Determination of pesticide residues in coconut water by liquid–liquid extraction and gas chromatography with electron-capture plus thermionic specific detection and solid-phase extraction and high-performance liquid chromatography with ultraviolet detection
Abstract
Two simple methods were developed to determine 11 pesticides in coconut water, a natural isotonic drink rich in salts, sugars and vitamins consumed by the people and athletes. The first procedure involves solid-phase extraction using Sep-Pak Vac C18 disposable cartridges with methanol for elution. Isocratic analysis was carried out by means of high-performance liquid chromatography with ultraviolet detection at 254 nm to analyse captan, chlorothalonil, carbendazim, lufenuron and diafenthiuron. The other procedure is based on liquid-liquid extraction with hexane-dichloromethane (1:1, v/v), followed by gas chromatographic analysis with effluent splitting to electron-capture detection for determination of endosulfan, captan, tetradifon and trichlorfon and thermionic specific detection for determination of malathion, parathion-methyl and monocrotophos. The methods were validated with fortified samples at different concentration levels (0.01-12.0 mg/kg). Average recoveries ranged from 75 to 104% with relative standard deviations between 1.4 and 11.5%. Each recovery analysis was repeated at least five times. Limits of detection ranged from 0.002 to 2.0 mg/kg. The analytical procedures were applied to 15 samples and no detectable amounts of the pesticides were found in any samples under the conditions described.
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Analyses by gas chromatography with electron capture and high-performance liquid chromatography with ultra-violet detection did not detect any pesticide residues in a set of 15 coconut water samples.
“Analyses by gas chromatography with electron capture and high-performance liquid chromatography with ultra-violet detection did not detect any pesticide residues in a set of 15 coconut water samples [71].”
From Coconut water uses, composition and properties: a review (2012) · cites this paper as [71]
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Diafenthiuron residue and decline in pakchoi and soil under field application
Wang, L., Zhao, P., Zhang, F., Du, F., & Pan, C. (2011) · Ecotoxicology and Environmental Safety · doi:10.1016/j.ecoenv.2011.12.002 · Cited by 12 · see citing works
Pirsaheb, M., Fattahi, N., Amirian, F., & Sharafi, K. (2019) · Journal of Analytical Chemistry · doi:10.1134/s1061934819020096 · Cited by 12 · see citing works
- Authors
- Brito, N. M., Navickiene, S., Polese, L., Jardim, E. F. G., Abakerli, R. B., & Ribeiro, M. L.
- Affiliations
- Universidade Estadual Paulista (Unesp) (BR)
- Embrapa (BR)
- Corresponding author
- Ribeiro, M.L.
- Venue
- Journal of Chromatography A
- Publisher
- Elsevier BV
- Published
- 2002-05
- Volume
- 957
- Issue
- 2
- Pages
- 201-209
- ISSN
- 0021-9673 (ISSN-L)
- OpenAlex
- W1974982552
- Cited by
- 147
- References
- 12
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 1 · 2023: 7 · 2022: 9 · 2021: 9 · 2020: 8 · 2019: 5 · 2018: 6 · 2017: 9 · 2016: 10 · 2015: 4 · 2014: 6 · 2013: 6 · 2012: 7
- FWCI
- 5.68
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Chromatography A (publishedVersion)
- PubMed (publishedVersion)
- Acervo Digital da Universidade Estadual Paulista (Universidade Estadual Paulista) (submittedVersion)
- UNESP Institutional Repository (São Paulo State University) (submittedVersion)
- Topics
- Life Sciences › Agricultural and Biological Sciences › Food Science › Pesticide Residue Analysis and Safety
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Chemistry › Spectroscopy › Analytical Chemistry and Chromatography
- Keywords
- pesticide residues, coconut water, solid-phase extraction, liquid-liquid extraction, electron capture detection, HPLC-UV, gas chromatography, captan, chlorothalonil, carbendazim, lufenuron, diafenthiuron, endosulfan, tetradifon, trichlorfon, malathion, methyl parathion, monocrotophos, food safety
- MeSH terms
- Chromatography, Gas, Chromatography, High Pressure Liquid, Cocos, Pesticide Residues, Sensitivity and Specificity, Spectrophotometry, Ultraviolet, Reproducibility of Results
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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