Release of bound aromatic hydrocarbons from late Archean and Mesoproterozoic kerogens via hydropyrolysis
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Low molecular mass aromatics (≤C16) predominate over high molecular mass PAHs (>C16), and nonalkylated parent PAHs are more abundant than alkylated PAHs in the AIDP samples and in previous Archean reports.
“Like the PAHs and diamondoids that previous studies reported in Archean rock extracts and hydropyrolysates (3,21,24,28), the low molecular mass aromatics (≤C 16 ) predominate over high molecular mass PAHs (>C 16 ), and nonalkylated parent PAHs are in greater abundance compared with alkylated PAH (SI Appendix, Figs.S4 and S5 and Tables S8 and S10).”
From Reappraisal of hydrocarbon biomarkers in Archean rocks (2015) · cites this paper as [24]
These three compounds are the most 13C-depleted PAHs reported from Archean rock extracts.
“These three compounds are the most 13 C-depleted PAHs that have been reported from Archean rock extracts (21,24,25).”
From Reappraisal of hydrocarbon biomarkers in Archean rocks (2015) · cites this paper as [24]
Hopanes and steranes were not detected in hydropyrolysates from AIDP-2 or AIDP-3.
“In agreement with previous HyPy studies of Archean rocks (24), hopanes and steranes were not detected in hydropyrolysates from AIDP-2 or AIDP-3.”
From Reappraisal of hydrocarbon biomarkers in Archean rocks (2015) · cites this paper as [24]
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- Authors
- Brocks, J. J., Love, G. D., Snape, C. E., Logan, G. A., Summons, R. E., & Buick, R.
- Affiliations
- Harvard University (US)
- Newcastle University (GB)
- University of Nottingham (GB)
- Geoscience Australia (AU)
- Massachusetts Institute of Technology (US)
- University of Washington (US)
- Corresponding author
- Brocks, Jochen J
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2003-04
- Volume
- 67
- Issue
- 8
- Pages
- 1521-1530
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W2171189696
- Cited by
- 103
- References
- 29
- Citations by year
- 2025: 3 · 2024: 5 · 2023: 2 · 2022: 2 · 2021: 2 · 2020: 5 · 2019: 6 · 2018: 6 · 2017: 4 · 2016: 4 · 2015: 7 · 2014: 8 · 2013: 4 · 2012: 3
- FWCI
- 9.21
- Type
- journal article
- Language
- en
- Open access
- green
- doi.org
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- ANU Open Research (Australian National University) (submittedVersion)
- Newcastle University ePrints (Newcastle Univesity)
- Topics
- Physical Sciences › Engineering › Mechanics of Materials › Hydrocarbon exploration and reservoir analysis
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Coal and Its By-products
- Keywords
- hydropyrolysis, bitumen, phenanthrene, pyrene, polycyclic aromatic hydrocarbons, iron ore deposits, Roper Group, McArthur Basin, carbon isotopes
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