Cited by 1,408Arsenic contamination and mitigationHeavy metals in environmentCoal and Its By-products

Arsenic fractionation in soils using an improved sequential extraction procedure

Wenzel, Walter W, Kirchbaumer, Natalie, Prohaska, Thomas, Stingeder, Gerhard, Lombi, Enzo, Adriano, Domy C·2001·Analytica Chimica Acta

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Crossref · 10.1016/s0003-2670(01)00924-2

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  • Wenzel et al. (2001) developed an innovative and simple method for arsenic sequential extraction which provides five extraction steps with reagents gradually stronger.

    “Wenzel et al . (2001) have developed an innovative and simple method for arsenic sequential extraction which provides the following five extraction steps with reagents gradually stronger (Table 4):”

    From MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS (2010) · cites this paper as Wenzel et al., 2001

  • The fine As fractions appear to be primarily associated with (1) nonspecifically sorbed; (2) specifically sorbed; (3) amorphous and poorly-crystalline hydrous Fe and Al oxides; (4) well crystallized hydrous Fe and Al oxides; and (5) residual phases.

    “These fine As fractions appear to be primarily associated with (1) nonspecifically sorbed; (2) specifically sorbed; (3) amorphous and poorly-crystalline hydrous Fe and Al oxides; (4) well crystallized hydrous Fe and Al oxides l; and (5) residual phases.”

    From MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS (2010) · cites this paper as Wenzel et al., 2001

  • The amount of readily labile As extracted by (NH4)2SO4 is generally small (0.3%).

    “The amount of readily labile As extracted by (NH 4 ) 2 SO4 is generally small (0.3%)”

    From MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS (2010) · cites this paper as Wenzel et al., 2001

  • The readily labile As fraction has been shown to correlate well with As concentrations in field-collected soil solutions.

    “and has been shown to correlate well with As concentrations in field -collected soil solutions.”

    From MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS (2010) · cites this paper as Wenzel et al., 2001

  • In 20 Austrian soils differing in As contamination (96 to 218 mg As kg-1) and soil characteristics, As was most prevalent in the two oxalate extractable fractions (30% from step 3 and 27% from step 4).

    “The results showed that As was most prevalent in the two oxalate extractable fractions (30% from step 3 and 27% from step 4)”

    From MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS (2010) · cites this paper as Wenzel et al., 2001

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Authors
Wenzel, W. W., Kirchbaumer, N., Prohaska, T., Stingeder, G., Lombi, E., & Adriano, D. C.
Affiliations
  • BOKU University (AT)
  • Rothamsted Research (GB)
  • University of Georgia (US)
Venue
Analytica Chimica Acta
Publisher
Elsevier BV
Published
2001-06
Volume
436
Issue
2
Pages
309-323
ISSN
0003-2670 (ISSN-L)
OpenAlex
W2030112809
Cited by
1,408
References
0
Citations by year
2026: 67 · 2025: 91 · 2024: 97 · 2023: 102 · 2022: 116 · 2021: 82 · 2020: 81 · 2019: 86 · 2018: 78 · 2017: 77 · 2016: 71 · 2015: 57 · 2014: 61 · 2013: 46 · 2012: 29
FWCI
8.04
Type
journal article
Language
en
Open access
closed
Locations
  • Analytica Chimica Acta (publishedVersion)
  • Rothamsted Repository (Rothamsted Repository) (submittedVersion)
Funders
Biotechnology and Biological Sciences Research Council
Topics
  • Physical Sciences › Environmental Science › Environmental Chemistry › Arsenic contamination and mitigation
  • Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
  • Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Coal and Its By-products
Keywords
arsenic, arsenic speciation, arsenic bioavailability, soil contamination risk assessment, energy-dispersive X-ray microanalysis, microwave digestion

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