrochemical behavior of graphite electrode in lithium ion batteries
Pan, Q., & Jiang, Y. (2007) · Journal of Power Sources · doi:10.1016/j.jpowsour.2007.12.025 · Cited by 9
FTIR spectroscopic study of Li+ solvation in the solutions of LiBF4 in propylene carbonate, dimethyl sulfoxide, and their mixtures
Zhang, B., Li, Y., & Hou, B. (2017) · Russian Journal of Physical Chemistry A · doi:10.1134/s003602441707007x · Cited by 8
Specific Features in the Low-Temperature Performance of Electrodes of Lithium-Ion Battery
Kuz’mina, A. A., Kulova, T. L., Tuseeva, E. K., & Chirkova, E. V. (2020) · Russian Journal of Electrochemistry · doi:10.1134/s1023193520100067 · Cited by 6
Alternative pulse current discharge strengthens solid electrolyte interphase to prolong cycle stability of propylene carbonate-based batteries
He, J., Li, S.-Y., Liu, Y., Pang, Y., Yang, H.-H., Yang, C., Zhang, N.-S., Zhao, D.-N., Wang, P., Li, H., et al. (2026) · Energy Storage Materials · doi:10.1016/j.ensm.2026.105226 · Cited by 13
Microemulsion Engineering Reconciles Propylene Carbonate Electrolytes and Graphite Anodes for All-Climate Lithium-Ion Batteries.
Li, Z.-Z., Hu, X., Ji, H.-J., Liao, Y.-Q., Dai, S., Kong, Y.-L., Hao, S.-P., Deng, X., Xie, Z., Fan, Y.-X., et al. (2025) · Angewandte Chemie · doi:10.1002/ange.202516984 · Cited by 11
Fabricating LiN3-doped polymer nanofiber enhances uniform lithium deposition for dendrite-free Li metal batteries
You, L., Wu, S., Xiong, Y., Yang, Q., Gong, Z., Lei, D., Zheng, Y., & Liu, J.-W. (2025) · Journal of Power Sources · doi:10.1016/j.jpowsour.2025.236210 · Cited by 4
Efek Penggunaan Cairan Ionik sebagai Aditif terhadap Konduktivitas Ionik Elektrolit Baterai Ion Litium
Septiana, A. R., Kartini, E., Honggowiranto, W., Sudaryanto, S., & Hidayat, R. (2019) · INDONESIAN JOURNAL OF APPLIED PHYSICS · doi:10.13057/ijap.v9i02.31700 · Cited by 4

Authors: Zhang, S. S., Xu, K., & Jow, T. R.
Affiliations: DEVCOM Army Research Laboratory (US)
Corresponding author: Zhang, S.S.
ORCID: Zhang, S.S.
Xu, K.
Jow, T.R.
Venue: Journal of Power Sources
Publisher: Elsevier BV
Published: 2006-06
Volume: 156
Issue: 2
Pages: 629-633
ISSN: 0378-7753 (ISSN-L)
DOI: 10.1016/j.jpowsour.2005.04.023
OpenAlex: W2084447311
Cited by: 108
References: 18
Citations by year: 2026: 2 · 2025: 6 · 2024: 9 · 2023: 14 · 2022: 7 · 2021: 6 · 2020: 6 · 2019: 7 · 2018: 2 · 2017: 9 · 2016: 4 · 2015: 6 · 2014: 9 · 2013: 5 · 2012: 2
FWCI: 1.27
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Journal of Power Sources (publishedVersion)
Topics: Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
Keywords: lithium-ion batteries, solid electrolyte interphase, graphite anode, high current density, electrolyte additives, ethylene carbonate, ethyl methyl carbonate

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Enhanced performance of Li-ion cell with LiBF4-PC based electrolyte by addition of small amount of LiBOB

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