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Hollow Mo-doped CoP nanoarrays for efficient overall water splitting

Guan, Cao, Xiao, Wen, Wu, Haijun, Liu, Ximeng, Zang, Wenjie, Zhang, Hong, Ding, Jun, Feng, Yuan Ping, Pennycook, Stephen J., Wang, John·2018·Nano Energy

Abstract

Abstract Earth-abundant, efficient and durable electrocatalysts for water splitting are vitally important for a sustainable energy system. Here we report the rational design of hollow Mo-doped CoP (Mo-CoP) nanoarrays, which simultaneously combine electronic structure modification through doping with a high density of reaction sites through nanostructuring. With this strategy the Mo-CoP arrays give significantly improved hydrogen evolution reaction (HER) performance, and also, when in situ transformed into Mo-doped CoOOH (Mo-CoOOH) arrays, excellent activity towards the oxygen evolution reaction (OER) is obtained. The origin of the improvement is determined by atomic-resolution imaging combined with density functional theory (DFT). An electrolyzer using Mo-CoP and Mo-CoOOH can be powered by a single AA battery (~1.5 V), and maintains a stable water-splitting current for 20 h, superior to most reported electrocatalysts in alkaline media, offering great promise for practical applications.

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Metadata

Authors
Guan, C., Xiao, W., Wu, H., Liu, X., Zang, W., Zhang, H., Ding, J., Feng, Y. P., Pennycook, S. J., & Wang, J.
Venue
Nano Energy
Publisher
Elsevier BV
Published
2018-06
Volume
48
Pages
73-80
ISSN
2211-2855 (ISSN-L)
OpenAlex
W2793942641
Cited by
716
References
12
FWCI
22.23
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Hollow Mo-doped CoP nanoarrays for efficient overall water splitting. https://app.cochat.ai/papers/10.1016/j.nanoen.2018.03.034
The paper
Guan, C., Xiao, W., Wu, H., Liu, X., Zang, W., Zhang, H., Ding, J., Feng, Y. P., Pennycook, S. J., & Wang, J. (2018). Hollow Mo-doped CoP nanoarrays for efficient overall water splitting. Nano Energy. https://doi.org/10.1016/j.nanoen.2018.03.034

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