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Solid-phase extraction of pesticides from water: possible interferences from dissolved organic material
Abstract
A multiresidue analysis for trifluralin, simazine, atrazine, propazine, diazinon, parathion-methyl, alachlor, malathion, parathion, chlorpyrifos, pendimethalin, methidathion, and DEF in water that utilizes liquid-solid extraction (LSE) with octadecyl-bonded silica cartridges (C18BSCs) followed by gas chromatography/mass spectrometric analysis was developed. Recoveries of most pesticides were greater than 80% with C18BSCs from fortified water at concentration levels from about 1 to 500 ppb. Recoveries with C18BSCs, from an optically adjusted humic acid solution (10 ppm dissolved organic carbon) made to simulate a natural water with a high dissolved organic content, ranged from 29 to 153% and in general were lower than recoveries obtained from pure water. 14C-Labeled diazinon and parathion were recovered from the humic acid solution at levels of 57 and 68%, respectively, with C18BSCs; the remainder of the labeled pesticides was found in the cartridge eluents. Partition coefficients with human acid were calculated based on recovery of 14C-labeled pesticides from the C18BSCs.
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Cited by
Pesticide soil sorption parameters: theory, measurement, uses, limitations and reliability
Wauchope, R. D., Yeh, S., Linders, J. B. H. J., Kloskowski, R., Tanaka, K., Rubin, B., Katayama, A., Kördel, W., Gerstl, Z., Lane, M., et al. (2002) · Pest Management Science · doi:10.1002/ps.489 · Cited by 593
Ahmadi, F., Assadi, Y., Hosseini, S. M. R. M., & Rezaee, M. (2006) · Journal of Chromatography A · doi:10.1016/j.chroma.2005.11.017 · Cited by 325
Casero, I., Sicilia, D., Rubio, S., & Pérez-Bendito, D. (1999) · Analytical Chemistry · doi:10.1021/ac990106g · Cited by 196
Khalili-Zanjani, M. R., Yamini, Y., Yazdanfar, N., & Shariati, S. (2008) · Analytica Chimica Acta · doi:10.1016/j.aca.2007.11.032 · Cited by 152
Standley, L. J., Rudel, R. A., Swartz, C. H., Attfield, K. R., Christian, J., Erickson, M., & Brody, J. G. (2008) · Environmental Toxicology and Chemistry · doi:10.1897/07-604.1 · Cited by 105
Metadata
- Authors
- Johnson, W. E., Fendinger, N. J., & Plimmer, J. R.
- Venue
- Analytical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1991-08-01
- Volume
- 63
- Issue
- 15
- Pages
- 1510-1513
- ISSN
- 0003-2700 (ISSN-L)
- 1520-6882
- OpenAlex
- W1978036912
- Cited by
- 184
- References
- 0
- FWCI
- 22.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Johnson, W. E., Fendinger, N. J., & Plimmer, J. R. (1991). Solid-phase extraction of pesticides from water: possible interferences from dissolved organic material. Analytical Chemistry. https://doi.org/10.1021/ac00015a003
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