Co-etching effect to convert waste polyethylene terephthalate into hierarchical porous carbon toward excellent capacitive energy storage
Abstract
With the ever-increasing consumption of polyethylene terephthalate (PET) related products, how to recycle the waste PET still remains as a great challenge for the sustainable development. Converting waste PET into porous carbon material has been emerged as a promising way to address this issue. Recently, the microporous carbon derived from waste PET has drawn considerable attention in adsorption field, but its electrochemical application is still impeded by low specific surface area (SSA <1500 m 2 g-1) and small meso-/macropores volume (<0.2 cm 3 g-1). Herein, hierarchical porous carbon (HPC) is successfully prepared from waste PET. The obtained HPC possesses a high SSA (2238 m 2 g-1) and a large meso-/macropores volume (0.51 cm 3 g-1). The formation mechanism of hierarchical porous structure is proposed: co-etching effect of sp 2/sp 3 hybridized carbon produces micropores and meso-/macropores, respectively. In a three-electrode configuration, HPC based electrode achieves an outstanding capacitance of 413 F g-1, while the traditional microporous carbon exhibits a low capacitance of 142 F g-1. The fabricated symmetric supercapacitor shows a high energy density of 25 Wh kg-1. This work provides a good reference to convert waste plastics into hierarchical porous carbon.
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Shear milling is suitable for reducing plastic size due to the good flexibility of waste plastics, for example flexible polyethylene terephthalate and polyvinyl chloride.
“Shear milling is suitable for reducing plastic size due to the good flexibility of waste plastics, for example flexible polyethylene terephthalate and polyvinyl chloride (Liu et al. 2020(Liu et al. , 2022b)).”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Liu et al. 2020
Oxygen-limited carbonization of polyethylene terephthalate in a quartz tube furnace at 773 K for 1 h produces porous carbon (Liu et al., 2020).
“| Oxygen-limited | Polyethylene tere- | Quartz tube | 773 K, 1 h | Porous carbon | - | Liu et al. (2020) |”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Liu et al. (2020)
Two carbonization temperatures affect the properties of carbon materials prepared from waste plastics (Liu et al., 2020).
“Effects of two carbonization temperatures on the properties of carbon materials prepared from waste plastics.Reprinted with permission of Elsevier fromLiu et al. (2020)”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Liu et al. (2020)
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- Authors
- Liu, X., Wen, Y., Chen, X., Tang, T., & Mijowska, E.
- Affiliations
- West Pomeranian University of Technology in Szczecin (PL)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Chen, Xuecheng
- Venue
- Science of The Total Environment
- Publisher
- Elsevier BV
- Published
- 2020-06
- Volume
- 723
- Pages
- 138055
- ISSN
- 0048-9697 (ISSN-L)
- OpenAlex
- W3011684790
- Cited by
- 117
- References
- 59
- Citations by year
- 2026: 11 · 2025: 24 · 2024: 24 · 2023: 14 · 2022: 17 · 2021: 19 · 2020: 8
- FWCI
- 9.99
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Science of The Total Environment (publishedVersion)
- PubMed (publishedVersion)
- Funders
- State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials (17kffk02)
- Narodowe Centrum Nauki (UMO-2015/18/E/ST8/00291)
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › MXene and MAX Phase Materials
- Keywords
- PET waste, hierarchical porous carbon, plastic recycling, supercapacitor electrodes, symmetric supercapacitor, specific surface area, capacitive energy storage, microporous carbon
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