Millimeter-scale concentration gradients of hydrocarbons in Archean shales: Live-oil escape or fingerprint of contamination?
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Hopanes and steranes in Archean rocks have been put forward as major evidence for an early emergence of oxygenic photosynthesis and eukaryotes, but whether they are syngenetic is debated.
“Hopanes and steranes found in Archean rocks have been presented as key evidence supporting the early rise of oxygenic photosynthesis and eukaryotes, but the syngeneity of these hydrocarbon biomarkers is controversial.”
From Reappraisal of hydrocarbon biomarkers in Archean rocks (2015) · cites this paper as [11]
The interpretation of the Archean biomarker record is controversial, with recent arguments that the hydrocarbons are not syngenetic.
“However, the interpretation of the Archean biomarker record has become controversial, with recent arguments for a nonsyngenetic origin of these hydrocarbons (10,11).”
From Reappraisal of hydrocarbon biomarkers in Archean rocks (2015) · cites this paper as [11]
These patterns support earlier observations that biomarkers and bitumen are enriched on surfaces of conventionally drilled and curated samples relative to their interiors.
“These patterns substantiate earlier observations of biomarker and bitumen enrichments on the surfaces of conventionally drilled and curated samples relative to the interiors (3,6,11).”
From Reappraisal of hydrocarbon biomarkers in Archean rocks (2015) · cites this paper as [11]
Known vectors and signatures of contamination, such as surface enrichments, are independent of sampling locality.
“Moreover, known vectors and signatures of contamination (i.e., surface enrichments) are independent of sampling locality (6,11).”
From Reappraisal of hydrocarbon biomarkers in Archean rocks (2015) · cites this paper as [11]
Contamination is the only explanation for the reproducible surficial hopanes and steranes in conventionally drilled and curated Archean samples and for the undetectable or blank-level hopanes and steranes in the ultraclean AIDP cores.
“Instead, contamination is the only explanation for the reproducibility of the detectable surficial hopanes and steranes in conventionally drilled and curated Archean samples (3,6,7,11) and the undetectable or blank level-equivalent hopane and sterane concentrations in samples from the ultraclean AIDP drill cores.”
From Reappraisal of hydrocarbon biomarkers in Archean rocks (2015) · cites this paper as [11]
Two hypotheses have been proposed for surficial biomarker enrichments in Archean drill core: contamination and the live oil effect.
“Two hypotheses have been proposed to explain surficial biomarker enrichments in Archean drill core: contamination and the live oil effect (i.e., the outward migration of hydrocarbons due to drill core depressurization during recovery) (11).”
From Reappraisal of hydrocarbon biomarkers in Archean rocks (2015) · cites this paper as [11]
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Hydrocarbon generation from bacterial biomass in ca. 1320 million years ago
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The rise of lichens during the colonization of terrestrial environments
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Assessing biomarker syngeneity: An in situ approach using monoclonal antibodies
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Quality Control Measures for Enhancing Confidence in Nanoscale IR Spectroscopy
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- Authors
- Brocks, J. J.
- Affiliations
- Australian National University (AU)
- Corresponding author
- Brocks, Jochen J.
- ORCID
- Brocks, Jochen J.
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2011-06
- Volume
- 75
- Issue
- 11
- Pages
- 3196-3213
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W2006914230
- Cited by
- 117
- References
- 33
- Citations by year
- 2026: 2 · 2025: 8 · 2024: 4 · 2023: 7 · 2022: 2 · 2021: 8 · 2020: 5 · 2019: 6 · 2018: 16 · 2017: 9 · 2016: 8 · 2015: 8 · 2014: 14 · 2013: 12 · 2012: 5
- FWCI
- 7.38
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- ANU Open Research (Australian National University) (submittedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Engineering › Mechanics of Materials › Hydrocarbon exploration and reservoir analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- contamination, biomarkers, steranes, hopanes, Hamersley Group, Fortescue Group, Pilbara, early eukaryotes, oil-source rock correlation
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