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Metallic Nanoparticle−Carbon Nanotube Composites for Electrochemical Determination of Explosive Nitroaromatic Compounds
Abstract
Metal nanoparticles (Pt, Au, or Cu) together with multiwalled and single-walled carbon nanotubes (MWCNT and SWCNT) solubilized in Nafion have been used to form nanocomposites for electrochemical detection of trinitrotoluene (TNT) and several other nitroaromatics. Electrochemical and surface characterization by cyclic voltammetry, AFM, TEM, SEM, and Raman spectroscopy confirmed the presence of metal nanoparticles on CNTs. Among various combinations tested, the most synergistic signal effect was observed for the nanocomposite modified glassy carbon electrode (GC) containing Cu nanoparticles and SWCNT solubilized in Nafion. This combination provided the best sensitivity for detecting TNT and other nitroaromatic compounds. Adsorptive stripping voltammetry for TNT resulted in a detection limit of 1 ppb, with linearity up to 3 orders of magnitude. Selectivity toward the number and position of the nitro groups in different nitroaromatics was very reproducible and distinct. Reproducibility of the TNT signal was within 7% (n = 8) from one electrode preparation to another, and the response signal was stable (+/-3.8% at 95% confidence interval) for 40 repeated analyses with 10 min of preconditioning. The Cu-SWCNT-modified GC electrode was demonstrated for analysis of TNT in tap water, river water, and contaminated soil.
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Cites
Helical microtubules of graphitic carbon
Iijima, S. (1991) · Nature · doi:10.1038/354056a0 · Cited by 43,098
Electrochemical Methods: Fundamentals and Applications
de Rooij, D. M. R. (2003) · Anti-Corrosion Methods and Materials · doi:10.1108/acmm.2003.12850eae.001 · Cited by 13,009
Crystalline Ropes of Metallic Carbon Nanotubes
Thess, A., Lee, R., Nikolaev, P., Dai, H., Petit, P., Robert, J., Xu, C., Lee, Y. H., Kim, S. G., Rinzler, A. G., et al. (1996) · Science · doi:10.1126/science.273.5274.483 · Cited by 5,580
Moskovits, M. (1985) · Reviews of Modern Physics · doi:10.1103/revmodphys.57.783 · Cited by 5,466
Baughman, R. H., Cui, C., Zakhidov, A. A., Iqbal, Z., Barisci, J. N., Spinks, G. M., Wallace, G. G., Mazzoldi, A., De Rossi, D., Rinzler, A. G., et al. (1999) · Science · doi:10.1126/science.284.5418.1340 · Cited by 2,490
Are fullerene tubules metallic?
Mintmire, J. W., Dunlap, B. I., & White, C. T. (1992) · Physical Review Letters · doi:10.1103/physrevlett.68.631 · Cited by 2,243
Enhancement of Protein Crystal Nucleation by Critical Density Fluctuations
Wolde, P. R. T., & Frenkel, D. (1997) · Science · doi:10.1126/science.277.5334.1975 · Cited by 1,433
Cloned Transgenic Calves Produced from Nonquiescent Fetal Fibroblasts
Cibelli, J. B., Stice, S. L., Golueke, P. J., Kane, J. J., Jerry, J., Blackwell, C., Ponce de León, F. A., & Robl, J. M. (1998) · Science · doi:10.1126/science.280.5367.1256 · Cited by 1,396
Electrochemical Biosensing Platforms Using Platinum Nanoparticles and Carbon Nanotubes
Hrapovic, S., Liu, Y., Male, K. B., & Luong, J. H. T. (2004) · Analytical Chemistry · doi:10.1021/ac035143t · Cited by 1,064
Self-citationProtein Electrochemistry Using Aligned Carbon Nanotube Arrays
Gooding, J. J., Wibowo, R., Liu, Yang, W., Losic, D., Orbons, S., Mearns, F. J., Shapter, J. G., & Hibbert, D. B. (2003) · Journal of the American Chemical Society · doi:10.1021/ja035722f · Cited by 881
Mutagenicity and genotoxicity of nitroarenes
Rosenkranz, H. S., & Mermelstein, R. (1983) · Mutation Research/Reviews in Genetic Toxicology · doi:10.1016/0165-1110(83)90034-9 · Cited by 631
Fully collapsed carbon nanotubes
Chopra, N. G., Benedict, L. X., Crespi, V. H., Cohen, M. L., Louie, S. G., & Zettl, A. (1995) · Nature · doi:10.1038/377135a0 · Cited by 496
Oxygen reduction reaction kinetics and mechanism on platinum nanoparticles inside Nafion®
Antoine, O., Bultel, Y., & Durand, R. (2001) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(00)00492-7 · Cited by 433
Bioelectrochemical Single-Walled Carbon Nanotubes
Azamian, B. R., Davis, J. J., Coleman, K. S., Bagshaw, C. B., & Green, M. L. H. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0272989 · Cited by 429
Control of the Shape and the Size of Copper Metallic Particles
Lisiecki, I., Billoudet, F., & Pileni, M. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9523837 · Cited by 358
Evidence from Antarctic ice cores for recent increases in snow accumulation
Morgan, V. I., Goodwin, I. D., Etheridget, D. M., & Wookey, C. W. (1991) · Nature · doi:10.1038/354058a0 · Cited by 348
The Magnetic Excitation Spectrum and Thermodynamics of High- T c Superconductors
Dai, P., Mook, H. A., Hayden, S. M., Aeppli, G., Perring, T. G., Hunt, R. D., & Doğan, F. (1999) · Science · doi:10.1126/science.284.5418.1344 · Cited by 306
Surface-enhanced Raman spectroscopy
Garrell, R. L. (1989) · Analytical Chemistry · doi:10.1021/ac00181a001 · Cited by 283
Electrochemical reduction of oxygen on platinum nanoparticles in alkaline media
Geniès, L., Faure, R., & Durand, R. (1998) · Electrochimica Acta · doi:10.1016/s0013-4686(98)00254-0 · Cited by 268
Majid, E., Hrapovic, S., Liu, Y., Male, K. B., & Luong, J. H. T. (2006) · Analytical Chemistry · doi:10.1021/ac0513562 · Cited by 242
Self-citationOxygen reduction on well-defined platinum nanoparticles inside recast ionomer
Gamez, A., Richard, D., Gallezot, P., Gloaguen, F., Faure, R., & Durand, R. (1996) · Electrochimica Acta · doi:10.1016/0013-4686(95)00305-x · Cited by 155
Eiler, J. M., Farley, K. A., Valley, J. W., Stolper, E. M., Hauri, E. H., & Craig, H. (1995) · Nature · doi:10.1038/377138a0 · Cited by 146
Solla‐Gullón, J., Montiel, V., Aldaz, A., & Clavilier, J. (2003) · Journal of The Electrochemical Society · doi:10.1149/1.1534600 · Cited by 130
Detection of 1-nitropyrene in yakitori (grilled chicken)
Kinouchi, T., Tsutsui, H., & Ohnishi, Y. (1986) · Mutation Research/Genetic Toxicology · doi:10.1016/0165-1218(86)90042-x · Cited by 77
Casella, I. G., Stradis, A. D., & Desimoni, E. (1996) · The Analyst · doi:10.1039/an9962100249 · Cited by 40
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Carbon nanotube reinforced metal matrix composites - a review
Bakshi, S. R., Lahiri, D., & Agarwal, A. (2010) · International Materials Reviews · doi:10.1179/095066009x12572530170543 · Cited by 1,446
Carbon nanotubes for electrochemical biosensing
RIVAS, G., RUBIANES, M., RODRIGUEZ, M., FERREYRA, N., LUQUE, G., PEDANO, M., MISCORIA, S., & PARRADO, C. (2007) · Talanta · doi:10.1016/j.talanta.2007.10.013 · Cited by 554
Role of carbon nanotubes in electroanalytical chemistry
Agüí, L., Yáñez-Sedeño, P., & Pingarrón, J. M. (2008) · Analytica Chimica Acta · doi:10.1016/j.aca.2008.05.070 · Cited by 497
Lu, J., Do, I., Drzal, L. T., Worden, R. M., & Lee, I. (2008) · ACS Nano · doi:10.1021/nn800244k · Cited by 438
Noble metal nanoparticles/carbon nanotubes nanohybrids: Synthesis and applications
Wu, B., Kuang, Y., Zhang, X., & Chen, J. (2011) · Nano Today · doi:10.1016/j.nantod.2010.12.008 · Cited by 388
Metadata
- Authors
- Hrapovic, S., Majid, E., Liu, Y., Male, K., & Luong, J. H. T.
- Venue
- Analytical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-06-17
- Volume
- 78
- Issue
- 15
- Pages
- 5504-5512
- ISSN
- 0003-2700 (ISSN-L)
- 1520-6882
- OpenAlex
- W1998720611
- Cited by
- 271
- References
- 25
- FWCI
- 18.89
- Type
- journal article
- Language
- en
- Open access
- closed
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