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Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
Open accessAbstract
Pd-catalyzed cross-coupling reactions that form C-N bonds have become useful methods to synthesize anilines and aniline derivatives, an important class of compounds throughout chemical research. A key factor in the widespread adoption of these methods has been the continued development of reliable and versatile catalysts that function under operationally simple, user-friendly conditions. This review provides an overview of Pd-catalyzed N-arylation reactions found in both basic and applied chemical research from 2008 to the present. Selected examples of C-N cross-coupling reactions between nine classes of nitrogen-based coupling partners and (pseudo)aryl halides are described for the synthesis of heterocycles, medicinally relevant compounds, natural products, organic materials, and catalysts.
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Cites
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Münzel, M., Szeibert, C., Glas, A. F., Globisch, D., & Carell, T. (2011) · Journal of the American Chemical Society · doi:10.1021/ja111304f · Cited by 28
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Predicting reaction performance in C–N cross-coupling using machine learning
Ahneman, D. T., Estrada, J. G., Lin, S., Dreher, S. D., & Doyle, A. G. (2018) · Science · doi:10.1126/science.aar5169 · Cited by 1,058
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The importance of synthetic chemistry in the pharmaceutical industry
Campos, K. R., Coleman, P. J., Alvarez, J. C., Dreher, S. D., Garbaccio, R. M., Terrett, N. K., Tillyer, R. D., Truppo, M. D., & Parmee, E. R. (2019) · Science · doi:10.1126/science.aat0805 · Cited by 668
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Reconfigurable system for automated optimization of diverse chemical reactions
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Metadata
- Authors
- Ruiz-Castillo, P., & Buchwald, S. L.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-09-30
- Volume
- 116
- Issue
- 19
- Pages
- 12564-12649
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2525864328
- Cited by
- 2,936
- References
- 1
- FWCI
- 6.17
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Ruiz-Castillo, P., & Buchwald, S. L. (2016). Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.6b00512
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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