Catalytic depolymerisation and conversion of Kraft lignin into liquid products using near-critical water
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In Nguyen et al. [114], raising the initial K2CO3 concentration from 0.4 wt.% to 2.2 wt.% increased the yield of 1-phenolic compounds from 16.9 wt.% to 27.1 wt.%.
“Raising the initial K 2 CO 3 concentration from 0.4 wt.% to 2.2 wt.% increased the yield of 1-phenolic compounds from 16.9 wt.% to 27.1 wt.%.”
From Sub- and Supercritical Water Liquefaction of Kraft Lignin and Black Liquor Derived Lignin (2020) · cites this paper as [114]
Table 11 (in the Conclusions section) reports that increasing feed K₂CO₃ from 0.4% to 2.2% raised the yield from 16.9% to 27.1% on a dry-lignin basis. But it labels those figures the total yield of 1-ring aromatic compounds, which includes anisoles; they are not specifically the yield of phenolic compounds. (LLM, conf=0.86)
Experimental — accuracy not yet measuredIn Nguyen et al. [114], increasing the initial K2CO3 concentration from 0.4 wt.% to 2.2 wt.% did significantly affect the proportion of suspended solids in the bio-oil fraction, which increased from 0.1 wt.% to 22.9 wt.%.
“However, increasing the initial K 2 CO 3 concentration from 0.4 wt.% to 2.2 wt.% did significantly affect the proportion of suspended solids in the bio-oil fraction, which increased from 0.1 wt.% to 22.9 wt.%.”
From Sub- and Supercritical Water Liquefaction of Kraft Lignin and Black Liquor Derived Lignin (2020) · cites this paper as [114]
In Nguyen et al. [114], the yields of bio-oil, WSO and char were relatively stable as the initial K2CO3 concentration rose from 0.4 wt.% to 2.2 wt.%.
“The yields of bio-oil, WSO and char were relatively stable as the initial K 2 CO 3 concentration rose from 0.4 wt.% to 2.2 wt.%.”
From Sub- and Supercritical Water Liquefaction of Kraft Lignin and Black Liquor Derived Lignin (2020) · cites this paper as [114]
In Nguyen et al. [114], the yields were 69.4-72.2 wt.% for bio-oil, 8.7-10.8 wt.% for WSO, and 17.2-20.7 wt.% for char.
“The yields were 69.4-72.2wt.% for bio-oil, 8.7-10.8wt.% for WSO, and 17.2-20.7 wt.% for char.”
From Sub- and Supercritical Water Liquefaction of Kraft Lignin and Black Liquor Derived Lignin (2020) · cites this paper as [114]
In Nguyen et al. [114], although the elemental composition of the bio-oil did not change significantly with different initial concentrations of K2CO3, the amount of ash in the bio-oil increased from 1.0 wt.% to 3.5 wt.% when the initial concentration of K2CO3 increased from 0.4 wt.% to 2.2 wt.%.
“Although the elemental composition of the bio-oil did not change significantly with different initial concentrations of K 2 CO 3 , the amount of ash in the bio-oil increased from 1.0 wt.% to 3.5 wt.%, when the initial concentration of K 2 CO 3 increased from 0.4 wt.% to 2.2 wt.%.”
From Sub- and Supercritical Water Liquefaction of Kraft Lignin and Black Liquor Derived Lignin (2020) · cites this paper as [114]
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- Authors
- Nguyen, T. D. H., Maschietti, M., Belkheiri, T., Åmand, L.-E., Theliander, H., Vamling, L., Olausson, L., & Andersson, S.-I.
- Affiliations
- Chalmers University of Technology (SE)
- Metso (Sweden) (SE)
- Corresponding author
- Maschietti, Marco
- Venue
- The Journal of Supercritical Fluids
- Publisher
- Elsevier BV
- Published
- 2014-02
- Volume
- 86
- Pages
- 67-75
- ISSN
- 0896-8446 (ISSN-L)
- OpenAlex
- W1997393803
- Cited by
- 99
- References
- 19
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 2 · 2023: 8 · 2022: 7 · 2021: 10 · 2020: 15 · 2019: 7 · 2018: 15 · 2017: 8 · 2016: 15 · 2015: 4 · 2014: 4
- FWCI
- 4.23
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- The Journal of Supercritical Fluids (publishedVersion)
- Chalmers Research (Chalmers University of Technology) (submittedVersion)
- Funders
- Energimyndigheten
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Lignin and Wood Chemistry
- Physical Sciences › Engineering › Biomedical Engineering › Subcritical and Supercritical Water Processes
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Keywords
- kraft lignin, lignin depolymerization, near-critical water, catalytic conversion, bio-oil, zirconia catalysts, potassium carbonate, phenols, fixed-bed reactor, alkylphenols, guaiacol, catechol, anisole, lignin valorization
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