A generalizable strategy toward highly tough and heat-resistant stereocomplex-type polylactide/elastomer blends with substantially enhanced melt processability
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The application of sc-PLA materials is limited by its weak melt memory effect in triggering complete sc-crystallization and inherent brittleness.
“However, the application of sc-PLA materials in more fields obviously is limited due to its weak melt memory effect in triggering complete sc-crystallization and inherent brittleness.”
From Crystallization, thermal and mechanical properties of stereocomplexed poly(lactide) with flexible PLLA/PCL multiblock copolymer (2022) · cites this paper as [18]
The weak melt memory effect of sc-PLA often results in sc-crystallization accompanied by large hc-crystallization during melt processing, so the performance of the prepared product is far from expected.
“The weak melt memory effect of sc-PLA often results in sc-crystallization accompanied by large hc-crystallization during melt processing, so the performance of the prepared product is far from that expected.18,19”
From Crystallization, thermal and mechanical properties of stereocomplexed poly(lactide) with flexible PLLA/PCL multiblock copolymer (2022) · cites this paper as [18]
The synthesized multi-block copolymer acts as a compatibilizer to stabilize the regular PLLA/PDLA chain clusters in the melt blends, thereby promoting the exclusive formation of sc-crystals in the melt-processed blend products.
“These results indicate that the synthesized multi-block copolymer acts as a compatibilizer to stabilize the regular PLLA/PDLA chain clusters in the melt blends (as Fig. 1(b)), thereby promoting the exclusive formation of sc-crystals in the melt-processed blend products.18”
From Crystallization, thermal and mechanical properties of stereocomplexed poly(lactide) with flexible PLLA/PCL multiblock copolymer (2022) · cites this paper as [18]
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- Authors
- Deng, S., Yao, J., Bai, H., Xiu, H., Zhang, Q., & Fu, Q.
- Affiliations
- Sichuan University (CN)
- Corresponding author
- Bai, Hongwei
- Fu, Qiang
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2021-05
- Volume
- 224
- Pages
- 123736
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W3141154401
- Cited by
- 45
- References
- 57
- Citations by year
- 2026: 4 · 2025: 11 · 2024: 5 · 2023: 7 · 2022: 14 · 2021: 4
- FWCI
- 1.96
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Polymer (publishedVersion)
- Funders
- National Natural Science Foundation of China (51873129)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- stereocomplex polylactide, PLLA/PDLA blends, ethylene-vinyl acetate copolymer, graft copolymers, melt processability, compatibilization, impact toughness, heat resistance, long-chain branching, stereocomplexation, injection molding
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