The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction
Open accessAbstract
In this study, carbon dioxide is one of the end products of combustion, and is not a benign component of the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented levels and continues to increase owing to an escalating rate of fossil fuel combustion, causing concern about climate change and rising sea levels. In view of the inevitable depletion of fossil fuels, a possible solution to this problem is the recycling of carbon dioxide, possibly captured at its point of generation, to fuels. Researchers in this field are using solar energy for CO2 activation and utilization in several ways: (i) so-called artificial photosynthesis using photo-induced electrons; (ii) bulk electrolysis of a CO2 saturated solution using electricity produced by photovoltaics; (iii) CO2 hydrogenation using solar-produced H2; and (iv) the thermochemical reaction of metal oxides at extremely high temperature reached by solar collectors. Since the thermodynamics of CO2 at high temperature (> 1000 ºC) are quite different from those near room temperature, only chemistry below 200 ºC is discussed in this review.
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Cites
Recent advances in catalytic hydrogenation of carbon dioxide
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Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
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Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst
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Metadata
- Authors
- Wang, W.-H., Himeda, Y., Muckerman, J. T., Manbeck, G. F., & Fujita, E.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-09-03
- Volume
- 115
- Issue
- 23
- Pages
- 12936-12973
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2296880544
- Cited by
- 1,507
- References
- 8
- FWCI
- 3.05
- Type
- journal article
- Language
- en
- Open access
- green
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- Wang, W.-H., Himeda, Y., Muckerman, J. T., Manbeck, G. F., & Fujita, E. (2015). CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.5b00197
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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