Arsenic speciation analysis
Abstract
Nearly two dozen arsenic species are present in the environmental and biological systems. Differences in their toxicity, biochemical and environmental behaviors require the determination of these individual arsenic species. Considerable analytical progresses have been made toward arsenic speciation analysis over the last decade. Hyphenated techniques involving a highly efficient separation and a highly sensitive detection have become the techniques of choice. Methods based on high-performance liquid chromatography separation with inductively coupled plasma mass spectrometry, hydride generation atomic spectrometry, and electrospray mass spectrometry detection have been shown most useful for arsenic speciation in environmental and biological matrices. These hyphenated techniques have resulted in the determination of new arsenic species, contributing to a better understanding of arsenic metabolism and biogeochemical cycling. Methods for extracting arsenic species from solid samples and for stabilizing arsenic species in solutions are required for obtaining reliable arsenic speciation information.
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The bioavailability of metal(loid)s is closely interlinked with their chemical speciation.
“many scientific studies demonstrated that the bioavailability of the metal(loid)s is closely interlinked with their chemical speciation [82 -85].”
From Chemical Processes Affecting the Mobility of Heavy Metals and Metalloids in Soil Environments (2016) · cites this paper as [82]
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- Authors
- Gong, Z.
- Affiliations
- University of Alberta (CA)
- Corresponding author
- Gong, Z
- Venue
- Talanta
- Publisher
- Elsevier BV
- Published
- 2002-08-16
- Volume
- 58
- Issue
- 1
- Pages
- 77-96
- ISSN
- 0039-9140 (ISSN-L)
- OpenAlex
- W2015011264
- Cited by
- 382
- References
- 153
- Citations by year
- 2026: 7 · 2025: 3 · 2024: 7 · 2023: 9 · 2022: 5 · 2021: 11 · 2020: 8 · 2019: 10 · 2018: 11 · 2017: 18 · 2016: 24 · 2015: 24 · 2014: 16 · 2013: 16 · 2012: 21
- FWCI
- 17.67
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Talanta (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Canada Research Chairs
- Canadian Water Network
- Natural Sciences and Engineering Research Council of Canada
- Topics
- Physical Sciences › Environmental Science › Environmental Chemistry › Arsenic contamination and mitigation
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Chemistry › Spectroscopy › Analytical Chemistry and Chromatography
- Keywords
- arsenic speciation, arsenic species, hyphenated analytical techniques, HPLC-ICP-MS, electrospray ionization mass spectrometry, environmental arsenic, arsenic extraction, arsenic immobilization, arsenic metabolism, biogeochemical cycles
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