Cited by 382Arsenic contamination and mitigationAnalytical chemistry methods developmentAnalytical Chemistry and Chromatography

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Arsenic speciation analysis

Gong, Z·2002·Talanta

DOI 10.1016/s0039-9140(02)00258-8

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Abstract

Nearly two dozen arsenic species are present in the environmental and biological systems. Differences in their toxicity, biochemical and environmental behaviors require the determination of these individual arsenic species. Considerable analytical progresses have been made toward arsenic speciation analysis over the last decade. Hyphenated techniques involving a highly efficient separation and a highly sensitive detection have become the techniques of choice. Methods based on high-performance liquid chromatography separation with inductively coupled plasma mass spectrometry, hydride generation atomic spectrometry, and electrospray mass spectrometry detection have been shown most useful for arsenic speciation in environmental and biological matrices. These hyphenated techniques have resulted in the determination of new arsenic species, contributing to a better understanding of arsenic metabolism and biogeochemical cycling. Methods for extracting arsenic species from solid samples and for stabilizing arsenic species in solutions are required for obtaining reliable arsenic speciation information.

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Authors: Gong, Z.
Affiliations: University of Alberta (CA)
Corresponding author: Gong, Z
Venue: Talanta
Publisher: Elsevier BV
Published: 2002-08-16
Volume: 58
Issue: 1
Pages: 77-96
ISSN: 0039-9140 (ISSN-L)
DOI: 10.1016/s0039-9140(02)00258-8
OpenAlex: W2015011264
Cited by: 382
References: 153
Citations by year: 2026: 7 · 2025: 3 · 2024: 7 · 2023: 9 · 2022: 5 · 2021: 11 · 2020: 8 · 2019: 10 · 2018: 11 · 2017: 18 · 2016: 24 · 2015: 24 · 2014: 16 · 2013: 16 · 2012: 21
FWCI: 17.67
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Talanta (publishedVersion)
PubMed (publishedVersion)
Funders: Canada Research Chairs
Canadian Water Network
Natural Sciences and Engineering Research Council of Canada
Topics: Physical Sciences › Environmental Science › Environmental Chemistry › Arsenic contamination and mitigation
Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
Physical Sciences › Chemistry › Analytical Chemistry › Analytical Chemistry and Chromatography
Keywords: arsenic speciation, arsenic species, hyphenated analytical techniques, HPLC-ICP-MS, electrospray ionization mass spectrometry, environmental arsenic, arsenic extraction, arsenic immobilization, arsenic metabolism, biogeochemical cycles

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