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Low temperature performance of graphite electrode in Li-ion cells
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“However, the capacity of LIB drops dramatically at low temperatures (LTs) below 0 °C, thus restricting its applications as a reliable power source for electric vehicles in cold climates and equipment used in the aerospace.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [3]
In the citing paper
“As reported in early 2000, most graphite anode materials can only deliver 12% of room-temperature (RT) capacity when both lithiation and delithiation were carried out at -20 °C [3].”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [3]
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“Additionally, in the electrode, the lithiation process normally proceeds more slowly than the delithiation below − 20 °C [21].”
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Self-citationAdvances in internal temperature measurement and estimation for lithium-ion batteries
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“However, the Li-ion battery performance, cycle life and capacity are adversely affected by sustained operation at sub zero temperature and at high temperature (over 45◦C) [3]–[6].”
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“…the LiB exhibits sluggish chemical reaction activity and slower charge transfer rates, which will lead to a reduction in the ionic conductivity of the electrolyte and a decrease in the diffusion rate of lithium ions within the electrodes, consequently diminishing the activity of LiBs [6,7] .”
BackgroundTemperature-Dependent Thévenin Model of a Li-Ion Battery for Automotive Management and Control
Rizzello, A., Scavuzzo, S., Ferraris, A., Airale, A., & Carello, M. (2020) · 2020 IEEE International Conference on Environment and Electrical Engineering and 2020 IEEE Industrial and Commercial Power Systems Europe (EEEIC / I&CPS Europe) · doi:10.1109/eeeic/icpseurope49358.2020.9160544 · Cited by 10
“At low operation temperature, a reduction of chemical-reaction activity and charge-transfer velocity [6] occurs, which means a lower ionic conductivity in the electrolyte [8] and a reduction of lithium-ion diffusivity in the electrodes [9].”
BackgroundCapron, O., Jaguemont, J., Gopalakrishnan, R., den Bossche, P. V., Omar, N., & Mierlo, J. V. (2018) · Applied Sciences · doi:10.3390/app8081364 · Cited by 10
Material parameters affecting Li plating in Si/graphite composite electrodes
Boveleth, L., Lindner, A., Menesklou, W., Danner, T., & Latz, A. (2024) · Electrochimica Acta · doi:10.1016/j.electacta.2024.145010 · Cited by 9
Ruan, H., Sun, B., Jiang, J.-C., Su, X., He, X.-T., Ma, S., & Gao, W.-Z. (2023) · Journal of Power Sources · doi:10.1016/j.jpowsour.2023.232775 · Cited by 9
Zhang, T., & Guo, Z. (2014) · Modelling and Simulation in Materials Science and Engineering · doi:10.1088/0965-0393/22/2/025016 · Cited by 8
Selinis, P., & Farmakis, F. (2024) · International Journal of Heat and Mass Transfer · doi:10.1016/j.ijheatmasstransfer.2024.125707 · Cited by 9
Effect of low temperature aging on thermal stability of lithium-ion batteries
Bai, J.-L., Gao, T.-F., Bai, W., Wang, J.-L., & Wang, Z.-R. (2025) · Thermal Science and Engineering Progress · doi:10.1016/j.tsep.2025.104291 · Cited by 8
Song, Y.-M., Liu, Y.-J., Zhou, X., Huang, X., Zhou, C., & Jin, G. (2024) · Journal of Energy Storage · doi:10.1016/j.est.2024.112567 · Cited by 8
Bauer, M. K. G., & Dahn, J. (2021) · doi:10.1149/1945-7111/abdde4 · Cited by 8
A Recurrent Neural Networks Approach for Estimating the Core Temperature in Lithium-Ion Batteries
Ojo, O., Lin, X.-K., Lang, H., & Kim, Y. (2020) · Progress in Canadian Mechanical Engineering. Volume 3 · doi:10.32393/csme.2020.130 · Cited by 7
The Roles of Electrolyte Additives on Low-temperature Performances of Graphite Negative Electrode
Park, S., Ryu, J., & Oh, S. M. (2012) · doi:10.5229/jkes.2012.15.1.019 · Cited by 7
Metadata
- Authors
- Zhang, S. S., Xu, K., & Jow, T. R.
- Affiliations
- DEVCOM Army Research Laboratory (US)
- Corresponding author
- Zhang, S.S
- Venue
- Electrochimica Acta
- Publisher
- Elsevier BV
- Published
- 2002-12
- Volume
- 48
- Issue
- 3
- Pages
- 241-246
- ISSN
- 0013-4686 (ISSN-L)
- OpenAlex
- W2036172814
- Cited by
- 311
- References
- 0
- Citations by year
- 2026: 10 · 2025: 33 · 2024: 19 · 2023: 48 · 2022: 30 · 2021: 28 · 2020: 29 · 2019: 22 · 2018: 11 · 2017: 14 · 2016: 15 · 2015: 10 · 2014: 10 · 2013: 8 · 2012: 5
- FWCI
- 2.45
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Electrochimica Acta (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- lithium-ion batteries, graphite anode, low-temperature performance, lithium ion diffusion, diffusion coefficient, capacity retention, cycling behavior, solid electrolyte interphase, ionic conductivity
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