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Improved Cycle Life and Stability of Lithium Metal Anodes through Ultrathin Atomic Layer Deposition Surface Treatments

Kazyak, Eric, Wood, Kevin N., Dasgupta, Neil P.·2015·Chemistry of Materials

Abstract

Improving the cycle life and failure resistance of lithium metal anodes is critical for next-generation rechargeable batteries. Here, we show that treating Li metal foil electrodes with ultrathin (∼2 nm) Al 2 O 3 layers using atomic layer deposition (ALD) without air exposure can prevent dendrite formation upon cycling at a current density of 1 mA/cm 2 . This has the effect of doubling the lifetime of the anode before failure both under galvanostatic deep discharge conditions and cyclic plating/stripping of symmetric Li–Li cells. The ALD treated electrodes can be cycled for 1259 cycles before failure occurs, which is attributed to improved electrode morphology resulting from homogeneous Li ion flux across the electrode/electrolyte interface.

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Crossref · 10.1021/acs.chemmater.5b02789

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Metadata

Authors
Kazyak, E., Wood, K. N., & Dasgupta, N. P.
Venue
Chemistry of Materials
Published
2015-09-11
Volume
27
Issue
18
Pages
6457-6462
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2512827926
Cited by
356
References
2
FWCI
16.68
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Improved Cycle Life and Stability of Lithium Metal Anodes through Ultrathin Atomic Layer Deposition Surface Treatments. https://app.cochat.ai/papers/10.1021/acs.chemmater.5b02789
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Kazyak, E., Wood, K. N., & Dasgupta, N. P. (2015). Improved Cycle Life and Stability of Lithium Metal Anodes through Ultrathin Atomic Layer Deposition Surface Treatments. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.5b02789

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.